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Low Temperature Diamond Growth With CF4 Addition in A Hot Filament Reactor

Published online by Cambridge University Press:  22 February 2011

Evaldo. J. Corat
Affiliation:
Instituto Nacional de Pesquisas Espaciais - INPE/LAS, C. P. 515, 12.201-970, São José dos Campos, S.P., Brazil
V. J. Trava-Airoldi
Affiliation:
Instituto Nacional de Pesquisas Espaciais - INPE/LAS, C. P. 515, 12.201-970, São José dos Campos, S.P., Brazil
Nélia F. Leite
Affiliation:
Instituto Nacional de Pesquisas Espaciais - INPE/LAS, C. P. 515, 12.201-970, São José dos Campos, S.P., Brazil
Angel F.V. Peña
Affiliation:
Instituto Nacional de Pesquisas Espaciais - INPE/LAS, C. P. 515, 12.201-970, São José dos Campos, S.P., Brazil
Vítor Baranauskas
Affiliation:
Faculdade de Engenharia Elétrica, Universidade Estadual de Campinas, Campinas, S.P., Brazil
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Abstract

In this work we show that the addition of a small amount of CF4 to a regular CH4 -H2 gas mixture allows diamond growth at lower temperatures with reasonable growth rates. We used a hot filament assisted reactor and observed diamond growth with a substrate temperature as low as 390 ଌ. We present a comparative study for the growth dependence on substrate temperature with and without CF4 addition in the gas mixture. The growth rate is measured by post growth weighting with a micro balance. Raman spectroscopy, SEM and AFM images show the good quality of the films grown at low temperatures when CF4 is added to the feeding gas.

Type
Research Article
Copyright
Copyright © Materials Research Society 1994

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References

REFERENCES

1. Patterson, D.E., Bai, B.J., Chu, C.J., Hauge, R.H. and Margrave, J.L., in Proc. of the 2nd Intern. Conf. on the New Diamond Science and Technology, edited by Messier, R., Glass, J.T., Butler, J.E. and Roy, R. (Materials Research Society, Pittsburgh, PA, 1991), p. 433 Google Scholar
2. Rudder, R.A., Hudson, G.C., Posthill, J.B., Thomas, R.E. and Markunas, R.J., Appl. Phys. Lett., 59, 791 (1991)Google Scholar
3. Hong, F.C.-N., Liang, G.T., Chang, D. and Yu, S.C., in Applications of Diamond Films and Related Materials, edited by Tzeng, Y., Yoshikawa, M., Murakawa, M. and Feldman, A. (Elsevier Science Publishers B.V., 1991), p. 577 Google Scholar
4. Hong, F.C.-N., Hsieh, J.-C., Wu, J.-J., Liag, G.-T. and Hwang, J.H., Diamond and Related Materials, 2, 365 (1993)Google Scholar
5. Baranauskas, V., Fukui, M., Rodrigues, C.R., Parizotto, N. and Trava-Airoldi, V.J., Appl. Phys. Lett., 60, 1567 (1992)Google Scholar
6. Kadono, M., Inoue, T., Miyanaga, A. and Yamazaki, S., Appl. Phys. Lett., 61, 772 (1992)Google Scholar
7. Corat, E.J., Goodwin, D.G. and Trava-Airoldi, V.J., in Proc. of the 2nd Intern. Conf. on the Applications of Diamond Films and Related Materials, edited by Yoshikawa, M., Murakawa, M., Tzeng, Y. and Yarbrough, W.A. (MYU, Tokio, 1993), p. 697 Google Scholar
8. Airoldi, V.J. Trava, Nobrega, B.N., Corat, E.J., Bosco, E. Del, Leite, N.F. and Baranauskas, V., to be published in Vacuum.Google Scholar
9. Harris, S.J. and Belton, D.N., Appl. Phys. Lett., 59, 1949 (1991)Google Scholar
10. Frenklach, M., in Proc. of the 2nd Intern. Symposium on Diamond Materials, edited by Purdes, A.J., Meyerson, B.M., Angus, J.C., Spear, K.E., Davis, R.F. and Yoder, M. (The Electrochemical Society, Inc., Washington, DC, 1991), p. 142 Google Scholar
11. Baranauskas, V., Peled, A., Trava-Airoldi, V.J., Lima, C.A.S., Doi, I. and Corat, E.J., to be published in Applied Surface Science 79–80, (1994)Google Scholar
12. Kondoh, E., Ohta, T., Mitomo, T. and Ohtsuka, K., Appl. Phys. Lett., 59, 488 (1991)Google Scholar
13. Spitsyn, B.V., Bouilov, L.L. and Deryagin, B.V., J. Cryst. Growth, 52, 219 (1981)Google Scholar
14. Zhu, W., Messier, R. and Badzian, A.R., in 1st Intern. Symposium on Diamond and Diamond-Like Films (The Electrochemical Society, 1989), p. 61 Google Scholar
15. Mitsuda, Y., Yoshida, T. and Akashi, K., Rev. Sci. Instrum., 60, 249 (1989)Google Scholar
16. Yarbrough, W.A., Badzian, A.R., Pickrell, D., Liou, Y. and Inspektor, A., J. Cryst. Growth, 99, 1177 (1990)Google Scholar
17. Liou, Y., Inspektor, A., Weimer, R. and Messier, R., Appl. Phys. Lett., 55, 631 (1989)Google Scholar
18. Ihara, M., Maeno, H., Miyamoto, K. and Komiyama, H., Appl. Phys. Lett., 59, 1473 (1991)Google Scholar