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Spectroscopic Studies on the Structures of Phosphate Sealing Glasses

Published online by Cambridge University Press:  29 November 2013

Richard K. Brow ,
Todd M. Alam ,
David R. Tallant  and
R. James Kirkpatrick
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Extract

Phosphate glasses generally have lower glass-transition temperatures and greater thermal-expansion coefficients than silicate and borate glasses, and so are candidate materials for specialty glass-metal sealing applications. Phosphate glasses also have desirable optical properties (rare-earth stimulated-emission cross sections, low thermo-optical coefficients, ultraviolet transparency, etc.) and so are used as laser glasses. Recent developments of novel compositions for biomedical applications and as fast-ion conductors have also revived interest in the study of phosphate glass structures.

The structure/property relationships in simple phosphate glasses have not received nearly the attention paid to silicate and borate-based systems. This is partially due to the difficulty in preparing anhydrous compositions with more than 50-mol% P2O5. Ultraphosphate compositions (where the [O]/[P] ratio is less than 3) are highly reactive to ambient water. In addition because P2O5 sublimes at about 300°C, ultraphosphate glasses have not been studied to the extent that metaphosphate ([O]/[P] = 3) and polyphosphate ([O]/[P] > 3) compositions have.

Type
New Functionality in Glass
Information
MRS Bulletin , Volume 23 , Issue 11 , November 1998 , pp. 63 - 67
Copyright
Copyright © Materials Research Society 1998

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References

1.Wilder, J.A., J. Non-Cryst. Solids 38/39 (1980) p. 879.CrossRefGoogle Scholar
2.Brow, R.K., Kovacic, L., and Loehman, R.E., Ceram. Trans. 70 (1996) p. 177.Google Scholar
3.Weber, M.J., J. Non-Cryst. Solids 123 (1990) p. 208.CrossRefGoogle Scholar
4.Hudgens, J.J. and Martin, S.W., J. AM. Ceram. Soc. 76 (1993) p. 1691.CrossRefGoogle Scholar
5.Hoppe, U., Walter, G., Barz, A., Stachel, D., and Hannon, A.C., J. Phys. Cond. Matter 10 (1998) p. 261.CrossRefGoogle Scholar
6.Van Wazer, J.R., Phosphorus and Its Compounds, vol. 1 (Interscience, New York, 1958).Google Scholar
7.Tatsumisago, M., Kowada, Y., and Minami, T., Phys. Chem. Glasses 29 (1988) p. 63.Google Scholar
8.Suzuki, K. and Ueno, M., J. Phys. (Paris) C8 (1985) p. 261.Google Scholar
9.Hoppe, U., Walter, G., Stachel, D., and Hannon, A.C., Z. Naturforsch. 51A (1996) p. 179.CrossRefGoogle Scholar
10.Uchino, T. and Ogata, Y., J. Non-Cryst. Solids 181 (1995) p. 175.CrossRefGoogle Scholar
11.Hudgens, J.J., Brow, R.K., Tallant, D.R., and Martin, S.W., J. Non-Cryst. Solids 223 (1998) p. 21.CrossRefGoogle Scholar
12.Hoppe, U., Walter, G., Stachel, D., Barz, A., and Hannon, A.C., Z. Naturforsch. 52A (1997) p. 259.CrossRefGoogle Scholar
13.Kirkpatrick, R.J. and Brow, R.K., Solid State Nucl. Magn. Reson. 5 (1995) p. 9.CrossRefGoogle Scholar
14.Brow, R.K., Tallant, D.R., Myers, S.T., and Phifer, C.C., J. Non-Cryst. Solids 191 (1995) p. 45.CrossRefGoogle Scholar
15.Brow, R.K., Tallant, D.R., Hudgens, J.J., Martin, S.W., and Irwin, A.D., J. Non-Cryst. Solids 177 (1994) p. 221.CrossRefGoogle Scholar
16.Gresch, R., Müller-Warmuth, W., and Dutz, H., J. Non-Cryst. Solids 34 (1979) p. 127.CrossRefGoogle Scholar
17.Sales, B.C., Ramsey, R.S., Bates, J.B., and Boatner, L.A., J. Non-Cryst. Solids 87 (1986) p. 137.CrossRefGoogle Scholar
18.Meadowcraft, T.R. and Richardson, F.D., Trans. Faraday Society 61 (1965) p. 54.CrossRefGoogle Scholar
19.Born, R., Feike, M., Jäger, C., and Spiess, H.W., Z. Naturforsch. 50A (1995) p. 169.CrossRefGoogle Scholar
20.Alam, T.M. and Brow, R.K., J. Non-Cryst. Solids 223 (1998) p. 1.CrossRefGoogle Scholar
21.Feike, M., Jäger, C., and Spiess, H.W., J. Non-Cryst. Solids 223 (1998) p. 200.CrossRefGoogle Scholar
22.Walter, G., Hoppe, U., Baade, T., Kranold, R., and Stachel, D., J. Non-Cryst. Solids 217 (1997) p. 299.CrossRefGoogle Scholar
23.Hoppe, U., J. Non-Cryst. Solids 195 (1996) p. 138.CrossRefGoogle Scholar
24.Frydman, L. and Harwood, J.S., J. Am. Chem. Soc. 117 (1995) p. 5367.CrossRefGoogle Scholar
25.Koller, H., Englehardt, G., Kentgens, A.P.M., and Sauer, J., J. Phys. Chem. 98 (1994) p. 1544.CrossRefGoogle Scholar
26.Bunker, B.C., Arnold, G.W., and Wilder, J.A., J. Non-Cryst. Solids 64 (1984) p. 291.CrossRefGoogle Scholar
27.Peng, Y.B. and Day, D.E., Glsss Technol. 32 (1991) p. 166.Google Scholar
28.Brow, R.K., J. Am. Ceram. Soc. 76 (1993) p. 913.CrossRefGoogle Scholar
29.Brow, R.K., Kirkpatrick, R.J., and Turner, G.L., J. Am. Ceram. Soc. p. 919.Google Scholar
30.Brow, R.K. and Tallant, D.R., J. Non-Cryst. Solids 222 (1997) p. 396.CrossRefGoogle Scholar
31.Brow, R.K. and Kovacic, L., U.S. Patent No. 5,262,364 (November 16, 1993).CrossRefGoogle Scholar
32.Weyl, W.A. and Marboe, E.C., The Constitution of Glasses (Interscience, New York, 1964) p. 578.Google Scholar
33.Quinn, C.J., Bell, G.H., and Dickinson, J.E., in Proc. XVI Int. Congress on Glass, vol. 4 (Spanish Ceramic and Glass Society, 1992) p. 79.Google Scholar
34.Efimov, A.M., J. Non-Cryst. Solids 209 (1997) p. 209.CrossRefGoogle Scholar
35.Dickinson, J.E., Chimica Chronica 23 (1994) p. 355.Google Scholar
36.Otaigbe, J.U. and Beali, G.H., Trends Polym. Sci. 5 (1997) p. 369.Google Scholar
37.Aitken, B.G., Bookbinder, D.C., Greene, M.E., and Morena, R.M., U.S. Patent No. 5,246,890 (September 21, 1993).Google Scholar
38.Tick, P.A., Phys. Chem. Glasses 25 (1984) p. 149.Google Scholar
39.Brow, R.K., Phifer, C.C., Xu, X.J., and Day, D.E., Phys. Chem. Glasses 33 (1992) p. 33.Google Scholar
40.Tick, P.A. and Hall, D.W., Diff. Defect Data 53–54 (1987) p. 179.CrossRefGoogle Scholar
41.Day, D.E., Wu, Z., and CRay, S., Final Technical Report, Pacific Northwest National Laboratories, Contract No. 276822-A-F1 (1995).Google Scholar
42.Marasinghe, G.K., Karabulut, M., Ray, C.S., Day, D.E., Shumsky, M.G., Yelon, W.B., Booth, C.H., Allen, P.G., and Shuh, D.K., J. Non-Cryst. Solids 222 (1997) p. 144.CrossRefGoogle Scholar
43.Fernandez, C., Delevoye, L., Amourex, J-P., Lang, D.P., and Pruski, M., J. Am. Chem. Soc. 119 (1997) p. 6858.CrossRefGoogle Scholar