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Mixed Valent Rhodates

Published online by Cambridge University Press:  01 February 2011

Hiroshi Mizoguch ,
Arthur William Sleight  and
Mas Subramanian
Hiroshi Mizoguch
Affiliation:
[email protected], Oregon State University, Chemistry, Corvallis, Oregon, United States
Arthur William Sleight
Affiliation:
[email protected], Oregon State University, Chemistry, Corvallis, Oregon, United States
Mas Subramanian
Affiliation:
[email protected], Oregon State University, Chemistry, Corvallis, Oregon, United States
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Abstract

Exploratory synthesis of mixed oxides of rhodium has produced many new rhodates containing both Rh3+ and Rh4+. The structures of all the compounds are based on networks formed from RhO6 octahedra sharing both corners and edges. All compounds exhibit good electrical conductivity, and some also show a high thermopower.

Keywords

Rhoxidethermoelectric
Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 1148: Symposium PP – Solid-State Chemistry of Inorganic Materials VII , 2008 , 1148-PP11-04
Copyright
Copyright © Materials Research Society 2009

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References

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