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Published online by Cambridge University Press: 15 February 2011
Research on a new process is described which utilized a laser to achieve controlled crystallization of amorphous Si thinfilms for photovoltaic applications. Amorphous Si films are deposited on suitable substrates using RF sputtering. A laser is used to inoculate these films with crystalline embryos at specific locations. These embryos should then grow in a controlled atmosphere annealing furnace under conditions optimized to maintain the nucleation rate at zero and the transformation rate (from amorphous to crystalline silicon) at a maximum value. The result will be a polycrystalline silicon film with a large grain size to film thickness ratio, where the ultimate grain size will be determined by the laser inoculation spacing.
This research was conducted with the support of the U.S. Department of Energy, Grant No. DE-FG01-79ET-00081. However, any opinions, findings, conclusions, or recommendations expressed herein are those of the authors and do not necessarily reflect the views of DOE.