Hostname: page-component-78c5997874-j824f Total loading time: 0 Render date: 2024-11-03T05:01:06.296Z Has data issue: false hasContentIssue false
  • English
  • Français

Determination of TN for Ba6Mn4MO15 (M = Cu, Zn) by Neutron Diffraction

Published online by Cambridge University Press:  18 March 2011

P. D. Battle  and
E. J. Cussen
P. D. Battle
Affiliation:
Inorganic Chemistry Laboratory, Oxford University, South Parks Road, Oxford, OX1 3QR, U.K.
E. J. Cussen
Affiliation:
Inorganic Chemistry Laboratory, Oxford University, South Parks Road, Oxford, OX1 3QR, U.K.
Get access

Abstract

The Néel temperatures of Ba6Mn4MO15 (M = Cu, Zn) have been determined by neutron powder diffraction to be ∼ 6 K. In both cases, short-range magnetic coupling within the individual chains of this pseudo-1D crystal structure produces a susceptibility maximum at a temperature somewhat higher than that at which the frustrated interchain interactions establish long-range magnetic order.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 658: Symposium GG – Solid-State Chemistry of Inorganic Materials III , 2000 , GG2.4
Copyright
Copyright © Materials Research Society 2001

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1. Darriet, J. and Subramanian, M.A., J. Mater. Chem. 5, 543 (1995).Google Scholar
2. Moore, C.A., Cussen, E.J., and Battle, P.D., J. Solid State Chem. 153, 254 (2000).Google Scholar
3. Irons, S.H., Sangrey, T.D., Beauchamp, K.M., Smith, M.D., and zur-Loye, H.C., Phys. Rev. B 61, 11594 (2000).Google Scholar
4. Vente, J.F., Lear, J.K., and Battle, P.D., J. Mater. Chem. 5, 1785 (1995).Google Scholar
5. Zakhour-Nakhl, M., Weill, F., Darriet, J., and Perez-Mato, J.M., Int. J. Inorg. Materials 2, 71 (2000).Google Scholar
6. Cussen, E.J., Vente, J.F., and Battle, P.D., J. Amer. Chem. Soc. 121, 3958 (1999).Google Scholar
7. Rietveld, H.M., J. Appl. Crystallogr. 2, 65 (1969).Google Scholar
8. Larson, A.C. and von-Dreele, R.B., General Structure Analysis System (GSAS), Los Alamos National Laboratories, Report LAUR 86-748, 1990.Google Scholar
9. Cussen, E.J. and Battle, P.D., Chem. Mater. 12, 831 (2000).Google Scholar