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Interfacial Adhesion of Pure-Silica-Zeolite Low-k Thin Films

Published online by Cambridge University Press:  01 February 2011

Lili Hu ,
Junlan Wang ,
Zijian Li ,
Shuang Li  and
Yushan Yan
Lili Hu
Affiliation:
Department of Mechanical Engineering
Junlan Wang
Affiliation:
Department of Mechanical Engineering
Zijian Li
Affiliation:
Department of Chemical and Environmental Engineering University of California, Riverside, CA 92521
Shuang Li
Affiliation:
Department of Chemical and Environmental Engineering University of California, Riverside, CA 92521
Yushan Yan
Affiliation:
Department of Chemical and Environmental Engineering University of California, Riverside, CA 92521
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Abstract

Nanoporous zeolite thin films are promising candidates as future low dielectric constant (low-k) materials. During the integration process with other semiconductor materials, the residual stresses resulting from the synthesis processes may cause fracture or delamination of the thin films. In order to achieve high quality low-k zeolite thin films, the evaluation of the adhesion performance is important. In this paper, laser spallation technique is utilized to investigate the interfacial adhesion of zeolite thin film-Si substrate interfaces prepared using three different processes. The experimental results demonstrate that the nature of the deposition method has a great effect on the resulted interfacial adhesion of the film-substrate interfaces. This is the first time that the interfacial strength of zeolite thin films-Si substrates is quantitatively evaluated. The results have great significance in the future applications of low-k zeolite thin film materials.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 875: Symposium O – Thin Films - Stresses and Mechanical Properties XI , 2005 , O10.5
Copyright
Copyright © Materials Research Society 2005

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References

1. Yan, Y., Li, S., and Li, Z., Zeolite News Letters 20 (2003) 111.Google Scholar
2. Breck, D.W., Zeolite molecular sieves: Structure, chemistry, and use. New York, Wiley. New York, 1974.Google Scholar
3. Baerlocher, W.M.M. Ch., Olson, D.H., Atlas of zeolite framework types. Amsterdam; Elsevier. New York, 2001.Google Scholar
4. Wang, Z., Mitra, A., Wang, H., Huang, L., and Yan, Y., Adv. Mater. 13 (2001) 1463.Google Scholar
5. Vella, J.B., Volinsky, A.A., Adhihetty, I.S., Edwards, N.V., and Gerberich, W.W., Mat. Res. Soc. Symp. Proc. 716 (2002) B12.13.Google Scholar
6. Volinsky, A., Vella, J., and Gerberich, W., Thin Solid Films 429 (2003) 201.Google Scholar
7. Yan, Y., Li, S., and Li, Z., Zeolite News Letters 20(3) (2003).Google Scholar
8. Lovallo, M.C. and Tsapatsis, M., AIChE Journal 42(11) (1996) 3020.Google Scholar
9. Wang, J., Weaver, R.L., and Sottos, N.R., Experimental Mechanics 42(1) (2002) 74.Google Scholar
10. Wang, J., Weaver, R.L., and Sottos, N.R., Journal of Applied Physics 93(12) (2003) 9529.Google Scholar