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Defects in Epitaxial lift-off Thin Si Films/Wafers and Their Influence on the Solar Cell Performance

Published online by Cambridge University Press:  03 November 2014

Bhushan Sopori
Affiliation:
National Renewable Energy Laboratory, Golden, CO
Srinivas Devayajanam
Affiliation:
National Renewable Energy Laboratory, Golden, CO New Jersey Institute of Technology, Newark, NJ
Prakash Basnyat
Affiliation:
National Renewable Energy Laboratory, Golden, CO New Jersey Institute of Technology, Newark, NJ
Helio Moutinho
Affiliation:
National Renewable Energy Laboratory, Golden, CO
Robert Reedy
Affiliation:
National Renewable Energy Laboratory, Golden, CO
Kaitlyn VanSant
Affiliation:
National Renewable Energy Laboratory, Golden, CO
T.S. Ravi
Affiliation:
Crystal Solar Inc., San Jose, CA
Ruiying Hao
Affiliation:
Crystal Solar Inc., San Jose, CA
Jean Vatus
Affiliation:
Crystal Solar Inc., San Jose, CA
Somnath Nag
Affiliation:
Crystal Solar Inc., San Jose, CA
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Abstract

In this paper, we will describe the nature of defects and impurities in thick epitaxial-Si layers and their influence on the cell efficiency. These wafers have very low average dislocation density. Stacking faults (SFs) are the main defect in epi layers. They can occur in many configurations—be isolated, intersecting, and nested. When nested, they can be accompanied by formation of coherent twins resulting in dendritic growth, with pyramids protruding out of the wafer surface. Such pyramids create large local stresses and punch out dislocations. The main mechanism of dislocation formation is through pyramids. Stacking faults degrade solar cell performance. Analyses of the solar cells have revealed that the nested SFs have a controlling effect on the solar cell performance. A well-controlled growth can minimize defect generation and produce wafers that can yield cell efficiencies close to 20%.

Type
Articles
Copyright
Copyright © Materials Research Society 2014 

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References

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