Hostname: page-component-745bb68f8f-f46jp Total loading time: 0 Render date: 2025-02-05T07:03:29.850Z Has data issue: false hasContentIssue false
  • English
  • Français

Exact Optical Susceptibilities of Three State Systems Interacting with a Single Frequency Electric Field

Published online by Cambridge University Press:  25 February 2011

Theresa C. Kavanaugh  and
Robert J. Silbey
Theresa C. Kavanaugh
Affiliation:
Department of Chemistry, Massachusetts Institute of Technology, Cambridge, MA
Robert J. Silbey
Affiliation:
Department of Chemistry, Massachusetts Institute of Technology, Cambridge, MA
Get access

Abstract

Using Floquet theory together with density matrix formalism, an exact, nonpertur-bative expression for the optical susceptibility of a three level system interacting with a single mode electric field is derived. By using a three state model that mimics a polymeric system, it is shown that in certain cases, using typical values for the intensity of the electric field, successive terms in the series χω=χ(1) + χ(3) E2… approach the same of order magnitude.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 247: Symposium N – Electrical, Optical, and Magnetic Properties of Organic Solid State Materials , 1992 , 169
Copyright
Copyright © Materials Research Society 1992

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1. Hanna, D. C., Yuratich, M. A., and Cotter, D., Nonlinear Optics of Free Atoms and Molecules (Springer, Berlin, 1979).Google Scholar
2. Shen, Y. R. Principles of Nonlinear Optics (Wiley, New York, 1984)Google Scholar
3. Wang, K. and Chu, S-I, J. Chem. Phys 86 3225 1987.Google Scholar
4. Dick, B. and Hochstrasser, R. M. Chem. Phys. 75 133 1985.Google Scholar
5. Kavanaugh, T. C. and Silbey, R. J., to be publishedGoogle Scholar
6. Soos, Z. G. and Ramasesha, S., J.Chem. Phys 90 1067 1989; S. Etemad and Z. Soos preprint (1991).Google Scholar