Hostname: page-component-586b7cd67f-2brh9 Total loading time: 0 Render date: 2024-11-24T15:06:10.575Z Has data issue: false hasContentIssue false
  • English
  • Français

Magnetic properties of bulk composite FeBSiM (M=Cr,Zr) alloys with high microhardness

Published online by Cambridge University Press:  01 February 2011

S. Báez ,
I. Betancourt ,
M. E. Hernandez-Rojas  and
I. A. Figueroa
S. Báez
Affiliation:
Departamento de Materiales Metálicos y Cerámicos, Instituto de Investigaciones en Materiales, Universidad Nacional Autónoma de México, México D.F. 04510, México.
I. Betancourt
Affiliation:
Departamento de Materiales Metálicos y Cerámicos, Instituto de Investigaciones en Materiales, Universidad Nacional Autónoma de México, México D.F. 04510, México.
M. E. Hernandez-Rojas
Affiliation:
Departamento de Biotecnología, Departamento de Ingeniería de Procesos e Hidráulica, Universidad Autónoma Metropolitana-Iztapalapa, México D.F. 09340, México.
I. A. Figueroa
Affiliation:
Departamento de Materiales Metálicos y Cerámicos, Instituto de Investigaciones en Materiales, Universidad Nacional Autónoma de México, México D.F. 04510, México.
Get access

Abstract

The synthesis, mechanical and magnetic properties of bulk composite Fe72B19.2Si4.8M4 (M=Cr, Zr) alloys obtained by a copper mould injection casting technique under a protective helium atmosphere are reported and discussed. The resultant microstructure of the composite alloys consists of crystalline Fe92Si8 and Fe2B phases embedded in a glassy matrix. The values of microhardness (Hv) show maxima for the alloy containing Cr with 10.24±0.95 GPa. The maximum value of saturation magnetization average (μ0Ms) is 1.25±0.02 T for Cr-containing alloy. The Curie temperatures (Tc) of amorphous phases are higher than 390 K for both alloys. However, the bulk composite alloys presents values for crystallization temperature (Tx) of 1289±10 K and 1140±10 K for Cr and Zr-containing alloys, respectively. These results are interpreted on the basis of the interplay between the crystalline and amorphous phases.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 1276: Advanced Structural Materials–2010 , 2010 , 23
Copyright
Copyright © Materials Research Society 2010

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

1. Functional Materials, European Conference on Advanced Materials and Processes, Euromat, K., Grassie, E., Tenckhoff, G., wegner, J., Haubelt and H., Hanselka (Eds), Vol. 13, Wiley-VCH, Weinheim, 2000.Google Scholar
2. Materials Science Forum, Y., Umakoshi, S., Fujimoto (Eds), Vol. 512, Trans. Tech. Pub. LTD, Beijing 2006.Google Scholar
3. Magnetism, materials and applications, Édu Trémolet, de Lacheisserie (Ed), Springer, New York, 2005.Google Scholar
4. Buschow, K. H. J., Handbook of Magnetic Materials. Vol. 10. K. H. J., Buschow (Ed), Elsevier Science, Holland, 1997.Google Scholar
5. Cullity, B. D. and Graham, C. D., Introduction to Magnetic Materials, 2nd Ed., IEEE Press Wiley, Hoboken, 2009.Google Scholar
6. Bozorth, R. M., Ferromagnetism, Van Nostrand, New York, 1968.Google Scholar
7. Klement, W., Willens, R. H. and Duwez, P., Nature 187 (1960) 869.Google Scholar
8. Smallman, R.E. and Ngan, A.H.W., Physical Metallurgy and Advanced Materials, Seven Edition (2007) p.40.Google Scholar
9. Hasegawa, R. and Ray, R., J. App. Phys. 49 (1978) 4174 Google Scholar
10. Chen, H.S., Rep. Prog. Phys. 43 (1980) 402.Google Scholar
11. Littmann, M.F., IEEE Trans. Magn. 1 (1971) 48.Google Scholar
12. Berger, L.I. and Pamplim, B.R., Handbook of Chemistry and Physics, CRC, Section 12, Properties of Solids, D.R., Lide (ed) (2005–2006) p.93.Google Scholar
13 Wang, W.H., Dong, C. and Shek, C.H., Mater. Sci. Eng. R 44 (2004) 45.Google Scholar
14. Long, Z., Wei, H., Ding, Y., Zhang, P., Xie, G. and Inoue, A., J. Alloys Comp. 475 (2009) 207.Google Scholar
15. Senkov, O.N. and Miracle, D.B., Mater. Res. Bull. 36 (2001) 2183.Google Scholar
16. American Society for Metals, Handbook Vol.1, Properties and selection: Irons, Steels and High-Performance Alloys, Wrought Tool Steels, Bayer, A.M., Vasco, T. and Walton, L.R (Rev.) (1990) p.757.Google Scholar
17. Figueroa, I.A., Rawal, R., Stewart, P., Carroll, P.A., Davies, H.A., Jones, H. and Todd, I., Non-Cryst, J.. Solids 353 (2007), p. 839.Google Scholar
18. Suzuki, K., in: Y., Liu, D.J., Sellmyer, D., Shindo (Eds.), Processing and modeling of novel nanocrystalline soft magnetic materials, (Tsinghua University Press-Springer, China, 2006) p.340.Google Scholar
19. McHenry, M.E., Willard, M.A. and Laughlin, D.E., Prog. Mater. Sci. 44 (1999) 291.Google Scholar