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Published online by Cambridge University Press: 22 February 2011
The effects of 1 to 5 keV Ar+ sputtering of (100) GaAs doped with >3 × 1018 cm−3 or <2 × 1017 cm−3 Si and contacted with 1000 Å of Au have been studied. Sputtering caused the contacts on highly doped GaAs to change from ohmic to rectifying, while it caused the Schottky barrier height on moderately doped GaAs to decrease. For both doping densities, barrier heights of ∼0.6 eV were measured. Inverse Laplace transform analysis of angle-resolved X-ray photoelectron spectroscopy data showed that As was preferentially sputtered, probably by a damage-assisted Gibbsian surface segregation mechanism. Modifications of the electrical contacts were explained by sputter-induced self-compensation by Si rearrangement and by damage-created shallow donors with a density of >2 × 1017 cm−3.