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Controlled Cleavage of Fully-Condensed Silsesquioxane Frameworks: A Revolutionary New Method for Manufacturing Precursors to Hybrid Inorganic/Organic Materials

Published online by Cambridge University Press:  10 February 2011

Frank J. Feher  and
Daravong Soulivong
Frank J. Feher
Affiliation:
Department of Chemistry, University of California, Irvine, CA 92697–2025, [email protected]
Daravong Soulivong
Affiliation:
Department of Chemistry, University of California, Irvine, CA 92697–2025, [email protected]
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Abstract

The reaction of readily available Cy8Si8O12 (3) with triflic acid (TfOH) can produce two different ditriflates derived from controlled cleavage of Si-O-Si linkages. These ditriflates can be subsequently hydrolyzed to four different incompletely condensed silsesquioxanes, which are attractive precursors to hybrid inorganic/organic materials.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 576: Symposium DD – Organic/Inorganic Hybrid Materials II , 1999 , 111
Copyright
Copyright © Materials Research Society 1999

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