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Polyimide/Norganic Composite - Interpenetrating Polymer Network For Stable Second-Order Nonlinear Optics

Published online by Cambridge University Press:  16 February 2011

Sutiyao Marturunkakul ,
Jeng-I Chen ,
Lian Li ,
Xin Li Jiang ,
Ru Jong Jeng ,
Jayant Kumar  and
Sukant K. Tripathy
Sutiyao Marturunkakul
Affiliation:
Center for Advanced Materials, Departments of Chemistry, University of Massachusetts Lowell, Lowell, MA 01854, USA
Jeng-I Chen
Affiliation:
Center for Advanced Materials, Departments of Chemistry, University of Massachusetts Lowell, Lowell, MA 01854, USA
Lian Li
Affiliation:
Center for Advanced Materials, Department of Physics, University of Massachusetts Lowell, Lowell, MA 01854, USA
Xin Li Jiang
Affiliation:
Center for Advanced Materials, Department of Physics, University of Massachusetts Lowell, Lowell, MA 01854, USA
Ru Jong Jeng
Affiliation:
Center for Advanced Materials, Departments of Chemistry, University of Massachusetts Lowell, Lowell, MA 01854, USA
Jayant Kumar
Affiliation:
Center for Advanced Materials, Department of Physics, University of Massachusetts Lowell, Lowell, MA 01854, USA
Sukant K. Tripathy
Affiliation:
Center for Advanced Materials, Departments of Chemistry, University of Massachusetts Lowell, Lowell, MA 01854, USA
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Abstract

A new class of IPN system has been prepared and investigated. This IPN system combines the polybismaleinimide network and the NLO-active phenoxysilicon network. The second-order NLO coefficients, d33, values of the samples range from 2.5 to 6.7 pm/V depending on the composition and the processing conditions. The temporal stability of the second-order nonlinearities for these samples at 110 °C varies from 47 to 88 % retention after 274 h.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 328: Symposium Q – Electrical, Optical, and Magnetic Properties of Organic Solid State Materials , 1993 , 541
Copyright
Copyright © Materials Research Society 1994

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References

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