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Combustion Chemistry of Energetic Materials Studied by Probing Mass Spectrometry

Published online by Cambridge University Press:  10 February 2011

O. P. Korobeinichev ,
L. V. Kuibida ,
A. A. Paletsky  and
A. G. Shmakov
O. P. Korobeinichev
Affiliation:
Institute of Chemical Kinetics and Combustion, Siberian Branch Russian Academy of Sciences, 630090 Novosibirsk, Russia, [email protected]
L. V. Kuibida
Affiliation:
Institute of Chemical Kinetics and Combustion, Siberian Branch Russian Academy of Sciences, 630090 Novosibirsk, Russia, [email protected]
A. A. Paletsky
Affiliation:
Institute of Chemical Kinetics and Combustion, Siberian Branch Russian Academy of Sciences, 630090 Novosibirsk, Russia, [email protected]
A. G. Shmakov
Affiliation:
Institute of Chemical Kinetics and Combustion, Siberian Branch Russian Academy of Sciences, 630090 Novosibirsk, Russia, [email protected]
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Abstract

The methods of probing mass spectrometry (PMS) for diagnostic of flames and for the study of kinetics and mechanism of the thermal decomposition products of energetic materials (EM) are described. Several types of instruments based on microprobe and molecular beam mass spectrometric sampling have been developed. Time of flight mass spectrometer has been used. Apparatuses for high (10 atm) and low (<1 atm) pressure have been developed for the study of combustion and decomposition of EM by PMS “in situ”. Several examples are presented to demonstrate application of PMS method for the study of EM flame structure, thermal decomposition and dynamic of ignition. Experimental data on decomposition of double base propellants ammonium dinitramide, ammonium perchlorate are presented.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 418: Symposium GG – Decomposition, Combustion, and Detonation Chemistry of Energetic Materials , 1995 , 245
Copyright
Copyright © Materials Research Society 1996

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References

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