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Characterization of carbon dioxide separation membrane with polycation nano-layers

Published online by Cambridge University Press:  18 February 2013

Tatsuya Funaoka*
Affiliation:
Department of materials science and chemistry, University of Hyogo, 2167 Shosha, Himeji, Hyogo 671-2280
Yusuke Daiko
Affiliation:
Department of materials science and chemistry, University of Hyogo, 2167 Shosha, Himeji, Hyogo 671-2280
Atsushi Mineshige
Affiliation:
Department of materials science and chemistry, University of Hyogo, 2167 Shosha, Himeji, Hyogo 671-2280
Tetsuo Yazawa
Affiliation:
Department of materials science and chemistry, University of Hyogo, 2167 Shosha, Himeji, Hyogo 671-2280
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Abstract

Ultrathin layers of positively charged poly(diallyl dimethylammonium) choloride (PDDA) and negatively charged poly(sodium 4-styrenesulfonate) (PSS) were deposited on SiO2/ polyethylene glycol hybrid membranes via layer-by-layer assembly technique, and carbon dioxide absorption/separation properties were investigated. Quartz crystal microbalance (QCM) measurements revealed that both PDDA and PSS nanocoatings have a good affinity for CO2 absorption. PDDA-deposited film shows about two times higher CO2 ideal gas selectivity compared with unmodified silica film.

Type
Articles
Copyright
Copyright © Materials Research Society 2013 

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References

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