Published online by Cambridge University Press: 21 February 2011
We present electric-field dependent electroreflectance and photocurrent spectra of visible-bandgap Inx(AlyGa1-y)1-xP/Inx’(Aly’Ga1-y’)1-x’P multiple-quantum-well (MQW) structures. These structures, grown by metal-organic vapor phase epitaxy on 6°-misoriented (100) GaAs substrates, have undoped MQWs sandwiched between doped Ino 5AI0.5P layers, forming p-i-n diodes. Quantum-well compositions in the range 0.46≤x≤0.52 and 0≤y≤0.4, corresponding to bandgaps in the red to yellow range, were used. The Stark shifts in these various samples were measured and found to depend on the details of the Mg p-type doping profile, confirming important diffusion effects, in agreement with secondary ion mass spectrometry and capacitance-voltage data. Our results show that these new materials are promising for visible-wavelength optical modulator applications.