Hostname: page-component-cd9895bd7-dzt6s Total loading time: 0 Render date: 2024-12-27T10:36:19.453Z Has data issue: false hasContentIssue false
  • English
  • Français

Layered Li(Ni, M)O2 Systems as the Cathode Material in Lithium-Ion Batteries

Published online by Cambridge University Press:  31 January 2011

C. Delmas  and
L. Croguennec
Get access

Abstract

Compared with LiCoO2, the dominant cathode material in today's lithium batteries, lithium nickel oxide derivatives [Li(Ni, M)O2, where M – Co, Fe, Al, Mg] offer a higher specific energy at a lower cost. The synthesis and structure of these materials are described. The electrochemical performances of the pure nickel compound and a number of multicomponent systems are assessed. The goals of these fundamental studies are to optimize the synthesis conditions and material composition to achieve good electrochemical reversibility, decrease capacity loss upon cycling, and enhance thermal stability in the deintercalated state in order to improve cell safety.

Keywords

cationic substitutiondiffractionintercalationlayered oxideslithium nickelaterechargeable lithium batteriesredox processes.
Type
Research Article
Information
MRS Bulletin , Volume 27 , Issue 8: Portable Power: Advanced Rechargeable Lithium Batteries , August 2002 , pp. 608 - 612
Copyright
Copyright © Materials Research Society 2002

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

1.Biensan, P., Pérès, J.P., and Perton, F., “Optimized LiNi1–mMmO2 Materials with Improved Safety and Fading,” presented at the 1999 Joint International Meeting of the Electrochemical Society and the Electrochemical Society of Japan, Honolulu, Hawaii, October 17–22, 1999.Google Scholar
2.Goodenough, J.B., Wickham, D.G., and Croft, W.J., J. Appl. Phys. 29 (1958) p. 382.CrossRefGoogle Scholar
3.Hirano, A., Kanno, R., Kawamoto, Y., Takeda, Y., Yamaura, K., Takano, M., Ohyama, K., Ohashi, M., and Yamaguchi, Y., Solid State Ionics 78 (1995) p. 123.CrossRefGoogle Scholar
4.Rougier, A., Gravereau, P., and Delmas, C., J. Electrochem. Soc. 143 (1996) p. 1168.CrossRefGoogle Scholar
5.Pouillerie, C., Suard, E., and Delmas, C., J. Solid State Chem. 158 (2001) p. 187.CrossRefGoogle Scholar
6.Barra, A.L., Chouteau, G., Stepanov, A., and Delmas, C., J. Magn. Magn. Mater. 177–181 (1998) p. 783.CrossRefGoogle Scholar
7.Mertz, D., Ksari, Y., Celestini, F., Debierre, J.M., Stepanov, A., and Delmas, C., Phys. Rev. B 61 (2000) p. 1240.CrossRefGoogle Scholar
8.Shirakami, T., Takematsu, M., Hirano, A., Kanno, R., Yamaura, K., Takano, M., and Atake, T., Mater. Sci. Eng., B 54 (1998) p. 70.CrossRefGoogle Scholar
9.Takematsu, M., Kawaji, H., Atake, T., Shirakami, T., Hirano, A., and Kanno, R., Electrochemistry 68 (2000) p. 465.CrossRefGoogle Scholar
10.Croguennec, L., Pouillerie, C., and Delmas, C., J. Electrochem. Soc. 147 (2000) p. 1314.CrossRefGoogle Scholar
11.Delmas, C., Ménétrier, M., Croguennec, L., Saadoune, I., Rougier, A., Pouillerie, C., Prado, G., Grüne, M., and Fournès, L., Electrochim. Acta 45 (1999) p. 243.CrossRefGoogle Scholar
12.Rougier, A., Saadoune, I., Gravereau, P., Willmann, P., and Delmas, C., Solid State Ionics 90 (1996) p. 83.CrossRefGoogle Scholar
13.Reimers, J.N., Rossen, E., Jones, C.D., and Dahn, J.R., Solid State Ionics 61 (1993) p. 335.CrossRefGoogle Scholar
14.Prado, G., Suard, E., Fournès, L., and Delmas, C., J. Mater. Chem. 10 (2000) p. 2553.CrossRefGoogle Scholar
15.Prado, G., Fournès, L., and Delmas, C., Solid State Ionics 138 (2000) p. 19.CrossRefGoogle Scholar
16.Guilmard, M., Rougier, A., Grüne, M., Croguennec, L., and Delmas, C., J. Power Sources (2002) submitted for publication.Google Scholar
17.Croguennec, L., Suard, E., Willmann, P., and Delmas, C., Chem. Mater. (2002) in press.Google Scholar
18.Pouillerie, C., Croguennec, L., Biensan, P., Willmann, P., and Delmas, C., J. Electrochem. Soc. 147 (2000) p. 2061.CrossRefGoogle Scholar
19.Rougier, A., Chadwick, A.V., and Delmas, C., Solid State Commun. 94 (1995) p. 123.CrossRefGoogle Scholar
20.Mansour, A.N., Yang, X.Q., Sun, X., McBreen, J., Croguennec, L., and Delmas, C., J. Electrochem. Soc. 147 (2000) p. 2104.CrossRefGoogle Scholar
21.Demourgues, A., Pérès, J.P., Rougier, A., and Delmas, C., “(Fe, Co, Ni) K Edge EXAFS Study of Lix(Ni1–yMy)O2 (M = Fe, Co) Phases: Effect of the Lithium Content and the Cation Substitution on the Ni(III) Jahn–Teller Distortion,” presented at the Lithium Battery Discussion: Electrode Materials, Bordeaux-Arcachon, France, May 27–June 1, 2001.Google Scholar
22.Nakagome, T. and Nakai, I., Denki Kagaku 66 (1998) p. 727.CrossRefGoogle Scholar
23.Delmas, C., Pérès, J.P., Rougier, A., Demourgues, A., Weill, F., Chadwick, A., Broussely, M., Perton, F., Biensan, P., and Willmann, P., J. Power Sources 68 (1997) p. 120.CrossRefGoogle Scholar
24.Li, W., Reimers, J.N., and Dahn, J.R., Solid State Ionics 67 (1993) p. 123.CrossRefGoogle Scholar
25.Ohzuku, T., Ueda, A., and Nagayama, M., J. Electrochem. Soc. 140 (1993) p. 1862.CrossRefGoogle Scholar
26.Delmas, C., Ménétrier, M., Croguennec, L., Levasseur, S., Pérès, J.P., Pouillerie, C., Prado, G., Fournès, L., and Weill, F., Int. J. Inorg. Mater. 1 (1999) p. 11.CrossRefGoogle Scholar
27.Seguin, L., Amatucci, G., Anne, M., Chabre, Y., Strobel, P., Tarascon, J.M., and Vaughan, G., J. Power Sources 81–82 (1999) p. 604.CrossRefGoogle Scholar
28.Tarascon, J.M., Vaughan, G., Chabre, Y., Seguin, L., Anne, M., Strobel, P., and Amatucci, G., J. Solid State Chem. 147 (1999) p. 410.CrossRefGoogle Scholar
29.Croguennec, L., Pouillerie, C., Mansour, A.N., and Delmas, C., J. Mater. Chem. 11 (2001) p. 131.CrossRefGoogle Scholar
30.Pérès, J.P., Demourgues, A., and Delmas, C., Solid State Ionics 111 (1998) p. 135.CrossRefGoogle Scholar
31.Arroyo de Dompablo, M.E., Marianetti, C., Van der Ven, A., and Ceder, G., Phys. Rev. B 63 144107 (2001).CrossRefGoogle Scholar
32.Delmas, C. and Saadoune, I., Solid State Ionics 53–56 (1992) p. 370.CrossRefGoogle Scholar
33.Pouillerie, C., Croguennec, L., and Delmas, C., Solid State Ionics 132 (2000) p. 15.CrossRefGoogle Scholar
34.Pouillerie, C., Perton, F., Biensan, P., Pérès, J.P., Broussely, M., and Delmas, C., J. Power Sources 96 (2001) p. 293.CrossRefGoogle Scholar
35.Ohzuku, T., Yanagawa, T., Kouguchi, M., and Ueda, A., J. Power Sources 68 (1997) p. 131.CrossRefGoogle Scholar
36.Prado, G., Rougier, A., Fournès, L., and Delmas, C., J. Electrochem. Soc. 147 (2000) p. 2880.CrossRefGoogle Scholar
37.Prado, G., Fournès, L., and Delmas, C., J. Solid State Chem. 159 (2001) p. 103.CrossRefGoogle Scholar