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Published online by Cambridge University Press: 20 December 2012
This paper demonstrates that electrostatic spray deposition (ESD) method is a promising solution process to fabricate highly-crystalline organic films (6,13-bis(triisopropylsilylethynyl) pentacene; TIPS pentacene) for the use in bottom-contact organic field-effect transistors (OFETs). We obtained large crystalline domains (i.e., molecularly-oriented domains) by using an o-DCB:acetone mixed solvent (1:1), and observed good transistor behavior in an OFET having the channel length of 20 μm.