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Materials Engineering Problems in Crystal Growth and Epitaxy of Cuprate Superconductors

Published online by Cambridge University Press:  29 November 2013

Hans J. Scheel
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Extract

The discovery of superconductivity in yttrium barium cuprate above the boiling point of liquid nitrogen by Wu et al. initiated a race in the search for higher critical temperatures (Tc) which was singular in the history of science. Since the ceramic superconducting pellets could be prepared nearly overnight and superconductivity easily demonstrated with liquid nitrogen and a levitating magnet, a great deal of effort went into garnering funds for a “new technological era.” High Tc superconductivity (HTSC) was expected to have applications in many areas of our life, be it for energy transport and high-power generators, transformers, current limiters, or for ultrafast computers and communication technology, or in medicine for NMR tomography and for SQUIDs in magnetic encephalography. Large-scale uses were also foreseen, such as levitation for trains, magnetohydrodynamic propulsion in ships, and applications for fusion reactors. Thousands of physicists and engineers searched for new materials with high Tc, and explored thin-film preparation by physical vapor deposition. In the early phase only a few scientists recognized that materials engineering problems would greatly hinder the development of applications of the cuprate superconductors. Most early efforts on HTSC went toward physical investigations of samples (crystals, layers, sheets, wires, etc.) which due to their complexity could not be reproducibly prepared, and which were not adequately characterized (see the section on Characterization). The Bi-, Tl-, and Hg-containing cuprates with Tc up to 135 K, for example, were found empirically, not by physical understanding of the HTSC phenomenon. Applications of HTSC have been limited to very specific areas, but a concerted effort should reveal opportunities for the materials research and superconductivity communities. Significant applications could be developed

which in the long run would also benefit fundamental physical investigations of the HTSC phenomenon.

Type
Crystal Engineering of High Tc-Related Oxide Films
Information
MRS Bulletin , Volume 19 , Issue 9 , September 1994 , pp. 26 - 32
Copyright
Copyright © Materials Research Society 1994

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References

1.Wu, M.K., Ashburn, J.R., Torng, C.J., Hor, P.H., Meng, R.L., Gao, L., Huang, Z.J., Wang, Y.Q., and Chu, C.W., Phys. Rev. Lett. 58 (1987) p. 908.CrossRefGoogle Scholar
2.Seeber, B., Herrmann, P., Zuccone, J., Cattani, D., Cors, J., Decroux, M., Fischer, Ø., Kny, E., and Perenboom, J.A.A.J., in Superconductivity, edited by Doyama, M., Sōmiya, S., and Chang, R.P.H. (Proc. Mater. Res. Soc. Int. Meeting Advanced Mater., Volume 6, Materials Research Society, Pittsburgh, PA, 1989) p. 83.Google Scholar
3.Scheel, H.J., Berkowski, M., and Chabot, B., J. Cryst. Growth 115 (1991) p. 19.CrossRefGoogle Scholar
4.Bardeen, J., Cooper, L.N., and Schrieffer, J.R., Phys. Rev. 108 (1957) p. 162, 1175.CrossRefGoogle Scholar
5.Bednorz, J.G. and Miiller, K.A., Z. Phys. B 64 (1986) p. 189.CrossRefGoogle Scholar
6.Lindemer, T.B., Washburn, F.A., MacDougall, C.S., Feenstra, R., and Cavin, O.B., Physica C 178 (1991) p. 93.CrossRefGoogle Scholar
7.Scheel, H.J. and Licci, F., Thermochim. Acta 174 (1991) p. 115.CrossRefGoogle Scholar
8.Holba, P. and Scheel, H.J., submitted.Google Scholar
9.Oka, K. and Unoki, H., Jpn. J. Appl. Phys. 26 (1987) p. L1590; 27 (1988) p. L1065; J. Cryst. Growth 99 (1990) p. 922.CrossRefGoogle Scholar
10.Klemenz, C. and Scheel, H.J., J. Cryst. Growth 129 (1993) p. 421.CrossRefGoogle Scholar
11.Erb, A., Biernath, T., and Müller-Vogt, G., J. Cryst. Growth 132 (1993) p. 389.CrossRefGoogle Scholar
12.Scheel, H.J., Licci, F., Besagni, T., Bolzoni, F., Cattani, S., Eckert, D., and Salviati, G., Mater. Sci. Eng. A 109 (1988) p. 299.CrossRefGoogle Scholar
13.François, M. and Scheel, H.J., J. Less Common Met. 150 (1989) p. 211.CrossRefGoogle Scholar
14.Elwell, D. and Scheel, H.J., Crystal Growth from High-Temperature Solutions, Chapter 7 (Academic Press, London, New York, 1975).Google Scholar
15.Scheel, H.J., Physica C 153–155 (1988) p. 44.CrossRefGoogle Scholar
16.Kaiser, D.L., Holtzberg, F., Scott, B.A., and McGuire, T.R., Appl. Phys. Lett. 51 (1987) p. 1040.CrossRefGoogle Scholar
17.Scheel, H.J., Sadowski, W., and Schellenberg, L., Supercon. Sci. Technol. 2 (1989) p. 17.CrossRefGoogle Scholar
18.Assmus, W. and Schmidbauer, W., Supercon. Sci. Technol. 6 (1993) p. 555.CrossRefGoogle Scholar
19.Berkowski, M., Bowen, P., Liechti, T., and Scheel, H.J., J. Am. Ceram. Soc. 75 (1992) p. 1005.CrossRefGoogle Scholar
20.Dembinski, K., Gervais, M., Odier, P., Coutures, J., and Coutures, J.P., Mater. Sci. Eng. B 5 (1990) p. 345.CrossRefGoogle Scholar
21. Institute of Electronic Materials Technology, 01-919 Warsaw, Poland; TEP K.K., Kosuge 2-20-4, Katsushika-ku, Tokyo 124, Japan; HITEC-Materials, G.Braun-Str. 2-4, D-7500 Karlsruhe 21; GPA, Grosslohering 70, D-2000 Hamburg 73, Germany; and for large quantities METOXIT AG, CH-8240 Thayngen, Switzerland.Google Scholar
22.Pellerin, N., Jouan, G., and Odier, P., J. Mater. Res. 8 (1993) p. 18.CrossRefGoogle Scholar
23.Licci, F., Frigeri, C., and Scheel, H.J., J. Cryst. Growth 112 (1991) p. 606.CrossRefGoogle Scholar
24.Schneemeyer, L.F., Waszczak, J.W., Siegrist, T., van Dover, R.B., Rupp, L.W., Batlogg, B., Cava, R.J., and Murphy, D.W., Nature 328 (1987) p. 601; see also R.A. Laudise, L.F. Schneemeyer, and R.L. Bams, J. Cryst. Growth 85 (1987) p. 569.CrossRefGoogle Scholar
25.Scheel, H.J. and Licci, F., MRS Bulletin XIII (10) (1988) p. 56.CrossRefGoogle Scholar
26.Scheel, H.J. and Licci, F., in High-Temperature Superconductors, edited by Brodsky, M.B., Dynes, R.C., Kitazawa, K., and Tuller, H.L. (Mater. Res. Soc. Symp. Proc. 99, Pittsburgh, PA, 1988) p. 595.Google Scholar
27.Boutellier, R., Sun, B.N., Scheel, H.J., and Schmid, H., J. Cryst. Growth 96 (1989) p. 465.CrossRefGoogle Scholar
28.Shiohara, Y., in Advances in Superconductivity VI, (6th Intl. Symp. on Superconductivity, Hiroshima, Oct. 1993), edited by Fujita, T. and Shiohara, Y. (Springer, Tokyo, 1994) p. 9.Google Scholar
29.Klemenz, C. and Scheel, H.J., unpublished.Google Scholar
30.Scheel, H.J. and Niedermann, P., J. Cryst. Growth 94 (1989) p. 281.CrossRefGoogle Scholar
31.Scheel, H.J., J. Less Common Met. 151 (1989) p. 199.CrossRefGoogle Scholar
32.Rothman, S.J., Routbort, J.L., Welp, U., and Baker, J.E., Phys. Rev. B 44 (1991) p. 2326.CrossRefGoogle Scholar
33.Scheel, H.J., Klemenz, C., Reinhart, F-K., Lang, H.P., and Güntherodt, H-J., Appl. Phys. Lett. 65 (August 15, 1994).CrossRefGoogle Scholar
34.Scheel, H.J., in Advances in Superconductivity VI, (6th Intl. Symp. on Superconductivity, Hiroshima, Oct. 1993), edited by Fujita, T. and Shiohara, Y. (Springer, Tokyo, 1994) p. 29.Google Scholar
35.Erbil, A. and Scheel, H.J., unpublished.Google Scholar
36.Luo, L., Hawley, M.E., Maggiore, C.E., Dye, R.C., Muenchhausen, R.E., Chen, L., Schmidt, B., and Kaloyeros, A.E., Appl. Phys. Lett. 62 (1993) p. 485.CrossRefGoogle Scholar
37.Stowell, M.J., Defects in Epitaxial Deposits, in Epitaxial Growth, Part B, edited by Matthews, J.W. (Academic Press, New York, 1975) Chapter 5.Google Scholar
38.Miyazawa, S. and Mukaida, M., Appl Phys. Lett. 64 (1994) p. 2160.CrossRefGoogle Scholar
39.Grabow, M.H. and Gilmer, G.H., Surf. Sci. 194 (1988) p. 333.CrossRefGoogle Scholar
40.Miyazawa, S., Appl. Phys. Lett. 55 (1989) p. 2230.CrossRefGoogle Scholar
41.Berkowski, M., Fink-Finowicki, J., and Scheel, H.J., unpublished.Google Scholar
42.Scheel, H.J., Berkowski, M., and Chabot, B., Physica C 185–189 (1991) p. 2059.Google Scholar