Hostname: page-component-586b7cd67f-rcrh6 Total loading time: 0 Render date: 2024-11-24T16:06:45.931Z Has data issue: false hasContentIssue false
  • English
  • Français

Facile synthesis of polypyrrole/graphene nanosheet-based nanocomposites as catalyst support for fuel cells

Published online by Cambridge University Press:  28 January 2011

Burcu Saner ,
Selmiye Alkan Gürsel  and
Yuda Yürüm
Burcu Saner
Affiliation:
Faculty of Engineering and Natural Sciences, Sabanci University Orhanli, Tuzla, Istanbul 34956, Turkey
Selmiye Alkan Gürsel
Affiliation:
Faculty of Engineering and Natural Sciences, Sabanci University Orhanli, Tuzla, Istanbul 34956, Turkey
Yuda Yürüm
Affiliation:
Faculty of Engineering and Natural Sciences, Sabanci University Orhanli, Tuzla, Istanbul 34956, Turkey
Get access

Abstract

The integration of catalyst metals into the graphene-based composites can be a new way to ensure thermal and electronic conductivities of the catalyst support materials in polymer electrolyte membrane fuel cells. In this work, graphene nanosheets were synthesized via a mild and safer chemical route including three major steps: graphite oxidation, ultrasonic treatment and chemical reduction. Then, polypyrrole was coated on graphene nanosheets by in-situ polymerization to fabricate polypyrrole/graphene nanosheet-based nanocomposites as the catalyst supports. Pt nanoparticles were uniformly dispersed on the surface of nanocomposites by sonication technique.

Keywords

chemical reactionpolymerizationsurface chemistry
Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 1312: Symposium HH/II/JJ – Polymer-Based Materials and Composites—Synthesis, Assembly and Applications , 2011 , mrsf10-1312-ii12-08
Copyright
Copyright © Materials Research Society 2011

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1. Kim, H., Abdala, A. A., and Macosko, C. W., Macromolecules 43, 6515–6530 (2010).Google Scholar
2. Stankovich, S., Dikin, D. A., Dommett, G. H. B., et al. , Nature 442, 282–286 (2006).Google Scholar
3. McAllister, M. J., et al. , Chem. Mater. 19, 4396 (2007).Google Scholar
4. Natarajan, S. and Hamelin, J., Journal of The Electrochemical Society 156, B210–B215 (2009).Google Scholar
5. Gasteiger, H. A., Kocha, S. S., Sompalli, B., Wagner, F. T., Appl. Catal. B. 56, 9 (2005).Google Scholar
6. Dersch, R., Steinhart, M., Boudriot, U., Greiner, A., Wendorff, J.H., Polym. Adv. Technol. 16, 276 (2005).Google Scholar
7. Zhao, H., Li, L., Yang, J., Zhang, Y., Journal of Power Sources 184, 375 (2008).Google Scholar
8. Saner, B., Okyay, F., Yürüm, Y., Fuel 89, 1903–1910 (2010).Google Scholar
9. Vernitskaya, T. V., Efimov, O. N., Russian Chemical Reviews 66, 443–457 (1997).Google Scholar
10. Armes, S. P., Synth. Met. 20, 365–371 (1987).Google Scholar
11. Sakintuna, B., Cetinkaya, S., Yürüm, Y., Energy Fuels 18, 883–888 (2004).Google Scholar
12. Sato, K., Saito, R., et al. , Chemical Physics Letters 427, 117–121 (2006).Google Scholar
13. Sahoo, N. G., Jung, Y. C., So, H. H., Cho, J. W., Synth. Met. 157, 374–379 (2007).Google Scholar
14. Rajalakshmi, N., Ryu, H., Shaijumon, M. M., Ramaprabhu, S., J. Power Sources 140, 250–257 (2005).Google Scholar