Hostname: page-component-586b7cd67f-dsjbd Total loading time: 0 Render date: 2024-11-28T14:52:25.727Z Has data issue: false hasContentIssue false
  • English
  • Français

Correlation Between Nanostructure and Crystalline Morphology and Mechanical Response in Nylon 6 Nanocomposites

Published online by Cambridge University Press:  11 February 2011

E. Reynaud ,
D. Shah  and
E.P. Giannelis
E. Reynaud
Affiliation:
Department of Materials Science and Engineering, Cornell University, Ithaca N.Y. 14853, U.S.A.
D. Shah
Affiliation:
Department of Materials Science and Engineering, Cornell University, Ithaca N.Y. 14853, U.S.A.
E.P. Giannelis
Affiliation:
Department of Materials Science and Engineering, Cornell University, Ithaca N.Y. 14853, U.S.A.
Get access

Abstract

Several nylon nanocomposites was prepared using pristine and organically modified silicates. DSC and XRD reveal that the metastable γ phase is stabilized in the nanocomposites and the amount of γ phase scales with the silicate loading. Both storage and loss moduli of the nanocomposites increase with increasing silicate content. The overall characteristics of these systems become more solid-like before the onset of the glass transition. The increases in moduli are most pronounced in the rubbery regime. Pristine silicates have marginal effect on the mechanical response due to poor dispersion and/or lack of interactions with the polymer matrix.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 734: Symposia A/B – Defect-Mediated Phenomena in Ordered Polymers – Polymer/Metal Interfaces and Defect Mediated Phenomena in Ordered Polymers , 2002 , B5.10
Copyright
Copyright © Materials Research Society 2003

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1. Giannelis, E. P., “Polymer layered silicate nanocomposites”, Advanced Materials 8(1), 29 (1996)CrossRefGoogle Scholar
2. Alexandre, M., Dubois, P., “Polymer-layered silicate nanocomposites: preparation, properties and uses of a new class of materials”, Materials Science & Engineering, R: Reports 28(1–2), 1 (2000)CrossRefGoogle Scholar
3. Vaia, R. A., Giannelis, E. P., “Polymer Nanocomposites: Status and Opportunities”, MRS Bulletin 26(5), 394 (2001)CrossRefGoogle Scholar
4. Vaia, R. A., Giannelis, E. P., “Lattice Model of Polymer Melt Intercalation in Organically-Modified Layered Silicates”, Macromolecules 30(25), 7990 (1997)CrossRefGoogle Scholar
5. Singh, C., Zhulina, E., Balazs, A. C., “Modeling the interactions between organically modified clay surfaces and polymer melts”, Book of Abstracts, 216th ACS National Meeting, Boston, August 23–27 (1998)Google Scholar
6. Mathias, L. J., Davis, R. D., Jarrett, W. L., “Observation of α and γ Crystal Forms and Amorphous Regions of Nylon 6-Clay Nanocomposites Using Solid-State 15N Nuclear Magnetic Resonance”, Macromolecules 32(23) 7958 (1999)CrossRefGoogle Scholar
7. Lincoln, D. M., Vaia, R. A., Wang, Z. G., Hsiao, B. S., “Secondary structure and elevated temperature crystallite morphology of nylon-6/layered silicate Nanocomposites”, Polymer 42(4), 1621 (2000)CrossRefGoogle Scholar
8. Lincoln, D. M., Vaia, R. A., Wang, Z. G., Hsiao, B. S., Krishnamoorti, R., “Temperature dependence of polymer crystalline morphology in nylon 6/montmorillonite Nanocomposites”, Polymer 42(25), 9975 (2001)CrossRefGoogle Scholar