Hostname: page-component-586b7cd67f-t7fkt Total loading time: 0 Render date: 2024-11-28T11:27:21.675Z Has data issue: false hasContentIssue false

Transferwear During Cu CMP

Published online by Cambridge University Press:  01 February 2011

H. Liang
Affiliation:
University of Alaska Fairbanks
G. Helen Xu
Affiliation:
University of Alaska Fairbanks
J.M. Martin
Affiliation:
Ecole Central de Lyon
Th. Le Mongne
Affiliation:
Ecole Central de Lyon
Get access

Extract

We conducted fundamental investigation of interfacial interactions between copper and polyurethane surfaces. Using in situ surface analysis techniques we were able to evaluate effects of water molecules on both materials surfaces during rubbing. Evidence of transferring elements between copper and urethane surfaces due to friction was found. Further investigation on pad wear indicated that transfer wear was taking a major role during copper CMP and mixed wear modes dominated pad wear.

Type
Research Article
Copyright
Copyright © Materials Research Society 2003

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

1 Kaufman, F. B. Thompson, D. B. Broadie, R. E. Jaso, M. A. Gutherie, W. L. Pearson, D. J. and Small, M. B.Chemical-Mechanical Polishing for Fabricating Patterned W Metal Features as Chip Interconnects,” J. Electrochem. Soc., 138, p.3460 (1991).Google Scholar
2 Stein, D. Hetherington, d. Guilinger, T., and Cecchi, J.In Situ Electrochemical Investigation of Tungsten Electrochemical Behavior during Chemical Mechanical Polishing,” J. Eletrochem. Soc., 145, p.3190 (1998).Google Scholar
3 Larsen-Basse, J. and Liang, H.Probable Roles of Abrasive Particles in W CMP,” Wear, 233-235, p.647 (1999).Google Scholar
4 Liang, H. Martin, J.M. , Beatrice, and Brusic, V.Experimental Investigation of Cu CMP,” MRS Proceeding, 2000.Google Scholar
5 Liang, H. Lee, R. and Martin, J.M. “Copper Oxides during CMP,” J. Elec. Soc., April, 2001.Google Scholar
6 Liang, H. and Xu, H. “Lubricating Behavior of Copper CMP“, presented at the STLE 2001 annual meeting, May, 2001, Orlando, Fl.Google Scholar
7 Xu, G. H. and Liang, H. “Tribological Behavior of Copper Chemical-Mechanical Polishing,” Proc. 6th Int. Conf. Solid-State & IC Tech., Oct. 22-25, 2001, Shanghai, China, pp. 851854.Google Scholar
8 Liang, H. and Xu, G.H. “Anti-Lubrication Behavior of Cu CMP,” Proceedings of 8th Int. VMIC, Sept. 25-26, 2001, Santa Clara, CA, 2001, pp.137140.Google Scholar
9 Liang, H. and Xu, G.Lubricating Behavior in Chemical-Mechanical Polishing of Copper,” Scripta Materialia, Vol. 46, No. 5, 2002, pp.343347.Google Scholar
10 Fischer, T.Tribochemistry,” Ann. Rev. Mater. Sci. 18, pp. 303308, 1988.Google Scholar
11 Martin, J.M.Antiwear Mechanisms of Zinc Dithiophosphate: a Chemical Hardness Approach,” Tribology Letters, Vo. 6, p.1, (1999).Google Scholar
12 Dickinson, J.T. Park, N.-S., Kim, M-W., and Langford, S.C.A Scanning Force Microscope Study of a Tribochemical System: Stress-Enhanced Dissolution,” Trib. Lett. 3, p.69 (1997).Google Scholar
13 Martin, J. M. Mogne, Th. Le, Grossiord, C. and Palermo, Th., “Tribochemistry in the Analytical UHV Tribometer,” Trib. Let., 3, p.87 (1997).Google Scholar
14 Liang, H. Mogne, T.L. and Martin, J.M.Interfacila Transfer between Copper and Polyurethane in Chemical-Mechanical Polishing.” J. Electronic Matls., Vol.31, No.8, p.872 (2002).Google Scholar
15 Oung, J. Lee, J. and Liang, H.Modeling of Polyurethane as CMP Pads,” J. of CMP, 1, 2000, pp.323335.Google Scholar
16 Liang, H. and Lee, J. “Influence of Microstructure and Mechanical Properties of Polishing Pads on CMP,” Proceedings of 5th International Conference on CMP for ULSI Multilevel Interconnection (CMP-MIC), March 2-3, 2000, Santa Clara, pp.206214.Google Scholar
17 Briscoe, B.J. and Tabor, D. in Fundamentals of Tribology, edSuh, s. N. and Saka, N. (MIT Press, Cambridge, Mass, 1980).Google Scholar
18 Buckley, D.H. in Advances in Polymer Friction and Wear, ed. Lee, H.H. (Plenum Press, New York, 1974).Google Scholar
19 Dawson, D. Challen, J.M. Holmes, K. and Atkinson, J.R. in The Wear of Non-Metallic Materials, Dowson, D. eds. Godet, M. and Taylor, C.M. (Mechanical Engineering Publ., London, 1976).Google Scholar
20 Eiss, N.S. and Warren, J.H. Paper No. IQ75-125, (SME, Detroit, Mich., 1975).Google Scholar