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State of the art of cyclic olefin polymers

Published online by Cambridge University Press:  13 March 2013

Laura Boggioni  and
Incoronata Tritto
Laura Boggioni
Affiliation:
Istituto per lo Studio delle, Macromolecole, CNR, Italy; [email protected]
Incoronata Tritto
Affiliation:
Istituto per lo Studio delle, Macromolecole, CNR, Italy; [email protected]
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Abstract

Highly active metallocenes and other single site catalysts as well as Grubbs and Schrock metathesis catalytic systems have opened up the possibility to polymerize cycloolefins or to copolymerize them with ethene or propene. The polymers obtained show exciting structures and properties. Cycloolefins such as cyclopentene, cyclooctene, norbornene, and their substituted derivatives are incorporated into the polymer chain either by double bonds or by ring-opening metathesis polymerization. Materials with elastomeric properties or tactic polymers with high glass transition temperatures and melting points are obtained with a wide range of microstructures. For example, cycloolefin copolymers and other homo- and copolymers of norbornene are of great academic and industrial interest because of their properties and applications in optoelectronics, lenses, and coatings.

Keywords

Chemical synthesispolymermacromolecular structurenuclear magnetic resonance (NMR)optical
Type
Research Article
Information
MRS Bulletin , Volume 38 , Issue 3: Ziegler-Natta catalysis: 50 years after the Nobel Prize , March 2013 , pp. 245 - 251
Copyright
Copyright © Materials Research Society 2013

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