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Thermoelectric Properties of Composite PbTe – PbSnS2 Materials

Published online by Cambridge University Press:  01 February 2011

Steven N Girard ,
Jiaqing He ,
Vinayak P Dravid  and
Mercouri Kanatzidis
Steven N Girard
Affiliation:
[email protected], Northwestern University, Chemistry, 2145 Sheridan Rd., Evanston, Illinois, 60208-3113, United States
Jiaqing He
Affiliation:
[email protected], Northwestern University, Materials Science and Engineering, Evanston, Illinois, United States
Vinayak P Dravid
Affiliation:
[email protected], Northwestern University, Materials Science and Engineering, Evanston, Illinois, United States
Mercouri Kanatzidis
Affiliation:
[email protected], Northwestern University, Chemistry, Evanston, Illinois, United States
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Abstract

The thermoelectric (Pb1-mSnmTe)1-x(PbS)x where m = 0.05 and x = 0.08 has been shown to produce PbS nanostructures that effectively scatter phonons, enhancing ZT. As Sn substitution is increased, a new phase of PbSnS2 precipitates. We find that incorporation of PbSnS2 in PbTe results in a significant reduction in lattice thermal conductivity around 0.6 W/mK at room temperature. We present preliminary characterization and thermoelectric properties.

Keywords

thermoelectricnanostructurethermal conductivity
Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 1267: Symposium DD – Thermoelectric Materials 2010-Growth, Properties, Novel Characterization Methods and Applications , 2010 , 1267-DD06-09
Copyright
Copyright © Materials Research Society 2010

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References

1 Vining, C. B. Nat. Mater. 8, 83 (2009).Google Scholar
2 Sootsman, J. R. Chung, D. Y. and Kanatzidis, M. G. Angew. Chem. Int. Ed. 48, 8616 (2009).Google Scholar
3 Kanatzidis, M. G. Chem. Mater. 22, 648 (2009).Google Scholar
4 Venkatasubramanian, R. Siivola, E. Colpitts, T. and O'Quinn, B., Nature 413, 597 (2001).Google Scholar
5 Li, D. Wu, Y. Fan, R. Yang, P. and Majumdar, A. Appl. Phys. Lett. 83, 3186 (2003).Google Scholar
6 Dresselhaus, M. S. Chen, G. Tang, M. Y. Yang, R. G. Lee, H. Wang, D. Z. Ren, Z. F. Fleurial, J. P. and Gogna, P. Adv. Mater. 19, 1043 (2007).Google Scholar
7 Androulakis, J. Lin, C. H. Kong, H. J. Uher, C. Wu, C. I., Hogan, T. Cook, B. A. Caillat, T. Paraskevopoulos, K. M. and Kanatzidis, M. G. J. Am. Chem. Soc. 129, 9780 (2007).Google Scholar
8 Orihashi, M. Noda, Y. Chen, L. D. Goto, T. and Hirai, T. J. Phys. Chem. Solids 61, 919 (2000).Google Scholar
9 Hayashi, K. Kitakaze, A. and Sugaki, A. Mineral. Mag. 65, 645 (2001).Google Scholar
10 Chang, L. L. Y. and Brice, W. R. W. R., Mineral. Mag. 38, 186 (1971).Google Scholar