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Polymer Electrolyte Membrane Technology for Fuel Cells

Published online by Cambridge University Press:  31 January 2011

Raj G. Rajendran
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Abstract

The concept of using an ion-exchange membrane as an electrolyte separator for polymer electrolyte membrane (PEM) fuel cells was first reported by General Electric in 1955. However, a real breakthrough in PEM fuel cell technology occurred in the mid-1960s after DuPont introduced Nafion®, a perfluorosulfonic acid membrane. Due to their inherent chemical, thermal, and oxidative stability, perfluorosulfonic acid membranes displaced unstable polystyrene sulfonic acid membranes.Today, Nafion® and other related perfluorosulfonic acid membranes are considered to be the state of the art for PEM fuel cell technology. Although perfluorosulfonic acid membrane structures are preferred today, structural improvements are still needed to accommodate the increasing demands of fuel cell systems for specific applications. Higher performance, lower cost, greater durability, better water management, the ability to perform at higher temperatures, and flexibility in operating with a wide range of fuels are some of the challenges that need to be overcome before widespread commercial adoption of the technology can be realized. The present article will highlight the membrane properties relevant to PEM fuel cell systems, the development history of perfluorosulfonic acid membranes, and the current status of R&D activities in PEM technology.

Keywords

ionic conductivityNafion®perfluorosulfonic acid membranesPEM fuel cellspolymer electrolyte membranesproton-exchange membranes
Type
Research Article
Information
MRS Bulletin , Volume 30 , Issue 8: Fuel Cells: The Next Evolution , August 2005 , pp. 587 - 590
Copyright
Copyright © Materials Research Society 2005

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References

1.Grubb, W.T., U.S. Patent 2,913,511 (November 17, 1959).Google Scholar
2.Grubb, W.T. and Niedrach, L.W., J. Electrochem. Soc. 107 (1960) p. 131.CrossRefGoogle Scholar
3.Cairns, E.J., Douglas, D.L., and Niedrach, L.W., AIChE J. 7 (1961) p. 551.CrossRefGoogle Scholar
4.Connolly, D.J. and Gresham, W.F., U.S. Patent 3,282,875 (November 1, 1966).Google Scholar
5.Chem. Eng. News (August 27, 1973) p. 15.Google Scholar
6.Grot, W.G., Macromol. Symp. 82 (1994) p. 161.CrossRefGoogle Scholar
7.LaConti, A.B., Hamdan, M., and McDonald, R.C., in Handbook of Fuel Cells: Fundamentals, Technology, and Applications, Vol. 3, Part 1, Chapter 49, edited by Vielstich, W., Gasteiger, H.A., and Lamm, A. (John Wiley & Sons, New York, 2003) p. 647.Google Scholar
8.Eisenberg, A. and Yeager, H.L., eds., Perfluorinated Ionomer Membranes, ACS Symposium Series No. 180 (American Chemical Society, Washington, D.C., 1982).CrossRefGoogle Scholar
9.Doyle, M. and Rajendran, G., in Handbook of Fuel Cells: Fundamentals, Technology, and Applications, Vol. 3, Part 1, Chapter 30, edited by Vielstich, W., Gasteiger, H.A., and Lamm, A. (John Wiley & Sons, New York, 2003) p. 351.Google Scholar
10.Mauritz, K.A. and Moore, R.B., Chem. Rev. 104 (10) (2004) p. 4535.CrossRefGoogle Scholar
11.Grot, W.G., Munn, G.E., Walmsley, P.N., “Perfluorinated Ion Exchange Membrane,” presented at the 141st Natl. Meet. Electrochem. Soc., Houston, Texas, May 7–11, 1972.Google Scholar
12.Doyle, M., Lewittes, M.E., Roelofs, M.G., and Perusich, S.A., J. Phys. Chem. B, 105 (2001) p. 9387.CrossRefGoogle Scholar
13.Fernandez, R.E., in Polymer Data Handbook (Oxford University Press, 1999) p. 233.Google Scholar
14.Banerjee, S. and Curtin, D., J. Fluorine Chem. 125 (2004) p. 1211.CrossRefGoogle Scholar
15.Grot, W.G., U.S. Patent 3,770,567 (November 6, 1973).Google Scholar
16.Watanabe, I., Yamakoshi, Y., Miyauchi, H., Tsushima, S., and Fukumoto, M., U.S. Patent 4,072,793 (February 7, 1978).Google Scholar
17.Grot, W.G., Rivers, J.T., and Silva, R.H., U.S. Patent 4,469,744 (September 4, 1984).Google Scholar
18.Banerjee, S., “Fuel cell incorporating a reinforced membrane,” U.S. Patent 5,795,668 (August 18, 1998).Google Scholar
19.Kolde, J.A., Bahar, B., Wilson, M.S., Zawodzinski, T.A., and Gottesfeld, S., in Proc. of the First Inatl. Symp. on Proton Exchange Membrane Fuel Cells, edited by Gottesfeld, S., Halpert, G., and Landgrebe, A., ECS Proc. Vol. 95–23 (The Electrochemical Society, Pennington, N.J., 1995) p. 193.Google Scholar
20.Ishisaki, T., Umemura, K., Yanagisawa, E., Kunisa, Y., Terada, I., and Yoshitake, M., in Abstracts, Fuel Cell Seminar (2000) p. 23.Google Scholar
21.Nakao, M. and Yoshitake, M., in Handbook of Fuel Cells: Fundamentals, Technology and Applications, Vol. 3, Part 1, Chapter 31, edited by Vielstich, W., Gasteiger, H.A., and Lamm, A. (John Wiley & Sons, New York, 2003) p. 412.Google Scholar
22.Savinell, R.F., Wainright, J., and Litt, M., 194th Meet. Electrochem. Soc., extended abstracts, No. 1107 (1998).Google Scholar
23.Peled, E., Devdevani, T., and Melman, A., Electrochem. Solid-State Lett. 1 (1998) p. 210.CrossRefGoogle Scholar
24.Grot, W.G. and Rajendran, G., “Membranes containing inorganic fillers and membrane and electrode assemblies and electrochemical cells employing same,” U.S. Patent 5,919,583 (July 6, 1999).Google Scholar
25.Antonucci, P.L., Arico, A.S., Creti, P., Ramunni, E., and Antonucci, V., Solid State Lett. 125 (1999) p. 431.Google Scholar
26.Kerres, J.A., J. Membr. Sci. 185 (2001) p. 3.CrossRefGoogle Scholar
27.Deluga, G. and Pivovar, B.S., Fourth Intl. Symp. on New Materials for Electrochemical Systems, extended abstracts, Montreal, Canada, July 4–8, 1999, p. 132.Google Scholar
28.Rajendran, G., presented at Electrochemical Technology for the 21st Century, Clearwater Beach, Fla., Nov. 12–13, 2000.Google Scholar
29.Chapiro, A., in High Polymers, Vol. XV, edited by Mark, H., Maxell, C.S., and Melville, H.W. (Wiley Interscience, London, 1962).Google Scholar
30.Brack, H.P., Buhrer, H.G., Bonorand, L., and Scherer, G.G., J Mater. Chem. 10 (2000) p. 17.CrossRefGoogle Scholar
31.Steck, A.E., in Proc. First Inatl. Symp. on New Materials for Fuel Cell Systems, edited by Savadogo, O., Roberge, P.R., and Veziroglu, T.N. (Montreal, Canada, July 9–13, 1995) p. 74.Google Scholar
32.Steck, A.E. and Stone, C., in Proc. Second Inatl. Symp. on New Materials for Fuel Cell and Modern Battery Systems, edited by Savadogo, O. and Roberge, P.R. (Ecole Polytechnique de Montreal, Montreal, Canada, 1997) p. 792.Google Scholar
33.Savadogo, O., J. New Mater. Electrochem. Sys. 1 (1998) p. 47.Google Scholar
34.Roziere, J. and Jones, D.J., Annu. Rev. Mater. Res. 33 (2003) p. 503.CrossRefGoogle Scholar
35.Laconti, A.B., Application of Perfluorocarbon Solid Polymer Electrolytes in Fuel Cells and Electrolyzers, ACS Polymer Tropical Workshop on Perfluorinated Ionomer Membranes, Lake Buena Vista, Fla., February 23–26, 1982.Google Scholar