Hostname: page-component-745bb68f8f-b95js Total loading time: 0 Render date: 2025-01-12T09:49:02.029Z Has data issue: false hasContentIssue false
  • English
  • Français

Combustion Chemistry of Energetic Materials Studied by Probing Mass Spectrometry

Published online by Cambridge University Press:  10 February 2011

O. P. Korobeinichev ,
L. V. Kuibida ,
A. A. Paletsky  and
A. G. Shmakov
O. P. Korobeinichev
Affiliation:
Institute of Chemical Kinetics and Combustion, Siberian Branch Russian Academy of Sciences, 630090 Novosibirsk, Russia, [email protected]
L. V. Kuibida
Affiliation:
Institute of Chemical Kinetics and Combustion, Siberian Branch Russian Academy of Sciences, 630090 Novosibirsk, Russia, [email protected]
A. A. Paletsky
Affiliation:
Institute of Chemical Kinetics and Combustion, Siberian Branch Russian Academy of Sciences, 630090 Novosibirsk, Russia, [email protected]
A. G. Shmakov
Affiliation:
Institute of Chemical Kinetics and Combustion, Siberian Branch Russian Academy of Sciences, 630090 Novosibirsk, Russia, [email protected]
Get access

Abstract

The methods of probing mass spectrometry (PMS) for diagnostic of flames and for the study of kinetics and mechanism of the thermal decomposition products of energetic materials (EM) are described. Several types of instruments based on microprobe and molecular beam mass spectrometric sampling have been developed. Time of flight mass spectrometer has been used. Apparatuses for high (10 atm) and low (<1 atm) pressure have been developed for the study of combustion and decomposition of EM by PMS “in situ”. Several examples are presented to demonstrate application of PMS method for the study of EM flame structure, thermal decomposition and dynamic of ignition. Experimental data on decomposition of double base propellants ammonium dinitramide, ammonium perchlorate are presented.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 418: Symposium GG – Decomposition, Combustion, and Detonation Chemistry of Energetic Materials , 1995 , 245
Copyright
Copyright © Materials Research Society 1996

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

1. Korobeinichev, O.P., Combustion, Explosion and Shock Waves, 23, 565 (1988).Google Scholar
2. Korobeinichev, O.P., Pure & Appl. Chem., 65 (2), 269 (1993).Google Scholar
3. Korobeinichev, O.P., Kuibida, L.V., in: Prog. Astron. and Aeron., New York, 88, (1983), p. 197–207.Google Scholar
4. Korobeinichev, O.P., Tereshchenko, A.G., Dokl. Akad. Nauk USSR, 231 (5), 1159 (1976) (in Russian).Google Scholar
5. Litzinger, T.A., Lee, Y.J., Tang, C.J., in: Application of Free-Jet. Molecular beam, Mass Spectrometric Sampling, Proceedings Workshop, Estes Park, Colorado, October 11–14, 1994, The National Renewable Energy Laboratory, 1994, p. 128–13 5.Google Scholar
6. Hanson-Parr, D., Par, T., to appear in The Proceedings of 25th International Symposium on Combustion (the Combustion Institute) (1994).Google Scholar
7. Edwards, T., paper presented at International workshop on transient combustion and stability of solid propellant, Milan, Italy, November 12–14 (1990).Google Scholar
8. Korobeinichev, O.P., Tereshchenko, A.G., Emel'ynov, I.D., Rudnitskii, A.L., Fedorov, S. Yu., Kuibida, L.V., Lotov, V.V., Fiz. Gorenia Vzryva, 21 (5), 22 (1985).Google Scholar
9. Korobeinichev, O.P., Anisiforov, G.I., Tereshchenko, A.G., AIAA Journal 13 (5), 628 (1975).Google Scholar
10. Brill, T., Prog. Energy Combust. Sci. 18, 91 (1992).Google Scholar
11. Pak, Z.. AIAA Paper. 93–1755, June 1993.Google Scholar
12. Brill, T.B., Brush, P.J. and Patil, D.G., Combustion and Flame, 92, 178 (1993).Google Scholar
13. Fetherolf, B.L. and Litzinger, T.A. in Proceeding of the 29th JANNAF Combustion Meeting (CPIA Publ., 1992), p. 329–338.Google Scholar
14. Luk'yanov, A.O., Gorelik, V.P. and Tartakovsky, V.A., Izv. Akad. Nauk., Ser Khim. 1, 94 (1994).Google Scholar