Hostname: page-component-586b7cd67f-t8hqh Total loading time: 0 Render date: 2024-11-28T14:18:00.707Z Has data issue: false hasContentIssue false
  • English
  • Français

Proton and Mixed Conductors for Dual Membrane Fuel Cells

Published online by Cambridge University Press:  30 August 2011

Massimo Viviani ,
Sabrina Presto ,
Antonio Barbucci ,
Maria P. Carpanese ,
Roberta Amendola ,
Alain S. Thorel ,
Anthony Chesnaud ,
Joao Abreu ,
Remi Costa  and
Zeynep Ilhan
...Show all authors
Massimo Viviani
Affiliation:
Institute for Energetics and Interphases, CNR, Via De Marini 6, 16149 Genova, Italy
Sabrina Presto
Affiliation:
Institute for Energetics and Interphases, CNR, Via De Marini 6, 16149 Genova, Italy
Antonio Barbucci
Affiliation:
Institute for Energetics and Interphases, CNR, Via De Marini 6, 16149 Genova, Italy DiCheP, University of Genoa, P. le Kennedy 1, 16129 Genova, Italy
Maria P. Carpanese
Affiliation:
Institute for Energetics and Interphases, CNR, Via De Marini 6, 16149 Genova, Italy DiCheP, University of Genoa, P. le Kennedy 1, 16129 Genova, Italy
Roberta Amendola
Affiliation:
Institute for Energetics and Interphases, CNR, Via De Marini 6, 16149 Genova, Italy
Alain S. Thorel
Affiliation:
Centre Matériaux, Mines-ParisTech, BP87, Evry Cedex 91003, France.
Anthony Chesnaud
Affiliation:
Centre Matériaux, Mines-ParisTech, BP87, Evry Cedex 91003, France.
Joao Abreu
Affiliation:
Centre Matériaux, Mines-ParisTech, BP87, Evry Cedex 91003, France.
Remi Costa
Affiliation:
Centre Matériaux, Mines-ParisTech, BP87, Evry Cedex 91003, France. German Aerospace Center (DLR-ITT), Pfaffenwaldring 38-40, Stuttgart D-70569, Germany
Zeynep Ilhan
Affiliation:
German Aerospace Center (DLR-ITT), Pfaffenwaldring 38-40, Stuttgart D-70569, Germany
Sayed-Asif Ansar
Affiliation:
German Aerospace Center (DLR-ITT), Pfaffenwaldring 38-40, Stuttgart D-70569, Germany
Daria E. Vladikova
Affiliation:
Institute of Electrochemistry and Energy Systems-BAS, 10 Acad. G. Bonchev, 1113 Sofia, Bulgaria
Zdravko B. Stoynov
Affiliation:
Institute of Electrochemistry and Energy Systems-BAS, 10 Acad. G. Bonchev, 1113 Sofia, Bulgaria
Get access

Abstract

This paper presents results for the conductivity of BaCe0.85Y0.15O2-δ (BCY15) measured by electrochemical impedance spectroscopy in wet hydrogen and in Air, as well as test results from the application of the material in a new dual membrane fuel cell configuration (“IDEAL Cell”), in which the water is produced and evacuated through a separate chamber. The conductivity of dense BCY15 in wet hydrogen atmosphere at 700 °C is 2.0 10-2 S/cm. The measured values in air are of the same order. Preliminary tests of the material in the new cell design, where the three types of conductivity (protonic, oxide ion and mixed) are used in different cell compartments, are successfully performed.

Keywords

ionic conductoroxideenergetic material
Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 1330: Symposium J – Protons in Solids , 2011 , mrss11-1330-j05-04
Copyright
Copyright © Materials Research Society 2011

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1. Iwahara, H., Uchida, H., Ogaki, K., J. Electrochem. Soc. 135(2) (1988) 529 Google Scholar
2. Iwahara, H., Solid State Ionics 168 (2004) 299 Google Scholar
3. Iwahara, H., Asakura, Y., Katahira, K., Tanaka, M. Solid State Ionics 28–30 (1988) 573 Google Scholar
4. Bonanos, N., Knight, K.S., Ellis, B., Solid State Ionics 79 (1955) 161 Google Scholar
5. Suksamai, W., Metcalfe, I.S., Solid State Ionics 178 (2007) 6276 Google Scholar
6. Malavasi, L., Fisher, C.A.J., Islam, M.S., Chem. Soc. Rev. 39 (2010) 4370 Google Scholar
7. Ishihara, T., Sammes, N.M., Yamamoto, O. in High Temperature Solid Oxide Fuel Cells: Fundamentals, Design and Applications, edited by Singhal, S.C. and Kendall, K., (Elsevier, 2003) pp. 83–117 Google Scholar
8. Iwahara, H., Solid State Ionics 86 – 88 (1996) 9 Google Scholar
9. Kreuer, K.D., Annu. Rev. Mater. Res. 33 2003, 333 Google Scholar
10. Bassano, A., Buscaglia, V., Viviani, M., Bassoli, M., Buscaglia, M-T., Sennour, M., Thorel, A. and Nanni, P., Solid State Ionics 180 (2009) 168 Google Scholar
11. Knight, K.S, Solid State Ionics, 2000, 127, 43 Google Scholar
12. Thorel, S., Chesnaud, A., Viviani, M., Barbucci, A., Presto, S., Piccardo, P., Ilhan, Z., Vladikova, D. E., Stoynov, Z., in Solid Oxide Fuel Cells 11 (SOFCXI), edited by Singhal, S.C., and Yokokawa, H., (The Electrochemical Society Proceedings Series, 25, ECS Transactions, 2009), pp.753–762 Google Scholar
13. Patent N° 0550696000, March 17th, 2005, Cellule de pile a combustible haute temperature a conduction mixte anionique et protonique ; International extension in 2006 Issue 2, Pennington, NJ (2009) 753.Google Scholar
14. Vladikova, D., Stoynov, Z., Raikova, G., Thorel, A., Chesnaud, A., Abreu, J., Viviani, M., Barbucci, A., Presto, S., Carpanese, P., Electrochim. Acta– in press Google Scholar
15. Guan, J.; Dorris, S.E.; Balachandran, U.; Liu, M., Journal of the Electrochemical Society, 1998, 145(5), p. 1780 Google Scholar
16. Norby, T., Solid State Ionics, 1999, 125, p. 1–11 Google Scholar
17. Bae, J.S.; Choo, W.K.; Lee, C. H. Journal of the European Ceramic Society, 2001, 21, p.1779–1782 Google Scholar
18. Haile, S.M., West, D.L., Campbell, J., Journal of Materials Research, 1998, 13(6), p. 1576–1595 Google Scholar
19. Iwahara, H., Yajima, T., Ushida, H., Solid State Ionics, 1994, 70–71, p. 267–271 Google Scholar
20. Coors, W.G., J. Electrochem.Soc. 151 (2004 A994 Google Scholar
21. Coors, W.G., Solid State Ionics, 2007, 178, 481 Google Scholar
22. Bonanos, N., J. Phys. Chem. Solids, 54 (19930 867 Google Scholar
23. Caboche, G., Hochepied, J.-F., Piccardo, P., Przybylski, K., Ruckdäschel, R., Ardigó, M.-R., Fatome, E., Chevalier, S., Perron, A., Combemale, L., Palard, M., Prazuch, J., Brylewski, T., Compatibility and reactivity between materials in an Innovative Dual mEmbrAne fueL-Cell (IDEAL-Cell) design, in Solid Oxide Fuel Cells 11 (SOFCXI) , edited by Singhal, S.C., and Yokokawa, H., (The Electrochemical Society Proceedings Series, 25, ECS Transactions, 2009), pp. 763–772.Google Scholar
24. Chiodelli, G., Malavasi, L., Tealdi, C., Barison, S., Battagliarin, M., Doubova, L., Fabrizio, M., Mortalo, C., Gerbasi, R., Journal of Alloys and Compounds, 470, 477 (2009)Google Scholar
25. Stoynov, Z., Vladikova, D., in: Garche, U. (Ed.) Encyclopedia of Electrochemical Power Sources, Elsevier (2009) 632 Google Scholar
26. Sutija, D.P, Norby, T., Björnbom, P., Solid State Ionics 77 (1995) 167.Google Scholar
27. Norby, T. and Kofstad, P., Solid State Ionics 20 (2986) 169.Google Scholar
28. Bertei, A., Nicolella, C. – private communication Google Scholar
29. Pending patent – Deposition No 1060705/17.12.2010 Google Scholar
30. Elangovan, S., Zhao, F., Hartvigsen, J., Ramirez, D. and Larsen, D., Proceedings of the 11th Annual SECA Workshop, Pittsburgh, PA, 2010.Google Scholar