Hostname: page-component-78c5997874-s2hrs Total loading time: 0 Render date: 2024-11-03T00:36:54.505Z Has data issue: false hasContentIssue false

Creep Deformation Studies in Directionally Solidified MoSi2-Mo5Si3 Eutectics

Published online by Cambridge University Press:  01 January 1992

D. P. Mason
Affiliation:
Department of Materials Science and Engineering, The University of Michigan, Ann Arbor, MI 48109-2125
D. C. Van Aken
Affiliation:
Department of Materials Science and Engineering, The University of Michigan, Ann Arbor, MI 48109-2125
Get access

Abstract

The high temperature deformation behavior of directionally solidified (DS) MoSi2-Mo5Si3 eutectics was studied and compared to powder processed MoSi2-Mo5Si3 composites having the same volume fraction of Mo5Si3. Decremental step strain rate tests were performed in the temperature range of 1100-1300°C and at strain rates between 10−4 to 10−6/s. A considerable increase in the flow stress was observed for the directionally solidified material. At 1200°C and a strain rate of 10−6/s the flow stress of the DS eutectic was 255 MPa as compared to 20 MPa for the powder processed composite. The high temperature strength of the DS eutectic was unaffected by changes in the scale of the lamellar micro-structure and these results were modeled using a constitutive relation for power law creep. A stress exponent of 4.5 and an activation energy of 300 kJ/mol was determined for the DS eutectic. Evidence of dislocation glide and climb was observed in the MoSi2 lamellae whereas the dislocation density was small in the Mo5Si3 phase. The improved creep strength of the eutectic is believed to be a result of both the fibrous morphology and a stronger interface structure as compared to the powder processed composite.

Type
Research Article
Copyright
Copyright © Materials Research Society 1995

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1. Petrovic, J. J. and Vasudevan, A.K., Intermetallic Matrix Composites II. eds. Miracle, D.B., Anton, D.L. and Graves, J.A. (Mat. Res. Soc. Proc.vol. 273, Pittsburg, PA 1992) p 229.Google Scholar
2. Alman, D.E., Shaw, K.G., Stoloff, N.S. and Rajan, K., Mat. Sci. and Eng. A155, 95 (1992).Google Scholar
3. Gibala, R., Ghosh, A.K., Van Aken, D.C., Srolovitz, D.J., Basu, A., Chang, H., Mason, D.P. and Yang, W., Mat. Sci. and Eng. A155, 147 (1992).Google Scholar
4. Wiederhom, S.M., Gettings, R.J., Roberts, D.E. and Ostertag, C., Mat. Sci. and Eng. A155, 147 (1992).Google Scholar
5. Aiken, R.M., Scripta Metall. 26, 1025 (1992).Google Scholar
6. Mason, D. P. and Van Aken, D. C., Scripta Metall., in press.Google Scholar
7. Anstis, G.R., Chantikul, P., Lawn, B.R. and Marshall, D.B., J. Am. Ceram. Soc. 64, 9 (1981).Google Scholar
8. Bhattacharya, A.K. and Petrovic, J.J., J. Am. Ceram. Soc. 74, 10 (1992).Google Scholar
9. Srinivasan, S.R. and Schwartz, R.B., J. Mater. Res. 7, 1610 (1992).Google Scholar
10. Hardwick, D. A., Martin, P. L. and Moores, R. J..Scripta Metall. 27, 391 (1992).Google Scholar
11. Cotton, J. D., Kim, Y. S. and Kaufman, M. J., Mat. Sci. and Eng. A144, 287 (1991).Google Scholar
12. Sadananda, K., Feng, C. R., Jones, H. and Petrovic, J. J., Mat. Sci. and Eng. A155, 227 (1992).Google Scholar
13. Suzuki, M., Nutt, S. R. and Aiken, R. M. Jr, Intermetallic Matrix Composites II. eds. Miracle, D. B., Anton, D. L. and Graves, J. A. (Mat. Res. Soc. Proc.vol. 273, Pittsburg, PA 1992) p267.Google Scholar
14. Bose, S., Mat. Sci. and Eng. A155, 217 (1992).Google Scholar
15. Anton, D. L. and Shaw, D. M., High Temperature Ordered Intermetallic Alloys IV, eds. Johnson, L. A., Pope, D.P. and Stiegler, J.O., (Mat. Res. Soc. Proc.Vol. 213, Pittsburg, PA 1991) p.733.Google Scholar
16. Kung, H., Mason, D.P., Basu, A., Chang, H., Van Aken, D.C, Ghosh, A.K and Gibala, R., Intermetallic Matrix Composites II, eds. Miracle, D. B., Anton, D. L. and Graves, J. A. (Mat. Res. Soc. Proc. vol. 273, Pittsburg, PA 1992) p 241.Google Scholar