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STM studies of epitaxial graphene

Published online by Cambridge University Press:  23 November 2012

Swee Liang Wong
Affiliation:
Department of Physics, National University of Singapore; [email protected]
Han Huang
Affiliation:
Department of Physics, National University of Singapore; [email protected]
Wei Chen
Affiliation:
Department of Physics, National University of Singapore; [email protected]
Andrew T.S. Wee
Affiliation:
Department of Physics, National University of Singapore; [email protected]
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Abstract

This article reviews the use of scanning tunneling microscopy (STM) and scanning tunneling spectroscopy (STS) to characterize the physical and electronic properties of epitaxial graphene. Topographical variations revealed by STM allow the determination of the number of graphene layers and the detection of lattice mismatch between the graphene and the substrate, as well as rotational disorder. STS allows the local electronic characterization of graphene. STM/STS can also be used to perform local studies of graphene modification through processes such as atomic/molecular adsorption and intercalation.

Type
Research Article
Copyright
Copyright © Materials Research Society 2012

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References

Geim, A.K., Science 324, 1530 (2009), and references therein.CrossRefGoogle Scholar
Novoselov, K.S., Geim, A.K., Morozov, S.V., Jiang, D., Zhang, Y., Dubonos, S.V., Grigorieva, I.V., Firsov, A.A., Science 306, 666 (2004), and references therein.CrossRefGoogle Scholar
Güntherodt, H.J., Wiesendanger, R., Eds., Scanning Tunneling Microscopy I: General Principles and Applications to Clean and Adsorbate-Covered Surfaces (Springer, Berlin, ed. 2, 1992).CrossRefGoogle Scholar
Binning, G., Rohrer, H., Gerber, C., Weibel, E., Phys. Rev. Lett. 49, 57 (1982).CrossRefGoogle Scholar
Brar, V., Zhang, Y., Yayon, Y., Ohta, T., McChesney, J., Bostwick, A., Rotenberg, E., Horn, K., Crommie, M., Appl. Phys. Lett. 91, 122102 (2007).CrossRefGoogle Scholar
Zhang, Y., Brar, V., Wang, F., Girit, C., Yayon, Y., Panlasigui, M., Zettl, A., Crommie, M., Nat. Phys. 4, 627 (2008).CrossRefGoogle Scholar
Lauffer, P., Emtsev, K.V., Graupner, R., Seyller, T., Ley, L., Phys. Rev. B 77, 155426 (2008).CrossRefGoogle Scholar
Cho, J., Gao, L., Tian, J., Cao, H., Wu, W., Yu, Q., Yitamben, E.N., Fisher, B., Guest, J.R., Chen, Y.P., Guisinger, N.P., ACS Nano 5, 3607 (2011).CrossRefGoogle Scholar
Wong, S.L., Huang, H., Wang, Y., Cao, L., Qi, D., Santoso, I., Chen, W., Wee, A.T.S., ACS Nano 5, 7662 (2011).CrossRefGoogle Scholar
Hamers, R.J., Annu. Rev. Phys. Chem. 40, 531 (1989).Google Scholar
Huang, H., Chen, W., Chen, S., Wee, A.T.S., ACS Nano 2, 2513 (2008).CrossRefGoogle Scholar
Mallet, P., Varchon, F., Naud, C., Magaud, L., Berger, C., Veuillen, J.Y., Phys. Rev. B 76, 041403(R) (2007).CrossRefGoogle Scholar
Veuillen, J.Y., Hiebel, F., Magaud, L., Mallet, P., Varchon, F., J. Phys. D: Appl. Phys. 43, 374008 (2010).CrossRefGoogle Scholar
Riedl, C., Coletti, C., Iwasaki, T., Zakharov, A.A., Starke, U., Phys. Rev. Lett. 103, 246804 (2009).CrossRefGoogle Scholar
Riedl, C., Coletti, C., Starke, U., J. Phys. D: Appl. Phys. 43, 374009 (2010).CrossRefGoogle Scholar
Bostwick, A., Emtsev, K., Horn, K., Huwald, E., Ley, L., McChesney, J., Ohta, T., Riley, J., Rotenberg, E., Speck, F., Seyller, Th., Adv. Solid State Phys. 47, 159 (2008).CrossRefGoogle Scholar
Kim, S., Ihm, J., Choi, H.J., Son, Y.W., Phys. Rev. Lett. 100, 176802 (2008).CrossRefGoogle Scholar
Varchon, F., Feng, R., Hass, J., Li, X., Nguyen, B.N., Naud, C., Mallet, P., Veuillen, J.Y., Berger, C., Conrad, E.H., Magaud, L., Phys. Rev. Lett. 99, 126805 (2007).CrossRefGoogle Scholar
Emtsev, K.V., Speck, F., Seyller, T., Ley, L., Phys. Rev. B 77, 155303 (2008).CrossRefGoogle Scholar
N’Diaye, A.T., Engler, M., Busse, C., Wall, D., Buckanie, N., Meyer zu Heringdorf, F.J., van Gastel, R., Poelsema, B., Michely, T., New J. Phys. 11, 023006 (2009).Google Scholar
Yu, Q., Jauregui, L.A., Wu, W., Colby, R., Tian, J., Su, Z., Cao, H., Liu, Z., Pandey, D., Wei, D., Chung, T.F., Peng, P., Guisinger, N.P., Stach, E.A., Bao, J., Pei, S.S., Chen, Y.P., Nat. Mater. 10, 443 (2011).CrossRefGoogle Scholar
Kwon, S., Ciobanu, C., Petrova, V., Shenoy, V., Bareño, J., Gambin, V., Petrov, I., Kodambaka, S., Nano Lett. 9, 3985 (2009).CrossRefGoogle Scholar
Gao, M., Pan, Y., Huang, L., Hu, H., Zhang, L., Guo, H., Du, S., Gao, H., Appl. Phys. Lett. 98, 033101 (2011).CrossRefGoogle Scholar
Lahiri, J., Miller, T., Adamska, L., Oleynik, I., Batzill, M., Nano Lett. 11, 518 (2011).CrossRefGoogle Scholar
Biedermann, L., Bolen, M., Capano, M., Zemlyanov, D., Reifenberger, R., Phys. Rev. B 79, 125411 (2009).CrossRefGoogle Scholar
Huang, H., Liang Wong, S., Tin, C.C., Qiang Luo, Z., Xiang Shen, Z., Chen, W., Shen Wee, A.T., J. Appl. Phys. 110, 014308 (2011).CrossRefGoogle Scholar
First, P., de Heer, W.A, Seyller, T., Berger, C., Stroscio, J., Moon, J., MRS Bull. 35, 296 (2010).CrossRefGoogle Scholar
Poon, S.W., Chen, W., Tok, E.S., Wee, A.T.S., Appl. Phys. Lett. 92, 104102 (2008).CrossRefGoogle Scholar
Poon, S.W., Chen, W., Wee, A.T.S., Tok, E.S., Phys. Chem. Chem. Phys. 12, 13522 (2010).CrossRefGoogle Scholar
Hiebel, F., Mallet, P., Varchon, F., Magaud, L., Veuillen, J.Y., Phys. Rev. B 78, 153412 (2008).CrossRefGoogle Scholar
Hupalo, M., Conrad, E., Tringides, M., Phys. Rev. B 80, 041401 (2009).CrossRefGoogle Scholar
Sprinkle, M., Siegel, D., Hu, Y., Hicks, J., Tejeda, A., Taleb-Ibrahimi, A., Le Fèvre, P., Bertran, F., Vizzini, S., Enriquez, H., Chiang, S., Soukiassian, P., Berger, C., de Heer, W.A., Lanzara, A., Conrad, E.H., Phys. Rev. Lett. 103, 226803 (2009).CrossRefGoogle Scholar
Siegel, D., Hwang, C., Fedorov, A., Lanzara, A., Phys. Rev. B 81, 241417 (2010).CrossRefGoogle Scholar
Hass, J., de Heer, W.A, Conrad, E., J. Phys.: Condens. Matter 20, 323202 (2008).Google Scholar
Hass, J., Varchon, F., Millán-Otoya, J., Sprinkle, M., Sharma, N., de Heer, W.A., Berger, C., First, P., Magaud, L., Conrad, E., Phys. Rev. Lett. 100, 125504 (2008).CrossRefGoogle Scholar
Song, Y.J., Otte, A.F., Kuk, Y., Hu, Y., Torrance, D.B., First, P.N., de Heer, W.A., Min, H., Adam, S., Stiles, M.D., MacDonald, A.H., Stroscio, J.A., Nature 467, 185 (2010).CrossRefGoogle Scholar
Berger, C., Song, Z., Li, X., Wu, X., Brown, N., Naud, C., Mayou, D., Li, T., Hass, J., Marchenkov, A.N., Conrad, E.H., First, P.N., de Heer, W.A., Science 312, 1191 (2006).CrossRefGoogle Scholar
Miller, D., Kubista, K., Rutter, G., Ruan, M., de Heer, W.A., First, P., Stroscio, J., Science 324, 924 (2009).CrossRefGoogle ScholarPubMed
Gao, L., Guest, J.R., Guisinger, N.P., Nano Lett. 10, 3512 (2010).CrossRefGoogle Scholar
N’Diaye, A.T., Coraux, J., Plasa, T.N., Busse, C., Michely, T., New J. Phys. 10, 043033 (2008).CrossRefGoogle Scholar
Coraux, J., N’Diaye, A.T., Busse, C., Michely, T., Nano Lett. 8, 565 (2008).CrossRefGoogle Scholar
Balog, R., Jørgensen, B., Nilsson, L., Andersen, M., Rienks, E., Bianchi, M., Fanetti, M., Lægsgaard, E., Baraldi, A., Lizzit, S., Sljivancanin, Z., Besenbacher, F., Hammer, B., Pedersen, T.G., Hofmann, P., Hornekær, L., Nat. Mater. 9, 315 (2010).CrossRefGoogle Scholar
Barja, S., Garnica, M., Hinarejos, J.J., Vázquez de Parga, A.L., Martín, N., Miranda, R., Chem. Commun. 46, 8198 (2009).Google Scholar
Huang, L., Pan, Y., Pan, L., Gao, M., Xu, W., Que, Y., Zhou, H., Wang, Y., Du, S., Gao, H.J., Appl. Phys. Lett. 99, 163107 (2011).CrossRefGoogle Scholar
Wintterlin, J., Bocquet, M., Surf. Sci. 603, 1841 (2009).CrossRefGoogle Scholar
Jin, L., Fu, Q., Mu, R., Tan, D., Bao, X., Phys. Chem. Chem. Phys. 13, 16655 (2011).CrossRefGoogle Scholar
Pan, Y., Zhang, H., Shi, D., Sun, J., Du, S., Liu, F., Gao, H.J., Adv. Mater. 21, 2777 (2009).Google Scholar
Marchini, S., Günther, S., Wintterlin, J., Phys. Rev. B 76, 075429 (2007).CrossRefGoogle Scholar
Wang, B., Bocquet, M.L., Marchini, S., Günther, S., Wintterlin, J., Phys. Chem. Chem. Phys. 10, 3530 (2008).CrossRefGoogle Scholar
Miller, D.L., Kubista, K.D., Rutter, G.M., Ruan, M., de Heer, W.A., Kindermann, M., First, P.N., Stroscio, J.A., Nat. Phys. 6, 811 (2010).CrossRefGoogle Scholar
Jung, S., Rutter, G.M., Klimov, N.N., Newell, D.B., Calizo, I., Hight-Walker, A.R., Zhitenev, N.B., Stroscio, J.A., Nat. Phys. 7, 245 (2011).CrossRefGoogle Scholar
Li, G., Luican, A., Lopes dos Santos, J.M.B., Castro Neto, A.H., Reina, A., Kong, J., Andrei, E.Y., Nat. Phys. 6, 109 (2009).CrossRefGoogle Scholar
Li, G., Luican, A., Andrei, E.Y., Phys. Rev. Lett. 102, 176804 (2009).CrossRefGoogle Scholar
Levy, N., Burke, S.A., Meaker, K.L., Panlasigui, M., Zettl, A., Guinea, F., Neto, A.H.C., Crommie, M.F., Science 329, 544 (2010).CrossRefGoogle Scholar
Yan, H., Sun, Y., He, L., Nie, J.C., Chan, M.H.W., Phys. Rev. B 85, 035422 (2012).CrossRefGoogle Scholar
Subramaniam, D., Libisch, F., Li, Y., Pauly, C., Geringer, V., Reiter, R., Mashoff, T., Liebmann, M., Burgdörfer, J., Busse, C., Michely, T., Mazzarello, R., Pratzer, M., Morgenstern, M., Phys. Rev. Lett. 108, 046801 (2012).CrossRefGoogle Scholar
Tapaszto, L., Dobrik, G., Lambin, P., Biro, L., Nat. Nanotechnol. 3, 397 (2008).CrossRefGoogle Scholar
Castro Neto, A., Peres, N., Novoselov, K., Geim, A., Rev. Mod. Phys. 81, 109 (2009).CrossRefGoogle Scholar
Wallace, P., Phys. Rev. 71, 622 (1947).CrossRefGoogle Scholar
Hossain, M.Z., Walsh, M.A., Hersam, M.C., J. Am. Chem. Soc. 132, 15399 (2010).CrossRefGoogle Scholar
Brihuega, I., Mallet, P., Bena, C., Bose, S., Michaelis, C., Vitali, L., Varchon, F., Magaud, L., Kern, K., Veuillen, J., Phys. Rev. Lett. 101, 206802 (2008).CrossRefGoogle Scholar
Ando, T., NPG Asia Mater. 1, 17 (2009).CrossRefGoogle Scholar
Yazyev, O., Helm, L., Phys. Rev. B 75, 125408 (2007).CrossRefGoogle Scholar
Ugeda, M., Fernández-Torre, D., Brihuega, I., Pou, P., Martínez-Galera, A., Pérez, R., Gómez-Rodríguez, J., Phys. Rev. Lett. 107, 116803 (2011).CrossRefGoogle Scholar
Lahiri, J., Lin, Y., Bozkurt, P., Oleynik, I.I., Batzill, M., Nat. Nanotechnol. 5, 326 (2010).CrossRefGoogle Scholar
Wang, Y., Huang, Y., Song, Y., Zhang, X., Ma, Y., Liang, J., Chen, Y., Nano Lett. 9, 220 (2008).CrossRefGoogle Scholar
Guisinger, N.P., Rutter, G.M., Crain, J.N., First, P.N., Stroscio, J.A., Nano Lett. 9, 1462 (2009).CrossRefGoogle Scholar
Zhao, L., He, R., Rim, K.T., Schiros, T., Kim, K.S., Zhou, H., Gutierrez, C., Chockalingam, S.P., Arguello, C.J., Palova, L., Nordlund, D., Hybertsen, M.S., Reichman, D.R., Heinz, T.F., Kim, P., Pinczuk, A., Flynn, G.W., Pasupathy, A.N., Science 333, 999 (2011).CrossRefGoogle Scholar
Haberer, D., Vyalikh, D.V., Taioli, S., Dora, B., Farjam, M., Fink, J., Marchenko, D., Pichler, T., Ziegler, K., Simonucci, S., Dresselhaus, M.S., Knupfer, M., Büchner, B., Grüneis, A., Nano Lett. 10, 3360 (2010).CrossRefGoogle Scholar
Sessi, P., Guest, J.R., Bode, M., Guisinger, N.P., Nano Lett. 9, 4343 (2009).CrossRefGoogle Scholar
Jee, H., Jin, K., Han, J., Hwang, H., Jhi, S., Kim, Y., Hwang, C., Phys. Rev. B 84, 075457 (2011).CrossRefGoogle Scholar
Nair, R.R., Ren, W., Jalil, R., Riaz, I., Kravets, V.G., Britnell, L., Blake, P., Schedin, F., Mayorov, A.S., Yuan, S., Katsnelson, M.I., Cheng, H.M., Strupinski, W., Bulusheva, L.G., Okotrub, A.V., Grigorieva, I.V., Grigorenko, A.N., Novoselov, K.S., Geim, A.K., Small 6, 2877 (2010).CrossRefGoogle Scholar
Jeon, K.J., Lee, Z., Pollak, E., Moreschini, L., Bostwick, A., Park, C.M., Mendelsberg, R., Radmilovic, V., Kostecki, R., Richardson, T.J., Rotenberg, E., ACS Nano 5, 1042 (2011).CrossRefGoogle Scholar
Elias, D.C., Nair, R.R., Mohiuddin, T.M.G., Morozov, S.V., Blake, P., Halsall, M.P., Ferrari, A.C., Boukhvalov, D.W., Katsnelson, M.I., Geim, A.K., Novoselov, K.S., Science 323, 610 (2009).CrossRefGoogle Scholar
Ohta, T., Bostwick, A., Seyller, T., Horn, K., Rotenberg, E., Science 313, 951 (2006).CrossRefGoogle Scholar
Balog, R., Jørgensen, B., Wells, J., Lægsgaard, E., Hofmann, P., Besenbacher, F., Hornekær, L., J. Am. Chem. Soc. 131, 8744 (2009).CrossRefGoogle Scholar
Xie, L., Wang, X., Lu, J., Ni, Z., Luo, Z., Mao, H., Wang, R., Wang, Y., Huang, H., Qi, D., Liu, R., Yu, T., Shen, Z., Wu, T., Peng, H., Özyilmaz, B., Loh, K., Wee, A.T.S., Ariando, , Chen, W., Appl. Phys. Lett. 98, 193113 (2011).CrossRefGoogle Scholar
Hupalo, M., Liu, X., Wang, C., Lu, W., Yao, Y., Ho, K., Tringides, M., Adv. Mater. 23, 2082 (2011).CrossRefGoogle Scholar
Choi, J., Lee, H., Kim, K.J., Kim, B., Kim, S., J. Phys. Chem. Lett. 1, 505 (2010).CrossRefGoogle Scholar
Chen, W., Chen, S., Qi, D.C., Gao, X.Y., Wee, A.T.S., J. Am. Chem. Soc. 129, 10418 (2007).CrossRefGoogle Scholar
Xie, L., Wang, X., Mao, H., Wang, R., Ding, M., Wang, Y., Özyilmaz, B., Loh, K.P., Wee, A.T.S., Ariando, , Chen, W., Appl. Phys. Lett. 99, 012112 (2011).CrossRefGoogle Scholar
Chen, Z., Santoso, I., Wang, R., Xie, L.F., Mao, H.Y., Huang, H., Wang, Y.Z., Gao, X.Y., Chen, Z.K., Ma, D., Wee, A.T.S., Chen, W., Appl. Phys. Lett. 96, 213104 (2010).CrossRefGoogle Scholar
Sun, J.T., Lu, Y.H., Chen, W., Feng, Y.P., Wee, A.T.S., Phys. Rev. B 81, 155403 (2010).CrossRefGoogle Scholar
Huang, H., Chen, S., Gao, X., Chen, W., Wee, A.T.S., ACS Nano 3, 3431 (2009).CrossRefGoogle Scholar
Wang, Q.H., Hersam, M.C., Nat. Chem. 1, 206 (2009).CrossRefGoogle Scholar
Hiebel, F., Mallet, P., Veuillen, J.Y., Magaud, L., Phys. Rev. B 83, 075438 (2011).CrossRefGoogle Scholar
Virojanadara, C., Zakharov, A., Yakimova, R., Johansson, L., Surf. Sci. 604, L4 (2010).CrossRefGoogle Scholar
Virojanadara, C., Yakimova, R., Zakharov, A.A., Johansson, L.I., J. Phys. D: Appl. Phys. 43, 374010 (2010).CrossRefGoogle Scholar
Sutter, P., Sadowski, J.T., Sutter, E.A., J. Am. Chem. Soc. 132, 8175 (2010).CrossRefGoogle Scholar
Oida, S., McFeely, F., Hannon, J., Tromp, R., Copel, M., Chen, Z., Sun, Y., Farmer, D., Yurkas, J., Phys. Rev. B 82, 041411(R) (2010).CrossRefGoogle Scholar
Cranney, M., Vonau, F., Pillai, P.B., Denys, E., Aubel, D., De Souza, M.M., Bena, C., Simon, L., Europhys. Lett. 91, 66004 (2010).CrossRefGoogle Scholar
Virojanadara, C., Watcharinyanon, S., Zakharov, A., Johansson, L., Phys. Rev. B 82, 205402 (2010).CrossRefGoogle Scholar
Varykhalov, A., Sánchez-Barriga, J., Shikin, A., Biswas, C., Vescovo, E., Rybkin, A., Marchenko, D., Rader, O., Phys. Rev. Lett. 101, 157601 (2008).CrossRefGoogle Scholar
Premlal, B., Cranney, M., Vonau, F., Aubel, D., Casterman, D., De Souza, M.M., Simon, L., Appl. Phys. Lett. 94, 263115 (2009).CrossRefGoogle Scholar
Walter, A.L., Jeon, K.J., Bostwick, A., Speck, F., Ostler, M., Seyller, T., Moreschini, L., Kim, Y.S., Chang, Y.J., Horn, K., Rotenberg, E., Appl. Phys. Lett. 98, 184102 (2011).CrossRefGoogle Scholar
Varykhalov, A., Gudat, W., Rader, O., Adv. Mater. 22, 3307 (2010).CrossRefGoogle Scholar