Hostname: page-component-78c5997874-lj6df Total loading time: 0 Render date: 2024-11-09T22:58:13.142Z Has data issue: false hasContentIssue false
  • English
  • Français

Synthesis of New Multifunctional Polymers inCorporating BIS-(Diphenylamino)Diphenylpolyene Moieties

Published online by Cambridge University Press:  10 February 2011

C. W. Spangler ,
T. Faircloth ,
E. H. Elandaloussi  and
B. Reeves
C. W. Spangler
Affiliation:
Department of Chemistry and Biochemistry, Montana State University, Bozeman, MT 59717, [email protected]
T. Faircloth
Affiliation:
Department of Chemistry and Biochemistry, Montana State University, Bozeman, MT 59717, [email protected]
E. H. Elandaloussi
Affiliation:
Department of Chemistry and Biochemistry, Montana State University, Bozeman, MT 59717, [email protected]
B. Reeves
Affiliation:
Department of Chemistry and Biochemistry, Montana State University, Bozeman, MT 59717, [email protected]
Get access

Abstract

A series of bis-(diphenylamino)diphenylpolyenes containing up to eight double bonds has been synthesized, both as parent model compounds, and functionalized for attachment as pendant chromophores. Oxidative doping of these new materials yields exceptionally stable bipolaronlike dications, even at the triene level. These new materials show promise as bimechanistic optical limiters by reverse saturable absorption and by 2-photon absorption.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 488: Symposium J – Electrical, Optical & Magnetic Properties of Organic IV , 1997 , 283
Copyright
Copyright © Materials Research Society 1998

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

1. Spangler, C.W., Sapochak, L.S. and Gates, B.D. in Organic Materials for Non-Linear Optics, edited by Hahn, R. and Bloor, D. (Roy. Soc. Chem. Spec. Pub. # 69, London, 1989) pp. 57–62.Google Scholar
2. Spangler, C.W. and Rathunde, R., J. Chem. Soc. Chem. Commun. 1969, 26.Google Scholar
3. Spangler, C.W. and Hall, T.J., Synthetic Met. 44, 85 (1991).Google Scholar
4. Spangler, C.W. and Liu, P.-K., J. Chem. Soc. Perk. Trans. 1 1992, 1959.Google Scholar
5. Spangler, C.W. and He, M.Q., J. Chem. Soc. Perk. Trans. 2 1995, 715.Google Scholar
6. Fromer, J.E. and Chance, R.R. in Electrical and Electronic Properties of Polymers, A State of the Art Compendium, edited by Kroschwitz, J.I. (John Wiley Publishers, New York, 1998) pp. 56–101.Google Scholar
7. Spangler, C.W., He, M.Q., Laquindanum, J., Dalton, L., Partanen, J.P. and Hellwarth, R. in Electrical, Optical, and Magnetic Properties of Organic Solid State Materials, edited by Garito, A., Jen, A.K.-Y., Lee, C.Y.-C. and Dalton, L.R. (Mater. Res. Soc. Proc. 328, Pittsburgh, PA, 1994) pp. 655–660.Google Scholar
8. Nickel, E.G., Spangler, C.W., Tang, N., Hellwarth, R. and Dalton, L., Nonlinear Optics, 6, 135 (1993).Google Scholar
9. deMelo, C.P. and Silbey, R., Chem. Phys. Lett. 140, 537 (1987).Google Scholar
10. deMelo, C.P. and Silbey, R., Chem. Phys. Lett. 88, 2567 (1988).Google Scholar
11. Tang, N., Partanen, J., Hellwarth, R., Laquindanum, J., Dalton, L., Spangler, C.W. and He, M.Q. in Nonlinear Properties of Organic Materials VII, edited by Möhlrmann, G.R. (Proc. SPIE, Bellingham, WA, 1994) pp. 186–192.Google Scholar
12. Spangler, C.W., Havelka, K.O., Liu, P.-K., Nickel, E.G., Polis, D., Sapochak, L.S. and Dalton, L.R. in Frontiers of Polymer Research, edited by Prasad, P.N. and Nigam, J.K. (Plenum Press, New York, 1991) pp. 149–156.Google Scholar
13. Spangler, C.W., Liu, P.-K., Hall, T.J., Polis, D., Sapochak, L. and Dalton, L.R., Polymer, 33, 3937 (1992).Google Scholar
14. Spangler, C.W. and He, M.Q. in Electrical, Optical, and Magnetic Properties of Organic Solid State Materials III, edited by Jen, A.K.-Y., Lee, C.Y.-C., Dalton, L.R., Rubner, M.F., Wnek, G.E. and Chiang, L.Y. (Mater. Res. Soc. Proc. 413, Pittsburgh, PA, 1996). Pp. 221–229.Google Scholar
15. Spangler, C.W., McCoy, R.K., Dembek, A.A., Sapochak, L.S. and Gates, B.D., J. Chem. Soc. Perk. Trans. 1 1989, 151.Google Scholar
16. Casstevens, M.K., Burzynski, R., Weibel, J.F., Spangler, C., He, G. and Prasad, P.N. in Nonlinear Optical Liquids and Power Limiters, (Proc. SPIE, Bellingham, WA, 1997) pp. 152–159.Google Scholar
17. Beljone, D., Brédas, J.-L., Cumpston, B.H., Erlich, J., Erskine, L., Heikal, A.A., Hu, Z.-Y., Kogej, T., Lee, I.-Y.S., Marder, S.R., Perry, J.W., Röckel, H., Thayumanavan, S. and Wu, X.-L., Polym. Preprints, 38(2), 497 (1997).Google Scholar
18. Natarajan, L., Sowards, A., Tang, N., Fleitz, P., Sutherland, R., Cooper, T. and Spangler, C. in Materials for Optical Limiting II (Mater. Res. Soc. Proc. 479, Pittsburgh, PA, 1997) (in press).Google Scholar