Hostname: page-component-586b7cd67f-g8jcs Total loading time: 0 Render date: 2024-12-01T01:12:26.306Z Has data issue: false hasContentIssue false

Electrochemical Kinetic of a Low Carbon Steel in Seawater at Different Flow Speed

Published online by Cambridge University Press:  11 May 2015

A. Carmona
Affiliation:
Unidad Anticorrosión, Instituto de Ingeniería, Universidad Veracruzana, Av. S.S. Juan Pablo II s/n, Fracc. Costa Verde, C.P. 94294, Veracruz, México.
R. Orozco-Cruz
Affiliation:
Unidad Anticorrosión, Instituto de Ingeniería, Universidad Veracruzana, Av. S.S. Juan Pablo II s/n, Fracc. Costa Verde, C.P. 94294, Veracruz, México.
E. Mejía-Sánchez
Affiliation:
Unidad Anticorrosión, Instituto de Ingeniería, Universidad Veracruzana, Av. S.S. Juan Pablo II s/n, Fracc. Costa Verde, C.P. 94294, Veracruz, México.
A. Contreras
Affiliation:
Instituto Mexicano del Petróleo, Eje Central Lázaro Cárdenas Norte No.152, Col. San Bartolo Atepehuacan, Del. Gustavo A. Madero, C.P. 07730, México.
R. Galván-Martínez*
Affiliation:
Unidad Anticorrosión, Instituto de Ingeniería, Universidad Veracruzana, Av. S.S. Juan Pablo II s/n, Fracc. Costa Verde, C.P. 94294, Veracruz, México.
*
Get access

Abstract

An electrochemical impedance spectroscopy (EIS) corrosion study of API X70 steel was carried out in synthetic seawater with different rotation speeds using a rotating cylinder electrode (RCE) to control the hydrodynamic conditions at room temperature, atmospheric pressure and 24 h of exposure time. A superficial analysis through a scanning electron microscope (SEM) was used to analyze the corrosion type. The rotation speed used was 0 rpm (static condition), 1000, 3000 and 5000 rpm (turbulent flow). The results show that the turbulent flow conditions affect directly the corrosion rate (CR) of the steel, because all values of the CR under turbulent flow conditions are higher than the CR values at static conditions. In addition, it is important to point out that at turbulent flow conditions, the CR increased as the rotation speed also increased. The morphology of the corrosion in all experiments was localized corrosion.

Type
Articles
Copyright
Copyright © Materials Research Society 2015 

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

Edmar Schulz, H., Andrade Simões, A.L., Jahara Lobosco, R., Hydrodynamics Optimizing Methods and Tools, 364, In Tech Rijeka (2011)CrossRefGoogle Scholar
Asher, S.L., PhD Thesis, Georgia Institute of Technology (2007).Google Scholar
Poulson, B., J. Appl. Electrochem., 24, 1 (1994).CrossRefGoogle Scholar
Silverman, D.C., Corrosion. 40, 220 (1984).CrossRefGoogle Scholar
Silverman, D.C., NACE-Corrosion/90, Paper No. 13, USA, (1990).Google Scholar
Kear, G., Barker, B. D., Stokes, K. R. and Walsh, F. C., Corros. Sci. 47, 1694 (2005).CrossRefGoogle Scholar
Mora Mendoza, J.L., Turgoose, S., Corros. Sci., 44, 1223 (2002).CrossRefGoogle Scholar
Nesic, S., Bienkowski, J., Bremhorst, K., Yang, K.S., Corrosion, 56, 1005 (2000).CrossRefGoogle Scholar
Galván Martínez, R., Orozco Cruz, R., Torres Sánchez, R., Martínez, E.A., Mater. Corros., 61, 872 (2010).CrossRefGoogle Scholar
Kear, G., Bremhorst, K., Coles, S., Huáng, S.H., Corros. Sci., 50, 1789 (2008).CrossRefGoogle Scholar
Gabe, D.R., Walsh, F.C., J. Appl. Electrochem., 13, 3 (1983).CrossRefGoogle Scholar
Llongueras, J. Genescá, Técnicas Electroquímicas para el Control y Estudio de la Corrosión, 56, (Programa Universitario de Ciencia e Ingeniería de Materiales, UNAM, México, 2002).Google Scholar
Huerta, E. Otero, Corrosión y degradación de materiales, 67, (Síntesis, Madrid, 2001).Google Scholar
Barsoukov, E., Macdonald, J.R., Impedance Spectroscopy: Theory, Experiment, and Applications, 2nd ed., 2 (John Wiley & Sons, New Jersey, 2005).CrossRefGoogle Scholar
Hernández Espejel, A., Domínguez Crespo, M.A, Cabrera Sierra, R., Rodríguez Meneses, C., and Arce Estrada, E. M., Corros. Sci., 52, 2258 (2010).CrossRefGoogle Scholar
Hsu, C.H., Mansfield, F., Corrosion, 57, 747 (2001).CrossRefGoogle Scholar
Corredor, E.C., Vera, E., Ortiz, C.A., Alfonso, J.E., Revista Colombiana de Física, 38, 21 (2006).Google Scholar
Groysman, A., Corrosion for Everybody, 32 (Springer, New York, 2010).CrossRefGoogle Scholar
Galván Martínez, R., PhD Thesis, UNAM, 2004.Google Scholar
Mansfeld, F., Shih, H., Greene, H., Tsai, C.H., ASTM Special Technical Publication, 1188, 37 (1993).Google Scholar