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Host-Guest Systems in the Development of Anticorrosive Polymeric Films

Published online by Cambridge University Press:  10 February 2011

L. R. M. Estevão  and
R. S. V. Nascimento
L. R. M. Estevão
Affiliation:
DQO - Instituto de Química, Universidade Federal do Rio de Janeiro, CT Bl A, 6° andar, Cidade Universitária, Rio de Janeiro, R.J. Brazil
R. S. V. Nascimento
Affiliation:
DQO - Instituto de Química, Universidade Federal do Rio de Janeiro, CT Bl A, 6° andar, Cidade Universitária, Rio de Janeiro, R.J. Brazil
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Abstract

Interactive dispersion-type LDPE/EVA films with anticorrosive properties were produced using host-guest systems of thermally stable volatile corrosion inhibitors (VCI) dicyclohexylammonium p-nitrobenzoate and phosphate, adsorbed on NaY zeolites and diatomaceous earths. Carbon steel specimens were either directly exposed to the inhibiting systems studied or wrapped with the additivated films. Accelerated corrosion tests were carried out where the inhibitive properties of the systems being studied were determined by mass loss of the test coupons. The influence of the mineral support on the volatility of the corrosion inhibitors was evaluated by TG/DTG techniques. The obtained results may be regarded as a confirmation of the hypothesis that VCI volatility may be controlled by their deposition on determined supports. Also, both VCIs had their efficiency enhanced by zeolites, and the phosphate greatly benefited from the use of diatomaceous earth.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 576: Symposium DD – Organic/Inorganic Hybrid Materials II , 1999 , 287
Copyright
Copyright © Materials Research Society 1999

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References

REFERENCES

1. Fiaud, C., Theory and Practice of Vapour Phase Inhibitors: Corrosion Inhibitors, edited by the European Federation 11 (The Institute of Materials, London, 1994), pp. 1–11.Google Scholar
2. Baker, H., Ind. Eng. Chem 46 (12), 3592 (1954).10.1021/ie50540a624Google Scholar
3. Fujita, T., Corr. Eng. 43, 563 (1994).Google Scholar
4. Brophy, J., Fitzsimmons, V., O’Rear, J., Price, T., Zisman, W., Ind. Eng. Chem 43, 884 (1951).10.1021/ie50496a034Google Scholar
5. Leng, A., Stratmann, M., Corr. Sci. 34 (10), 1657 (1993).10.1016/0010-938X(93)90039-JGoogle Scholar
6. Andreev, N., Kuznetsov, Y., Prot. Met. 32 (2), 148 (1996).Google Scholar
7. Dorfman, A., Zamyatina, O., Kuznetsov, Y., Prot. Met. 31 (6), 511 (1995).Google Scholar
8. Carlson, R., Malwitz, N., Hill, B., US Patent No. 4,973,448 (1990).Google Scholar
9. Pinto, W., MSc Thesis, DQO-Instituto de Quimica, UFRJ, pp.97–100, 1995.Google Scholar