Hostname: page-component-78c5997874-xbtfd Total loading time: 0 Render date: 2024-11-12T22:19:20.462Z Has data issue: false hasContentIssue false
  • English
  • Français

Ceramic Processing using Inorganic Polymers

Published online by Cambridge University Press:  21 February 2011

John J. Lannumti ,
Christopher H. Schilling  and
Ilhan A. Aksay
John J. Lannumti
Affiliation:
Department of Materials Science and Engineering, and Advanced Materials Technology Program, Washington Technology Center University of Washington, Seattle, WA 98195
Christopher H. Schilling
Affiliation:
Pacific Northwest Laboratory, Richland, WA 99352
Ilhan A. Aksay
Affiliation:
Department of Materials Science and Engineering, and Advanced Materials Technology Program, Washington Technology Center University of Washington, Seattle, WA 98195
Get access

Abstract

Inorganic polymers are used in the formation of green compacts via sedimentation of colloidal alumina suspended in chloroform. Polymers containing highly polar components tend to produce constant density profiles of greater than 55% density, while those containing nonpolar, reactive components produce profiles with a large gradient in packing density. Density profiles describing the sedimentation behavior versus time and the final dried density of the compacts are generated via the use of gamma-ray densitometry. These polymers have the potential not only to increase green compact density but also to reduce weight losses due to “burnout” and subsequent sintering requirements by pyrolyzing to a ceramic phase.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 155: Symposium L – Processing Science of Advanced Ceramics , 1989 , 155
Copyright
Copyright © Materials Research Society 1989

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1. Reed, J. S., in Ceramic Transactions, Vol. I, Ceramic Powder Science II, edited by Messing, G. L., Fuller, E. R., and Hausner, H., (American Ceramic Society, Westerville, OH, 1988), p. 601.Google Scholar
2. Silicon Compounds, Petrarch Systems (1987), p. 275.Google Scholar
3. Lannutti, J. J. and Aksay, I. A., to be submitted to the J. Am. Ceram. Soc.Google Scholar
4. Gallagher, D. G., Ph. D. Thesis, University of Washington, Seattle (1988).Google Scholar
5. Schilling, C. H., Graff, G. L., Samuels, W. D., and Aksay, I. A., in Atomic and Molecular Processing of Electronic and Ceramic Materials: Preparation, Characterization, and Properties, edited by Aksay, I. A., McVay, G. L., Stoebe, T. G., and Wager, J. F. (Mater. Res. Soc. Symp. Proc., Pittsburgh, PA 1987), pp. 239–51.Google Scholar
6. Stroosnijder, L. and Swart, J. G. De, Soil Science 118, 61 (1974).Google Scholar
7. Nofziger, D. L. and Swartzendruber, D., J. Appl. Phys. 45, 5443 (1974).Google Scholar
8. Mayes, D. M. and Callis, J. B., Appl. Spect. 43, 27 (1989).Google Scholar
9. Weyer, L. G., Appl. Spect. Rev. 21, 1 (1985).Google Scholar
10. Wheeler, O. H., Chem. Rev. 59, 629 (1959).Google Scholar
11. Schreiber, L. B. and Vaughan, R. W., J. Catal. 40, 226 (1975).Google Scholar
12. Exarhos, G. J., Ferris, K. F., Friedrich, D. M., and Samuels, W. D., J. Am. Ceram. Soc. 71 C–406 (1988).Google Scholar
13. Perrin, D. D. and Armarego, W. L. F., Purification of Laboratory Chemicals, 3rd ed., (Pergamon Press, New York, 1988), p. 121.Google Scholar
14. Dawkins, J. V. and Taylor, G., Polymer 20, 599 (1979).Google Scholar
15. Christenson, H. K., Horn, R. G., and Israelachvili, J. N., J. Colloid Interface Sci. 88, 79 (1982); H. K. Christenson, J. Colloid Interface Sci. 104, 234 (1985).Google Scholar
16. Yeh, T. and Sacks, M. D., J. Am. Ceram. Soc. 71, 841 (1988).Google Scholar