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Progress in Oxide-Based Electrochromics: Towards Roll-to-Roll Manufacturing

Published online by Cambridge University Press:  04 April 2011

Claes G. Granqvist*
Affiliation:
Department of Engineering Sciences, The Ångström Laboratory, Uppsala University, P. O. Box 534, SE-75121 Uppsala Sweden
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Abstract

Electrochromics is a key “green” technology for massive energy savings in the built environment jointly with indoor comfort. This paper surveys basic electrochromic (EC) device designs, useful oxide materials and their nanostructures, and elements of a theoretical description of the EC phenomenon. It also outlines critical manufacturing technologies and their pros and cons. Focus is on EC foil technology, which is shown capable of mass fabrication via roll-to-roll web coating and continuous lamination.

Type
Research Article
Copyright
Copyright © Materials Research Society 2011

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References

REFERENCES

1. Granqvist, C. G., Handbook of Inorganic Electrochromic Materials (Elsevier, Amsterdam, The Netherlands, 1995).Google Scholar
2. Monk, P. M. S., Mortimer, R. J. and Rosseinsky, D. R., Electrochromism and Electrochromic Devices (Cambridge University Press, Cambridge, UK, 2007).Google Scholar
3. Deb, S. K., Appl. Opt. Suppl. 3, 192 (1969); Philos. Mag. 27, 801(1973).Google Scholar
4. Lampert, C. M., Solar Energy Mater. 11, 1 (1984).Google Scholar
5. Svensson, J. S. E. M. and Granqvist, C. G., Solar Energy Mater. 11, 29 (1984).Google Scholar
6. Smith, G. B. and Granqvist, C. G., Green Nanotechnology: Solutions for Sustainability and Energy in the Built Environment (CRC Press, Boca Raton, FL, USA, 2010).Google Scholar
7. Richter, B., Goldston, D., Crabtree, G., Glicksman, L., Goldstein, D., Greene, D., Kammen, D., Levine, M., Lubell, M., Sawitz, M., Sperling, D., Schlachter, F., Scofield, J. and Dawson, D., Rev. Mod. Phys. 80, S1 (2008).Google Scholar
8. Lee, E. S., Selkowitz, S. E., Clear, R. D., DiBartolomeo, D. L., Klems, J. H., Fernandes, L. L., Ward, G. J., Inkarojrit, V. and Yazdanian, M., Advancement of Electrochromic Windows(California Energy Commission, PIER, 2006), CEC-500-2006-052.Google Scholar
9. Eichholtz, P., Kok, N. and Quigley, J. M., Doing well by going good? Green office buildings (Center for the Study of Energy Markets, Berkeley, CA, USA, 2009), Working Paper CSEM WP-192.Google Scholar
10. Granqvist, C. G., Nature Mater. 5, 89 (2006).Google Scholar
11. Andersson, A. M., Granqvist, C. G. and Stevens, J. R., Appl. Opt. 28, 3295 (1989).Google Scholar
12. Sbar, N., Badding, M., Budziak, R., Cortez, K., Laby, L., Michalski, L., Ngo, T., Schulz, S. and Urbanik, K., Solar Energy Mater. Solar Cells 56, 321 (1999).Google Scholar
13. O’Brien, N. A., Mathew, J. G. H. and Hichwa, B. P., Thin Solid Films 345, 312 (1999).Google Scholar
14. Kraft, A. and Rottmann, M., Solar Energy Mater. Solar Cells 93, 2088 (2009).Google Scholar
15. Niklasson, G. A. and Granqvist, C. G., J. Mater. Chem. 17, 127 (2007).Google Scholar
16. Avendaño, E., Azens, A., Niklasson, G. A. and Granqvist, C. G., J. Electrochem. Soc. 152, F203 (2005); E. Avendaño, H. Rensmo, A. Azens, A. Sandell, G. de M. Azevedo, H. Siegbahn, G. A. Niklasson and C. G. Granqvist, J. Electrochem. Soc. 156, P132(2009).Google Scholar
17. Goodenough, J. B., Progr. Solid State Chem. 5, 145 (1971).Google Scholar
18. Talledo, A. and Granqvist, C. G., J. Appl. Phys. 77, 4655 (1995).Google Scholar
19. Denesuk, M. and Uhlmann, D. R., J. Electrochem. Soc. 143, L186 (1996).Google Scholar
20. Berggren, L., Jonsson, J. C. and Niklasson, G. A., J. Appl. Phys. 102, 083538 (2007).Google Scholar
21. Avendaño, E., Azens, A., Niklasson, G. A. and Granqvist, C. G., Solar Energy Mater. Solar Cells 84, 337 (2004).Google Scholar
22. Green, S., Electrochromism in Nickel Oxide, Tungsten Oxide and Composites Based on These, Licentiate Thesis (Uppsala University, Uppsala, Sweden, 2010), unpublished.Google Scholar
23. Thornton, J. A., J. Vacuum Sci. Technol. 11, 666 (1974).Google Scholar
24. Granqvist, C. G., Solar Energy Mater. Solar Cells 91, 1529 (2007).Google Scholar
25. Hamberg, I. and Granqvist, C. G., J. Appl. Phys. 60, R123 (1986).Google Scholar
26. Smith, G. B., Niklasson, G. A., Svensson, J. S. E. M. and Granqvist, C. G., J. Appl. Phys. 59, 571 (1986).Google Scholar
27. Lansåker, P. C., Backholm, J., Niklasson, G. A. and Niklasson, G. A., Thin Solid Films 518, 1225 (2009).Google Scholar
28. Geim, A. K. and Novoselov, K. S., Nature Mater. 6, 183 (2007).Google Scholar
29. Bae, S., Kim, H., Lee, Y., Xu, X., Park, J.-S., Zheng, Y., Balakrishnan, J., Lei, T., Kim, H. R., Song, Y. I., Kim, Y.-J., Kim, K. S., Özyilmaz, B., Ahn, J.-H., Hong, B. H. and Iijima, S., Nature Nanotechnol. 5, 574 (2010).Google Scholar
30. Hu, L., Kim, H. S., Lee, J.-Y., Peumans, P. and Cui, Y., ACS Nano 4, 2955 (2010).Google Scholar
31. Granqvist, C. G., Green, S., Jonson, E. K., Marsal, R., Niklasson, G. A., Roos, A., Topalian, Z., Azens, A., Georén, P., Gustavsson, G., Karmhag, R., Smulko, J. and Kish, L. B., Thin Solid Films 516, 5921 (2008).Google Scholar
32. Avendaño, E., private communication (2010).Google Scholar
33. Blackman, C. S., Piccirillo, C., Binions, R. and Parkin, I. P., Thin Solid Films 517, 4565 (2009).Google Scholar
34. Mlyuka, N. R., Niklasson, G. A. and Granqvist, C. G., Appl. Phys. Lett. 95, 171909 (2009).Google Scholar
35. Mlyuka, N. R., Niklasson, G. A. and Granqvist, C. G., Phys. Stat. Sol. A 206, 2155 (2009).Google Scholar
36. Li, S.-Y., Niklasson, G. A. and Granqvist, C. G., J. Appl. Phys. 108, 063525 (2010).Google Scholar