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Eosin Y-sensitized ZnO/TiO2 for efficient visible light photocatalytic hydrogen evolution

Published online by Cambridge University Press:  23 August 2011

Haipei Liu ,
Dengwei Jing  and
Liejin Guo
Haipei Liu
Affiliation:
State Key Laboratory of Multiphase Flow in Power Engineering, School of Energy and Power Engineering, Xi’an Jiaotong University, Xi’an 710049, P. R. China
Dengwei Jing
Affiliation:
State Key Laboratory of Multiphase Flow in Power Engineering, School of Energy and Power Engineering, Xi’an Jiaotong University, Xi’an 710049, P. R. China
Liejin Guo*
Affiliation:
State Key Laboratory of Multiphase Flow in Power Engineering, School of Energy and Power Engineering, Xi’an Jiaotong University, Xi’an 710049, P. R. China
*
*[email protected]
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Abstract

In this work a series of Eosin Y-ZnO(x%)/TiO2 were prepared. ZnO well dispersed on the surface of TiO2, which improves the adsorption of Eosin Y and the excited electron to transfer to the conduction band of TiO2. Therefore the visible light activity of 0.2%Pt-Eosin Y-ZnO(x%)/TiO2 is much higher than that of the 0.2%Pt-Eosin Y-TiO2 and 0.2%Pt-Eosin Y-ZnO. The 0.2%Pt-Eosin Y- ZnO(1.5%)/TiO2 has the highest visible light activity among the catalysts coupled with various ZnO amount, whose activity is increased by a factor of 3.5 compared to that of 0.2%Pt-Eosin Y-TiO2. It is proposed that, 0.2%Pt-Eosin Y-ZnO(1.5%)/TiO2 has the optimal trapping sites of carriers and thickness of the space-charge layer on the TiO2 particle surface, so these factors result a more efficient charge separation, an increased lifetime of the charge carriers, and the enhanced of hydrogen production .

Keywords

catalytichydrogenationenergy generation
Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 1326: Symposium F – Renewable Fuels and Nanotechnology , 2011 , mrss11-1326-f03-07
Copyright
Copyright © Materials Research Society 2011

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References

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