Published online by Cambridge University Press: 10 February 2011
Diamond nucleation and growth by CFD were investigated to examine the possibility of engineering diamond growth shapes for practical applications. The results obtained include the following:
a) Evidence supporting certain factors influencing nucleation - useful in controlling nucleation sites and nucleation density.
b) Evidence for a double spiral growth mechanism operating on (111) faces under specific conditions - indicates the possibility of a new mechanism operating for diamond growth from the vapour phase, and the possibility of larger growth rates.
c) Evidence for the enhanced growth in <100= crystallographic direction on a cubooctahedral crystal and its control by varying the process parameters – thus showing the possibility of obtaining diamond needles and tips as engineered growth shapes, for specific applications.