Hostname: page-component-586b7cd67f-g8jcs Total loading time: 0 Render date: 2024-11-30T23:51:57.207Z Has data issue: false hasContentIssue false
  • English
  • Français

Reticular Chemistry and Metal-Organic Frameworks for Clean Energy

Published online by Cambridge University Press:  31 January 2011

Omar M. Yaghi  and
Qiaowei Li
Get access

Abstract

Reticular chemistry concerns the linking of molecular building blocks into predetermined structures using strong bonds. We have been working on creating and developing the conceptual and practical basis of this new area of research. As a result, new classes of crystalline porous materials have been designed and synthesized: metal-organic frameworks, zeolitic imidazolate frameworks, and covalent organic frameworks. Crystals of this type have exceptional surface areas (2,000−6,000 m2/g) and take up voluminous amounts of hydrogen (7.5 wt% at 77 K and 3−4 × 106 Pa), methane (50 wt% at 298 K and 2.5 × 106 Pa), and carbon dioxide (140 wt% at 298 K and 3 × 106 Pa). We have driven the basic science all the way to applications without losing sight of our quest for understanding the underlying molecular aspects of this chemistry. The presentation was focused on the design concepts, synthesis, and structure of these materials, with emphasis on their applications to onboard energy storage.

Type
Articles
Information
MRS Bulletin , Volume 34 , Issue 9: Electromechanics on the Nanometer Scale: Emerging Phenomena, Devices, and Applications , September 2009 , pp. 682 - 690
Copyright
Copyright © Materials Research Society 2009

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

1Yaghi, O.M., O'Keeffe, M., Ockwig, N.W., Chae, H.K., Eddaoudi, M., Kim, J., Nature 423, 705 (2003).CrossRefGoogle Scholar
2Long, J.R., Yaghi, O.M., Chem. Soc. Rev. 38, 1213 (2009).CrossRefGoogle Scholar
3Côté, A.P., Benin, A.I., Ockwig, N.W., O'Keeffe, M., Matzger, A.J., Yaghi, O.M., Science 310, 1166 (2005).CrossRefGoogle Scholar
4Park, K.S., Ni, Z., Côté, A.P., Choi, J.Y., Huang, R.D., Uribe-Romo, F.J., Chae, H.K., O'Keeffe, M., Yaghi, O.M., Proc. Natl. Acad. Sci. USA 103, 10186 (2006).CrossRefGoogle Scholar
5Wong-Foy, A.G., Matzger, A.J., Yaghi, O.M., J. Am. Chem. Soc. 128, 3494 (2006).CrossRefGoogle Scholar
6Dincâ, M., Dailly, A., Liu, Y., Brown, C.M., Neumann, D.A., Long, J.R., J. Am. Chem. Soc. 128, 16876 (2006).CrossRefGoogle Scholar
7Murray, L.J., Dincâ, M., Long, J.R., Chem. Soc. Rev. 38, 1294 (2009).CrossRefGoogle Scholar
8Eddaoudi, M., Kim, J., Rosi, N., Vodak, D., Wachter, J., O'Keeffe, M., Yaghi, O.M., Science 295, 469 (2002).CrossRefGoogle Scholar
9Millward, A.R., Yaghi, O.M., J. Am. Chem. Soc. 127, 17998 (2005).CrossRefGoogle Scholar
10Czaja, A.U., Trukhan, N., Müller, U., Chem. Soc. Rev. 38, 1284 (2009).CrossRefGoogle Scholar
11O'Keeffe, M., Peskov, M.A., Ramsden, S.J., Yaghi, O.M., Acc. Chem. Res. 41, 1782 (2008).CrossRefGoogle Scholar
12Eddaoudi, M., Kim, J., Wachter, J.B., Chae, H.K., O'Keeffe, M., Yaghi, O.M., J. Am. Chem. Soc. 123, 4368 (2001).CrossRefGoogle Scholar
13Furukawa, H., Kim, J., Plass, K.E., Yaghi, O.M., J. Am. Chem. Soc. 128, 8398 (2006).CrossRefGoogle Scholar
14Furukawa, H., Kim, J., Ockwig, N.W., O'Keeffe, M., Yaghi, O.M., J. Am. Chem. Soc. 130, 11650 (2008).CrossRefGoogle Scholar
15Li, H., Eddaoudi, M., Groy, T.L., Yaghi, O.M., J. Am. Chem. Soc. 120, 8571 (1998).CrossRefGoogle Scholar
16Eddaoudi, M., Kim, J., O'Keeffe, M., Yaghi, O.M., J. Am. Chem. Soc. 124, 376 (2002).CrossRefGoogle Scholar
17Ockwig, N.W., Delgado-Friedrichs, O., O'Keeffe, M., Yaghi, O.M., Acc. Chem. Res. 38, 176 (2005).CrossRefGoogle Scholar
18Delgado-Friedrichs, O., O'Keeffe, M., Yaghi, O.M., Acta Cryst. A59, 22 (2003).CrossRefGoogle Scholar
19Delgado-Friedrichs, O., O'Keeffe, M., Yaghi, O.M., Acta Cryst. A59, 515 (2003).CrossRefGoogle Scholar
20Delgado-Friedrichs, O., O'Keeffe, M., Yaghi, O.M., Acta Cryst. A62, 350 (2006).CrossRefGoogle Scholar
21Sudik, A.C., Côté, A.P., Yaghi, O.M., Inorg. Chem. 44, 2998 (2005).CrossRefGoogle Scholar
22Chen, B., Eddaoudi, M., Reineke, T.M., Kampf, J.W., O'Keeffe, M., Yaghi, O.M., J. Am. Chem. Soc. 122, 11559 (2000).CrossRefGoogle Scholar
23Kim, J., Chen, B., Reineke, T.M., Li, H., Eddaoudi, M., O'Keeffe, M., Yaghi, O.M., J. Am. Chem. Soc. 123, 8239 (2001).CrossRefGoogle Scholar
24Li, H., Eddaoudi, M., O'Keeffe, M., Yaghi, O.M., Nature 402, 276 (1999).CrossRefGoogle Scholar
25Kaye, S.S., Dailly, A., Yaghi, O.M., Long, J.R., J. Am. Chem. Soc. 129, 14176 (2007).CrossRefGoogle Scholar
26Rowsell, J.L.C., Spencer, E.C., Eckert, J., Howard, J.A.K., Yaghi, O.M., Science 309, 1350 (2005).CrossRefGoogle Scholar
27Chae, H.K., Siberio-Perez, D.Y., Kim, J., Go, Y., Eddaoudi, M., Matzger, A.J., O'Keeffe, M., Yaghi, O.M., Nature 427, 523 (2004).CrossRefGoogle Scholar
28Rosi, N.L., Eddaoudi, M., Kim, J., O'Keeffe, M., Yaghi, O.M., Angew. Chem. Int. Ed. 41, 284 (2002).3.0.CO;2-M>CrossRefGoogle Scholar
29Rosi, N.L., Kim, J., Chen, B., Eddaoudi, M., O'Keeffe, M., Yaghi, O.M., J. Am. Chem. Soc. 127, 1504 (2005).CrossRefGoogle Scholar
30Han, S.S., Goddard, W.A., J. Am. Chem. Soc. 129, 8422 (2007).CrossRefGoogle Scholar
31Furukawa, H., Miller, M.A., Yaghi, O.M., J. Mater. Chem. 17, 3197 (2007).CrossRefGoogle Scholar
32El-Kaderi, H.M., Hunt, J.R., Mendoza-Cortés, J.L., Côté, A.P., Taylor, R.E., O'Keeffe, M., Yaghi, O.M., Science 316, 268 (2007).CrossRefGoogle Scholar
33Han, S.S., Furukawa, H., Yaghi, O.M., Goddard, W.A., J. Am. Chem. Soc. 130, 11580 (2008).CrossRefGoogle Scholar
34Han, S.S., Mendoza-Cortés, J.L., Goddard, W.A., Chem. Soc. Rev. 38, 1460 (2009).CrossRefGoogle Scholar
35Furukawa, H., Yaghi, O.M., J. Am. Chem. Soc. 131, 8875 (2009).CrossRefGoogle Scholar
36http://www.ecofuel-asia-tour.com/; http://www.ecofuel-world-tour.com/.Google Scholar
37Sanderson, K., Nature 448, 746 (2007).CrossRefGoogle Scholar
38Banerjee, R., Phan, A., Wang, B., Knobler, C., Furukawa, H., O'Keeffe, M., Yaghi, O.M., Science 319, 939 (2008).CrossRefGoogle Scholar
39Wang, B., Côté, A.P., Furukawa, H., O'Keeffe, M., Yaghi, O.M., Nature 453, 207 (2008).CrossRefGoogle Scholar
40Banerjee, R., Furukawa, H., Britt, D., Knobler, C., O'Keeffe, M., Yaghi, O.M., J. Am. Chem. Soc. 131, 3875 (2009).CrossRefGoogle Scholar