Hostname: page-component-586b7cd67f-dsjbd Total loading time: 0 Render date: 2024-11-24T16:59:56.178Z Has data issue: false hasContentIssue false

Phase Transitions in Pure Plutonium

Published online by Cambridge University Press:  24 May 2012

Jeremy N. Mitchell
Affiliation:
Materials Science and Technology Division, Los Alamos National Laboratory, Los Alamos, NM 87545
Franz, J. Freibert
Affiliation:
Materials Science and Technology Division, Los Alamos National Laboratory, Los Alamos, NM 87545
Daniel S. Schwartz
Affiliation:
Materials Science and Technology Division, Los Alamos National Laboratory, Los Alamos, NM 87545
Get access

Abstract

The five solid-solid phase transformations of pure Pu are typically represented in idealized thermal expansion plots as having sharp onsets and finishes with linear expansion behavior between the transitions. These behaviors are in reality less common, and the various transitions may have bursting behavior, curved onsets and finishes, and non-linear thermal expansion. In this presentation we will review the transformation behavior of diverse set of pure Pu types. These types include zone-refined pure Pu, electro-refined pure Pu, pure Pu doped with 1000 appm Ga, and alpha-phase Pu within an as-cast 1.9 atomic. % Ga alloy.

Type
Articles
Copyright
Copyright © Materials Research Society 2012

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1. Martin, A. E., and Selmanoff, G. D., Los Alamos Scientific Laboratory Report LA-502, (September 1, 1945).Google Scholar
2. Ellinger, F.H., Journal of Metals 80 (10), 12561259 (1956).Google Scholar
3. Elliott, R. O. and Larson, A. C., in Coffinberry, A. S. and Miner, W. N., The Metal Plutonium (The University of Chicago Press, Chicago, 1961) pp. 265280.Google Scholar
4. Morgan, J. R., in Proceedings of the Fourth International Conference on Plutonium and other Actinides, edited by Miner, W. N. (The Metallurgical Society of AIME, Warrendale, PA, 1970) pp. 669678.Google Scholar
5. Clark, D. L., Hecker, S. S., Jarvinen, G. D., and Neu, M. P., in The Chemistry of the Actinide and Transactinide Elements, edited by Morss, L. R., Edelstein, N. M., Fuger, J., and Katz, J. J. (Springer, Dordrecht, Netherlands, 2010) Vol. 2, pp. 8131264.Google Scholar
6. Lashley, J. C., Blau, M. S., Staudhammer, K. P., and Pereyra, R. A., Journal of Nuclear Materials 274, 315319 (1974).Google Scholar
7. Pascard, R., in Proceedings of the Second International Conference on Plutonium Metallurgy, edited by Grison, E., Lord, W. B. H., and Fowler, R. D. (Cleaver-Hume Press LTD, London, 1961) pp. 1625.Google Scholar
8. Schwartz, D. S. and Zocco, T. G., in Solid-Solid Phase Transformations in Inorganic Materials 2005, edited by Howe, J. M., Laughlin, D. E., Lee, J. K., Dahmen, U., and Soffa, W. A. (The Minerals, Metals, & Materials Society, Warrendale, PA, 2005) Vol. 2, pp. 591596.Google Scholar