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Colloid Formation During the Interaction of HLW Glass with Interstitial Clay Water

Published online by Cambridge University Press:  03 September 2012

J. Wei  and
P. Van Iseghem
J. Wei
Affiliation:
SCK·CEN Boeretang 200, B-2400 Mol, Belgium
P. Van Iseghem
Affiliation:
SCK·CEN Boeretang 200, B-2400 Mol, Belgium
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Abstract

During the reaction of HLW glass with interstitial clay water at different temperatures with various ratios of glass surface area to solution volume (SA/V) and durations, Eu released from the glass forms predominantly Eu-humate colloids (organic colloids) by a complexation reaction. The size distribution and stability of Eu-humate colloids have been characterized. It is likely that inorganic colloids which are mainly composed of Si, Al and Ca are generated from the corrosion of waste glass by a nucleation reaction.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 465: Symposium II – Scienfific Basis for Nuclear Waste Management XX , 1996 , 269
Copyright
Copyright © Materials Research Society 1997

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References

REFERENCES

1. Kim, J.I., MRS Bulletin, XIX(11), pp. 47–56 (1994)Google Scholar
2. Kim, J.I., Treiber, W., Lierse, Ch., and Offermann, P., Mat. Res. Soc. Symp. 44, pp. 359–368 (1985)Google Scholar
3. Cunnane, J. C. and Bates, J. K., Ceram. Trans. 23, pp. 65–73 (1991)Google Scholar
4. Bates, J. K., Bradley, J. P., Teetsov, A., Bradley, C. R. and Buchholtz ten Brink, M., Science 256, pp. 649–651 (1992)Google Scholar
5. Buck, E.C., Bates, J. K., Cunnane, J. C., Ebert, W. L., Feng, X. and Wronkiewicz, D. J., Mat. Res. Soc. Symp. Proc. 287, pp. 199–208 (1993)Google Scholar
6. Feng, X., Buck, E. C., Mertz, C., Bates, J. K., Cunnane, J.C. and Chaiko, D. J., Proc. Waste Management'93, Feb. 28 to March 4, Tucson, AZ, Vol. 2, pp. 1015–1024 (1993)Google Scholar
7. Wang, L., Van Iseghem, P. and Maes, A., Mat. Res. Soc. Symp. Proc. 294, pp. 155–162 (1993)10.1557/PROC-294-155Google Scholar
8. Finn, P. A., Buck, E. C., Gong, M., Hoh, J.C., Emery, J. W., Hafenrichter, L. D. and Bates, J.K., Radiochim. Acta 66/67, pp. 181–187 (1994)Google Scholar
9. Feng, X., Buck, E. C., Mertz, M., Bates, J. K., Cunnane, J.C. and Chaiko, D. J., Radiochim. Acta 66/67, pp. 197–205 (1994)Google Scholar
10. Hart, K. P., Robinson, B. J., Payne, T. E., Van Iseghem, P. and Lemmens, K., Mat. Res. Soc. Symp. Proc. 353, pp. 841–845(1995)Google Scholar
11. Lemmens, K. and Van Iseghem, P., Mat. Res. Soc. Symp. Proc. 257, PP. 49–56 (1992)Google Scholar
12. Ebert, W. L., Physics and Chemistry of Glasses, 34 (2), pp. 58–67 (1993)Google Scholar
13. Dierckx, A., Complexation of Europium with Humic acidss, Influence of Cations and Competing Ligands. PhD thesis, Katholieke Universiteit Leuven, 1995 Google Scholar
14. Kim, J. I., Buckau, G. and Zhuang, W., Mat. Res. Soc. Symp. Proc. 84, pp. 747–756 (1987)Google Scholar
15. Dearlove, J. P. L., Longworth, G., Ivanovich, M., Kim, J. I., Delakowitz, B. and Zeh, P., Radiochim. Acta 52/53, pp. 83–89 (1991).Google Scholar
16. Wei, J. and Van Iseghem, P., The Effect of Humic Acids on the Element Release from High Level Waste Glass. These Proceedings.Google Scholar
17. Bourcier, W. L., Critical Review of Glass Performance Modeling. ANL-94/17 (1994)Google Scholar
18. Henrion, P. N., Monsecour, M., Fonteyne, A., Put, M. and De Regge, P., Radioactive Waste Management and the Nuclear Fuel Cycle, 6(3–4), pp. 313–359 (1985)Google Scholar
19. Van Iseghem, P. and Lemmens, K., Proceedings of an International Symposium on Geologic Disposal of Spent Fuel, High Level and Alpha Bearing Wastes (1992: Antwerp, Belgium), pp. 209–215 (1993)Google Scholar
20. DOE/TIC 11400, Nuclear Waste Materials Handbook, Test Methods. PNL, Richland, Washington (1981)Google Scholar
21. Kim, J. I., Radiochim. Acta 52/53, pp. 71–81 (1991)Google Scholar
22. Schnitzer, M. and Hoffmann, J., Geochimica and Cosmochimica Acta 29, pp. 859–865 (1965)Google Scholar
23. Maes, A., De Brabandere, J. and Cremers, , Radiochim. Acta 44/45, pp. 51–57 (1988)Google Scholar
24. Maes, A., De Brabandere, J. and Cremers, , Radiochim. Acta 52/53, pp. 41–47 (1991)Google Scholar
25. Dran, J. C., Lombardi, J., Magonthier, M. C., Moulin, V., Petit, J. C. and Trotignon, L., Radiochim. Acta 58/59, pp. 17–20 (1992)Google Scholar
26. Gin, S., Godon, N., Mestre, J. P., Vernaz, E. Y. and Beaufort, D., Mat. Res. Soc. Symp. Proc. 333, pp. 565–572 (1994)Google Scholar
27. Xing, S., Matlack, K. S. and Pegg, I. L., Ceram. Trans. 39, pp. 353–365 (1994)Google Scholar
28. Choppin, G. R., Radiochim. Acta 44/45, pp. 23–28 (1988)Google Scholar
29. Moulin, V. and Stammose, D., Mat. Res. Soc. Symp. Proc. 127, pp. 723–727 (1989)Google Scholar
30. Righetto, L., Bidoglio, G., Marcandalli, B. and Bellobono, I.R., Radiochim. Acta 44/45, pp. 73–75 (1988)Google Scholar
31. Ledin, A., Karlsson, S., Duker, A. and Allard, B., Radiochim. Acta 66/67, pp. 213–220(1994)Google Scholar
32. Dierckx, A., Maes, A. and Vancluysen, J., Radiochim. Acta 66/67, pp. 149–156 (1994)Google Scholar