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Some Transition Ions in Heavy Metal Fluoride Glasses

Published online by Cambridge University Press:  25 February 2011

L. D. Bogomolova
Affiliation:
Institute of Nuclear Physics, Moscow State University, Moscow 119889, USSR
F. Caccavale
Affiliation:
Institute of Nuclear Physics, Moscow State University, Moscow 119889, USSR
N. A. Krasil'nikova
Affiliation:
Institute of Nuclear Physics, Moscow State University, Moscow 119889, USSR
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Abstract

The heavy metal fluoride glasses (HMFG) have attracted considerable attention in recent years because of their unusual physical and chemical properties which allow potential use in numerous electrical and optical applications. The HMFG are transparent over a wide range of the optical spectrum (from 220 nm to 8,μ) and have sufficient chemical stability to make them a suitable optical material middle IR fibers optics. Their high anionic conductivity permits their application as solid electrolytes. They are also of interest scientifically since their structure is different from that of other inorganic glasses. The high coordination number of the network formers ions is the principal structural peculiarity of the HMFG.

Type
Research Article
Copyright
Copyright © Materials Research Society 1987

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References

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