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Design of semi-interpenetrating networks based on poly(ethyl-2-cyanoacrylate) and oligo(ethylene glycol) diglycidyl ether

Published online by Cambridge University Press:  08 February 2012

Guiseppe Tripodo ,
C. Wischke  and
A. Lendlein
Guiseppe Tripodo
Affiliation:
Center for Biomaterial Development and Berlin-Brandenburg Center for Regenerative Therapies, Institute of Polymer Research, Helmholtz-Zentrum Geesthacht, Kantstrasse 55, 14513 Teltow, Germany.
C. Wischke
Affiliation:
Center for Biomaterial Development and Berlin-Brandenburg Center for Regenerative Therapies, Institute of Polymer Research, Helmholtz-Zentrum Geesthacht, Kantstrasse 55, 14513 Teltow, Germany.
A. Lendlein
Affiliation:
Center for Biomaterial Development and Berlin-Brandenburg Center for Regenerative Therapies, Institute of Polymer Research, Helmholtz-Zentrum Geesthacht, Kantstrasse 55, 14513 Teltow, Germany.
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Abstract

The synthesis of semi-interpenetrating networks (SIPN) based on linear poly(ethyl 2-cyanoacrylate) (PECA) and oligo(ethylene glycol) diglycidyl ether (OEGDG) based polymer networks was motivated by the hypothesis that the brittleness of polycyanoacrylates may be overcome by incorporating them into a polymer network architecture. A sequential synthetic route was applied, in which first PECA was prepared by anionic polymerization. Subsequently, OEGDG was crosslinked with different anhydrides and curing catalysts to form networks with hydrolyzable ester bonds and interpenetrating PECA. These SIPNs showed a low water uptake compared to other polyether based networks. Some of the obtained materials were transparent and exhibited a great flexibility, which was maintained also after 24 h of immersion in water and subsequent drying. Such networks could be components of future stimuli-sensitive material systems.

Keywords

biomaterialpolymerfilm
Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 1403: Symposium V – Multifunctional Polymer-Based Materials , 2012 , mrsf11-1403-v12-23
Copyright
Copyright © Materials Research Society 2012

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