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Computational Materials Science of Cement-Based Materials

Published online by Cambridge University Press:  29 November 2013

E.J. Garboczi  and
D.P. Bentz
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Cement-based materials are random composite materials over many length scales. In common with any random material, the two main problems that must be solved to obtain quantitative theoretical understanding of microstructure-property relationships are: (1) what actually is the microstructure, and (2) given enough knowledge of a micro-structure, how can properties be calculated?

In the past few decades, physicists and chemists have studied microstructure/property relationships for atomically disordered materials like semiconductor and metallic glasses, while mechanical engineers have done the same for continuum problems of macroscopic inclusions of one material distributed in a matrix of a second material. With the large memories and fast computational speeds of late 20th-century computers, it is now possible to attack problems that lie between these two extremes, namely random grain problems like those of cement-based and ceramic materials. For these kinds of materials, the important randomness for most problems is at the grain or particle level, not the atomic level, and is complicated by the fact that their microstructure changes markedly on time scales of hours and days, either due to sintering (ceramics), or hydration reactions (cement-based materials). The following sections of this paper describe how microstructures are simulated and properties like electrical conductivity and elastic moduli are computed-mostly for cement-based materials, but with some mention of parallel work on ceramic materials.

Type
Advanced Cement-Based Materials
Information
MRS Bulletin , Volume 18 , Issue 3 , March 1993 , pp. 50 - 54
Copyright
Copyright © Materials Research Society 1993

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References

1.Zallen, R., The Physics of Amorphous Solids (Wiley and Sons, New York, 1983).CrossRefGoogle Scholar
2.Hashin, Z., J. Appl. Mech. 50 (1983) p. 481.CrossRefGoogle Scholar
3.Bentz, D.P. and Stutzman, P.E., “Combination of SEM Backscattered Electron and X-ray Map Images to Identify Phases in Portland Cement,” to be presented at ASTM Symp. Petrogr. Cement. Mater., Atlanta, GA, June, 1993.Google Scholar
4.Stauffer, D., introduction to Percolation Theory (Taylor and Francis, London, 1985).CrossRefGoogle Scholar
5.Bentz, D.P. and Garboczi, E.J., Cem. and Cone. Res. 21 (1991) p. 325.CrossRefGoogle Scholar
6.Garboczi, E.J. and Bentz, D.P., in Materials Science of Concrete II, edited by Skalny, J. and Mindess, S. (American Ceramic Society, Westerville, OH, 1991) p. 249.Google Scholar
7.Young, J.F. and Hansen, W., in Microstructurenal Development During Hydration of Cement. adited by Struble, L.J. and Brown, P.W. (Mater. Res. Soc. Symp. Proc. 85, Pittsburgh, PA, 1987) p. 313.Google Scholar
8.Bentz, D.P., Coveney, P.V., Garboczi, E.J., Kleyn, M.F., and Stutzman, P.E., Modelling Simulation Mater. Sci. Eng., submitted for publication.Google Scholar
9.Schaefer, D.W., MRS Bulletin XIII (2) (1988) p. 22.CrossRefGoogle Scholar
10.Jennings, H.M., in Advances in Cement Technology, edited by Ghosh, S.N. (Pergamon Press, New York, 1983) p. 349.CrossRefGoogle Scholar
11.Zimbelmann, R., Cem. Concr. Res. 15 (1985) p. 801.CrossRefGoogle Scholar
12.Uchikawa, R., J. Res. Onoda Cem. Co. 40 (1988) p. 1–24.Google Scholar
13.Scrivener, K.L. and Gartner, E.M., in Bonding in Cementitious Composites, edited by Mindess, S. and Shah, S.P. (Mater. Res. Soc. Symp. Proc. 114, Pittsburgh, PA, 1988) p. 77.Google Scholar
14.Bentur, A., Ceram. Trans. 16 (1991) p. 523.Google Scholar
15.Winslow, D.N., Cohen, M.D., Bentz, D.P., Snyder, K.A., and Garboczi, E.J., Cem. Concr. Res., in press.Google Scholar
16.Garboczi, E.J. and Bentz, D.P., J. Mater. Res. 6 (1991) p. 196.CrossRefGoogle Scholar
17.Bentz, D.P., Stutzman, P.E., and Garboczi, E.J., Cem. Concr. Res. 22 (1992) p. 891.CrossRefGoogle Scholar
18.Bentz, D.P. and Garboczi, E.J., Am. Concr. Inst. Mater. J. 88 (1991) p. 518.Google Scholar
19.Bentz, D.P., Garboczi, E.J., and Stutzman, P.E., Proc. RILEM Conf. on Interfaces in Cem. Composites, Toulouse, France, October, 1992, in press.Google Scholar
20.Yang, S., Zhongzi, X., Ping, X., and Mingshu, T., Cem. Concr. Res. 22 (1992) p. 612 and 769.CrossRefGoogle Scholar
21.McLachlan, D.S., Blaszkiewicz, M., and Newnham, R.E., J. Am. Ceram. Soc. 73 (1990) p. 2187.CrossRefGoogle Scholar
22.Christensen, B.J., Mason, T.O., and Jennings, H.M., J. Am. Ceram. Soc. 75 (1992) p. 939.CrossRefGoogle Scholar
23.Garboczi, E.J. and Bentz, D.P., J. Mater. Sci. 27 (1992) p. 2083.CrossRefGoogle Scholar
24.Christensen, B.J., Mason, T.O., Jennings, H.M., Bentz, D.P., and Garboczi, E.J., in Advanced Cementitious Systems: Mechanisms and Properties, edited by Glasser, F.P., Pratt, P.L., Mason, T.O., Young, J.F., and McCarthy, G.J. (Mater. Res. Soc. Symp. Proc. 245, Pittsburgh, PA, 1992) p. 259.Google Scholar
25.Impedance Spectroscopy: Emphasizing Solid Materials and Systems, edited by McDonald, J.R. (Wiley and Sons, New York, 1987).Google Scholar
26.Coverdale, R.T., Garboczi, E.J., Jennings, H.M., Christensen, B.J., and Mason, T.O., “Computer Simulation of Impedance Spectroscopy in 2-D: Application to Cement Paste,” J. Am. Ceram. Soc., in press.Google Scholar
27.Snyder, K.A., Garboczi, E.J., and Day, A.R., J. Appl. Phys. 72 (1992) p. 5948.CrossRefGoogle Scholar
28.Bentz, D.P., Pimienta, P.J.P., Garboczi, E.J., and Carter, W.C., in Synthesis and Processing of Ceramics: Scientific Issues, edited by Rhine, W.E., Shaw, T.M., Gottschal, R.J., and Chen, Y. (Mater. Res. Soc. Symp. Proc. 249, Pittsburgh, PA, 1992) p. 413.Google Scholar
29.Pimienta, P., Carter, W.C., and Garboczi, E.J., Comp. Mater. Sci. 1 (1992) p. 63.CrossRefGoogle Scholar
30.Clarke, D.R., J. Am. Ceram. Soc. 75 (1992) p. 739.CrossRefGoogle Scholar