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Proton Conducting Organic/Inorganic Nanocomposite Polymer Electrolytic Membrane Synthesized by Sol-Gel Process

Published online by Cambridge University Press:  21 February 2011

I. Honma ,
S. Nomura  and
H. Nakajima
I. Honma
Affiliation:
Energy Fundamental Division, Electrotechnical Laboratory, AIST, mezono, sukuba, baraki, 05-8568, Japan, [email protected]
S. Nomura
Affiliation:
Minase Research Institute, Sekisui Chemical Co., Ltd., saka 618-8589, Japan
H. Nakajima
Affiliation:
Energy Fundamental Division, Electrotechnical Laboratory, AIST, mezono, sukuba, baraki, 05-8568, Japan
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Abstract

In this paper, new synthetic routes have been investigated for the preparation of Organic/inorganic nanocomposite polymer membranes consisting of SiO2 /PTMO(polytetramethylene oxide) hybrids and novel proton conducting materials. These materials have been synthesized through sol-gel processes in flexible, ductile, free-standing thin membrane form. The hybrid membrane has been found to be thermally stable up to 160 C and possesses proton conductivities of approximately 10−4 S/cm from a room temperature to 160 C.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 581: Symposium F – Nanophase & Nanocomposite Materials II , 1999 , 381
Copyright
Copyright © Materials Research Society 2000

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References

REFERENCES

1. Depre, L., Kappel, J. and Popall, M., Electrochimica Acta, 43, 1301 (1998)Google Scholar
2. Popall, M. and Durand, H., Electrochimica Acta, 37, 1593 (1992)Google Scholar
3. Croce, F., Appetecchi, G.B., Persi, L. and Scrosati, B., Nature, 394, 456 (1998)Google Scholar
4. Goward, G.R., Leroux, F. and Nazar, L.F., Electrochimica Acta, 43, 1307 (1998)Google Scholar
5. Sanchez, J-Y., Denoyelle, A. and Poinsignon, C., Polymers for Advanced Technologies, 4, 99 (1993)Google Scholar
6. Gautier-Luneau, I., Denoyelle, A., Sanchez, J.Y. and Poinsignon, C., Electrochimica Acta, 37, 1615 (1992)Google Scholar
7. Charbouillot, Y., Ravaine, D., Armand, M. and Poinsignon, C., J. Non-Crystalline Solids, 103, 325 (1988)Google Scholar
8. Vaivars, G., Kleperis, J., Azens, A., Granqvist, C.G. and Lusis, A., Solid State Ionics, 97, 365 (1997)Google Scholar
9. Honma, I., Hirakawa, S., Yamada, K. and Bae, J.M., Solid State Ionics, 118, 29 (1998)Google Scholar
10. Honma, I., Hirakawa, S. and Bae, J.M. Proceeding MRS Fall meeting, Nov.30, 1998 Boston MA, USA Google Scholar
11. Honma, I., Hirakawa, S. and Bae, J.M., Proc. Electrochemical Society 194th meeting, Nov. 4. 1998 Boston MA, USA Google Scholar
12. Bae, J.M., Hirakawa, S. and Honma, I. Proc. IUMRS-ICEM, August 25, 1998 Cheju Island, Korea Google Scholar
13. Nakamura, O., Kodama, T., Ogino, I. and Miyake, Y., Chem. Lett. 1979, 17 Google Scholar
14. Tatsumisago, M., Honjo, H., Sakai, Y. and Minami, T., Solid State Ionics, 74, 105 (1994)Google Scholar
15. Moic, U.B., Milonjic, S.K., Malovic, D., Stamenkovic, V., Colomban, Ph., Mitrovic, M.M., Dimitrijevic, R., Solid State lonics 97, 239 (1997)Google Scholar
16. Honma, I., Takeda, Y. and Bae, J.M., Solid State lonics, 120, 255 (1999)Google Scholar
17. England, W.A., Cross, M.G., Hamnett, A., Wiseman, P.J. and Goodenough, J.B., Solid State Ionics, 1, 231 (1980)Google Scholar
18. Kreuer, K.D., Solid State Ionics, 94, 55 (1997)Google Scholar
19. Kreuer, K.D., Fuchs, A., Ise, M., Spaeth, M. and Maier, J., Electrochimica Acta, 43, 1281 (1998)Google Scholar
20. Sone, Y., Kishimoto, A. and Kudo, T., Solid State Ionics, 66, 53 (1993)Google Scholar