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Nonunear Absorption in Phthalocyanines and Naphthalocyanines

Published online by Cambridge University Press:  16 February 2011

James S. Shirk
Affiliation:
Naval Research Laboratory, Washington, DC 20375
Steven R. Flom
Affiliation:
Naval Research Laboratory, Washington, DC 20375
J. R. Lindle
Affiliation:
Naval Research Laboratory, Washington, DC 20375
F. J. Bartoli
Affiliation:
Naval Research Laboratory, Washington, DC 20375
Arthur W. Snow
Affiliation:
Naval Research Laboratory, Washington, DC 20375
Michael E. Boyle
Affiliation:
Naval Research Laboratory, Washington, DC 20375
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Abstract

The wavelength dependence of the nonlinear absorption for lead tetrakis (cumyl-phenoxy) phthalocyanine (PbPc(CP)4) and lead octa (α-pentoxy) napthalocyanine (PbNc(α-PO)8) are reported. The ground state absorption and the reverse saturable absorption are substantially red shifted in PbNc (α-PO)8 as expected. Such control over the reverse saturable absorption is crucial to design optical limiting materials for specific wavelength ranges.

Type
Research Article
Copyright
Copyright © Materials Research Society 1994

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References

REFERENCES

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