Hostname: page-component-78c5997874-fbnjt Total loading time: 0 Render date: 2024-11-02T18:59:21.409Z Has data issue: false hasContentIssue false

Nonlinear Optical Material Fabrication via Sol-Gel Processing

Published online by Cambridge University Press:  25 February 2011

Jongsung Kim
Affiliation:
Rensselaer Polytechnic Institute, Dept. of Chemical Engineering, Troy, N.Y. 12180.
Joel L. Plawsky
Affiliation:
Rensselaer Polytechnic Institute, Dept. of Chemical Engineering, Troy, N.Y. 12180.
Get access

Abstract

Nonlinear optical materials which are highly transparent and show large second harmonic generation coefficients were fabricated via the sol-gel process. Nonlinear chromophores were directly incorporated into the silica network by polymerizing chromophore containing organo silanes such as N-[3-(Triethoxysilyl)propyl]-2, 4-dinitrophenylamine (TDP) and 3-(4-Formyl phenoxy)propyl trimethoxy silane (FPT).

Type
Research Article
Copyright
Copyright © Materials Research Society 1992

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1. Williams, D. J., Angew. Chem., Int. Ed. Engl. 23, 690 (1984)Google Scholar
2. Williams, D. J., ed., Nonlinear Optical Properties of Organic and Polymeric Materials (ACS Symp. Ser. No. 233, Washington, 1983).Google Scholar
3. Chemia, D. S. and Zyss, J., ed., Nonlinear Optical Properties of Organic Molecules and Crystals Vols. 1 and 2 (Academic Press, New York, 1987).Google Scholar
4. Havinga, E. E. and van Pelt, P., Ber. Bunsenges. Phys. Chem. 83, 816 (1979).Google Scholar
5. Singer, K. D., Sohn, J. E., and Lalama, S. J., Appl. Phys. Lett. 49, 248 (1986).Google Scholar
6. Singer, K. D., Kuzyk, M. G., Holand, W. R., Shon, T.E., Lalama, S.J.. Comizzolli, R.B., Katz, G.E., and Schilling, M.L., Appl. Phys. Lett. 53, 1800 (1988).Google Scholar
7. Jungbauer, D., Reck, B., Twieg, R., Yoon, D. Y., Willson, C. G., and Swalen, J. D., Appl. Phys. 56, 2610 (1990).Google Scholar
8. Mackenzie, J. D. and Ulrich, D. R., in Sol-Gel Optics, edited by Mackenzie, J. D., Ulrich, D. R., and Brinker, C. J. (SPIE, 1328. Bellingham, Washington, 1990).Google Scholar
9. Che, T. M., Carney, R. V., Khanarian, G., Keosian, R. A., Borzo, M., J. Non-Cryst. Solids 102, 280(1988).Google Scholar
10. Prasad, P. N., Karasz, F. E., Yang, Y., Wang, C. J., U. S. Patent Appl. No. 312132 (1989).Google Scholar
11. Boulton, J. M., Thompson, J., Fox, H. H., Goredisher, I., Teowee, G., Calvert, P. D. and Uhlmann, D. R., in Better Ceramics Through Chemistry IV, edited by Zelinski, B.J., Brinker, C. J., Clark, D. E., and Ulrich, D. R. (Mater. Res. Soc. Proc. 180, Pittsburgh, PA 1990) pp. 987993.Google Scholar
12. NSF Report (1991, Aug. Contract #CBT-9009481)Google Scholar
13. Brattain, W. H. and Briggs, H.B., Phy. Rev. 75, 1705 (1949).Google Scholar
14. Pedrotti, F. L. and Pedrotti, L.S., Introduction to Optics (Prentice-Hall, Englewood, 1987) p. 263.Google Scholar
15. Jerphagnon, J. and Kurtz, S. K., J. of Applied Physics, 41, 1667, (1970).Google Scholar
16. Prasad, P. N. and Williams, D. J., Introduction to Nonlinear Optical Effects in Molecules and Polymers. (J. Wiley & Sons, New York 1990).Google Scholar