Hostname: page-component-78c5997874-j824f Total loading time: 0 Render date: 2024-11-03T02:41:36.060Z Has data issue: false hasContentIssue false
  • English
  • Français

Radiation Tolerance of A2Ti2O7 Materials - A Question of Bonding?

Published online by Cambridge University Press:  19 October 2011

Karl Whittle ,
Gregory R Lumpkin ,
Katherine L Smith ,
Mark G Blackford ,
Elizabeth J Harvey  and
Nestor J Zaluzec
Karl Whittle
Affiliation:
[email protected], University of Sheffield, Department of Engineering Materials, Sir Robert Hadfield Building, Mappin Street, Sheffield, S1 3JD, United Kingdom
Gregory R Lumpkin
Affiliation:
[email protected], Australian Nuclear Science and Technology Organisation, Sydney, NSW 2234, Australia
Katherine L Smith
Affiliation:
[email protected], Australian Nuclear Science and Technology Organisation, Sydney, NSW 2234, Australia
Mark G Blackford
Affiliation:
[email protected], Australian Nuclear Science and Technology Organisation, Sydney, NSW 2234, Australia
Elizabeth J Harvey
Affiliation:
[email protected], University of Cambridge, Cambridge, CB2 3EQ, United Kingdom
Nestor J Zaluzec
Affiliation:
[email protected], Argonne National Laboratory, Chicago, IL, 60439, United States
Get access

Abstract

The resistance of Ln2Ti2O7 (Ln=lanthanide) compounds to radiation damage is an important topic in the understanding and development of new materials by which radioactive nuclear waste can safely be immobilised. A model has been developed, from previously published density functional theory and molecular orbital theory simulations of the band structure for Ln2Ti2O7 materials. This model provides a chemical interpretation of radiation stability.

Keywords

radiation effectsion-implantationcrystalline
Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 985: Symposium NN – Scientific Basis for Nuclear Waste Management XXX , 2006 , 0985-NN09-02
Copyright
Copyright © Materials Research Society 2007

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1. Lumpkin, G. R., Whittle, K. R., Rios, S., Smith, K. L. and Zaluzec, N. J., Journal Of Physics- Condensed Matter, 16, 8557–8570, (2004).Google Scholar
2. Schmalle, H. W., Williams, T., Reller, A., Linden, A. and Bednorz, J. G., Acta Crystallographica Section B-Structural Science, 49, 235–244, (1993).Google Scholar
3. Ishizawa, N., Marumo, F., Iwai, S., Kimura, M. and Kawamura, T., Acta Crystallographica Section B-Structural Science, 38, 368–372, (1982).Google Scholar
4. Chakoumakos, B. C., Journal of Solid State Chemistry, 53, 120–129, (1984).Google Scholar
5. Subramanian, M. A., Aravamudan, G. and Rao, G. V. S., Progress in Solid State Chemistry, 15, 55–143, (1983).Google Scholar
6. Lian, J., Ewing, R. C., Wang, L. M. and Helean, K. B., Journal of Materials Research, 19, 1575–1580, (2004).Google Scholar
7. Ewing, R. C., Lian, J. and Wang, L. M. in Radiation Effects and Ion Beam Modification of Materials, edited by Wang, L. M., Fromknecht, R., Snead, L. L., Downey, D. F., Takahashi, H., (Mater. Res. Soc. Symp. Proc. 792, Materials Research Society, 2004) pp.37–48 Google Scholar
8. Wang, S. X., Wang, L. M., Ewing, R. C. and Govindana Kutty, K. V. in Microstructural Processes in Irradiated Materials, edited by Zinkle, S. J., Lucas, G. E., Ewing, R. C., Williams, J. S., (Mater. Res. Soc. Symp. Proc. 540, Materials Research Society, 1999) pp.355–360 Google Scholar
9. Wang, S. X., Wang, L. M., Ewing, R. C. and Kutty, K. V. G., Nuclear Instruments & Methods in Physics Research Section B- Beam Interactions with Materials and Atoms, 169, 135–140, (2000).Google Scholar
10. Smith, K. L., Blackford, M. G., Lumpkin, G. R., Whittle, K. R. and Zaluzec, N. J., Microscopy and Microanalysis, 12 (Supp 2), 1094–1095, (2006).Google Scholar
11. Lian, J., Chen, J., Wang, L. M., Ewing, R. C., Farmer, J. M., Boatner, L. A. and Helean, K. B., Physical Review B, 68, 134107, (2003).Google Scholar
12. Lumpkin, G. R., Pruneda, J. M., Rios, S., Smith, K. L., Trachenko, K., Whittle, K. R. and Zaluzec, N. J., Journal Of Solid State Chemistry, (2007).Google Scholar
13. Hwang, D. W., Lee, J. S., Li, W. and Oh, S. H., Journal Of Physical Chemistry B, 107, 4963–4970, (2003).Google Scholar
14. Nemoshkalenko, V. V., Borisenko, S. V., Uvarov, V. N., Yaresko, A. N., Vakhney, A. G., Senkevich, A. I., Bondarenko, T. N. and Borisenko, V. D., Physical Review B, 63, 075106, (2001).Google Scholar
15. Panero, W. R., Stixrude, L. and Ewing, R. C., Physical Review B, 70, 054110, (2004).Google Scholar