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Formation and Spatial Statistics of Spherulitic Grain Pattern in Solidified Films of Isotactic Polypropylene

Published online by Cambridge University Press:  15 February 2011

Tao Huang ,
Alejandro D. Rey  and
Musa R. Kamal
Tao Huang
Affiliation:
MzGill University, Department of Chemical Engineering, Montreal, Quebec, Caral, H3A2A7
Alejandro D. Rey
Affiliation:
MzGill University, Department of Chemical Engineering, Montreal, Quebec, Caral, H3A2A7
Musa R. Kamal
Affiliation:
MzGill University, Department of Chemical Engineering, Montreal, Quebec, Caral, H3A2A7
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Abstract

Image analysis and measurements on forimation and spatial statistics of spherulitic grain pattern in solidified films of a model polymer, isotactic polypropylene (iPP), have been carried out during in-situ observation experiments under isothermnl conditions. Topological correlations and geometrical distribution fuinctions of polymer grain sides and area are reported. Some topologically unstable configurations, such as multi-vertices, “T” type vertices and two sided grain (lens), have been found. Analysis by spatial tessellations shows that the tenWal evolution and spatial distributions of nuclei point patterns play a role in all of these microstructural properties.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 362: Symposium J – Grain-Size and Mechanical Properties--Fundamentals and Applications , 1994 , 193
Copyright
Copyright © Materials Research Society 1995

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References

[1] Fradkov, V.E., Glicksman, M.E., Palmer, M., Nordbergand, J. and Rajan, K., Physics D, 66,50,(1993); Acta metall. Mater. 42,2719,(1994).Google Scholar
[2] Huang, Tao, Rey, A.D. and Kamal, M.R., Polmer, (1994), in press.Google Scholar
[3] Weaire, D. and River, N., Contemp.Phys. 25,59,(1984).Google Scholar
[4] Rivier, N., J.Phys. I. France, 4,127,(1994).Google Scholar
[5] Abbruzese, G., Heckelmann, I. and Lucke, K., Acta matell. mater. 40,519,(1992).Google Scholar
[6] Huang, Tao, Kamal, M.R. and Rey, A.D., J. Mater.Sci.Lett., (1994), in press.Google Scholar
[7] Holm, E.A., AGlazier, J., Srolovity, D.J. and Grest, G.S., Phys.Rev.A 43,2662,(1992).Google Scholar
[8] Fortune, S., Algorithmica, 2,153,(1987); in Lecture Notes Series on Computing, Vol.1, World Scientific, p. 193, (1992).Google Scholar