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Bulk Glass-Forming Metallic Alloys: Science and Technology

Published online by Cambridge University Press:  29 November 2013

William L. Johnson
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The following article is based on the MRS Medal talk presented by William L. Johnson at the 1998 MRS Fall Meeting on December 2, 1998. The MRS Medal is awarded for a specific outstanding recent discovery or advancement that has a major impact on the progress of a materials-related field. Johnson received the honor for his development of bulk metallic glass-forming alloys, the fundamental understanding of the thermodynamics and kinetics that control glass formation and crystallization of glass-forming liquids, and the application of these materials in engineering.

The development of bulk glass-forming metallic alloys has led to interesting advances in the science of liquid metals. This article begins with brief remarks about the history and background of the field, then follows with a discussion of multicomponent glass-forming alloys and deep eutectics, the chemical constitution of these new alloys, and how they differ from metallic glasses of a decade ago or earlier. Recent studies of deeply undercooled liquid alloys and the insights made possible by their exceptional stability with respect to crystallization will then be discussed. Advances in this area will be illustrated by several examples. The article then describes some of the physical and specific mechanical properties of bulk metallic glasses (BMGs), and concludes with some interesting potential applications.

The first liquid-metal alloy vitrified by cooling from the molten state to the glass transition was Au-Si, as reported by Duwez at Caltech in 1960. Duwez made this discovery as a result of developing rapid quenching techniques for chilling metallic liquids at very high rates of 105–106 K/s.

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Technical Features
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MRS Bulletin , Volume 24 , Issue 10 , October 1999 , pp. 42 - 56
Copyright
Copyright © Materials Research Society 1999

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References

1.Clement, W., Willens, R.H., and Duwez, P., Nature 187 (1960) p. 869.CrossRefGoogle Scholar
2.Chen, H.S. and Turnbull, D., J. Chem. Phys. 48 (1968) p. 2560.CrossRefGoogle Scholar
3.Chen, H.S. and Turnbull, D., Acta Metall. 17 (1969) p. 1021.CrossRefGoogle Scholar
4.Turnbull, D. and Fisher, J.C., J. Chem. Phys. 17 (1949) p. 71; D. Turnbull, J. Chem. Phys. 18 (1950) p. 198.CrossRefGoogle Scholar
5. For a review of melt spinning and planar flow casting technology, see Kavesh, S., in Metallic Glasses, Chapter 2, edited by Gillman, J.J. and Leamy, H.J. (ASM International, Metals Park, OH, 1978) p. 36.Google Scholar
6.Chen, H.S., Acta Metall. 22 (1974) p. 1505.CrossRefGoogle Scholar
7.Drehman, A.L., Greer, A.L., and Turnbull, D., Appl. Phys. Lett. 41 (1982) p. 716.CrossRefGoogle Scholar
8.Kui, H.W., Greer, A.L., and Turnbull, D., Appl. Phys. Lett. 45 (1984) p. 615.CrossRefGoogle Scholar
9.Inoue, A., Yamaguchi, H., Zhang, T., and Masumoto, T., Mater Trans. JIM 31 (1990) p. 104; A. Inoue, T. Zhang, and T. Masumoto, Mater. Trans. JIM 30 (1990) p. 965.CrossRefGoogle Scholar
10.Inoue, A., Nakamura, T., Nishiyama, N., and Masumoto, T., Mater. Trans. JIM 33 (1992) p. 937; A. Inoue, T. Nakamura, T. Sugita, T. Zhang, and T. Masumoto, Mater. Trans. JIM 34 (1993) p. 351.CrossRefGoogle Scholar
11.Inoue, A., Kato, A., Zhang, T., Kim, S.G., and Masumoto, T., Mater. Trans. JIM 32 (1991) p. 609.CrossRefGoogle Scholar
12.Inoue, A., Mater. Trans. 36 (1995) p. 866.CrossRefGoogle Scholar
13.Inoue, A., Zhang, T., and Masumoto, T., Mater. Trans. JIM 31 (1990) p. 177.CrossRefGoogle Scholar
14.Inoue, A., Zhang, T., Nishiyama, N., Ohba, K., and Masumoto, T., Mater. Trans. JIM 34 (1993) p. 1234.CrossRefGoogle Scholar
15.Peker, A. and Johnson, W.L., Appl. Phys. Lett. 63 (1993) p. 2342.CrossRefGoogle Scholar
16.Peker, A. and Johnson, W.L., Patent, U.S. No. 5,288,344 (February 1994); A. Peker, PhD dissertation, California Institute of Technology, 1994.Google Scholar
17.Lin, X.H. and Johnson, W.L., J. Appl. Phys. 78 (1995) p. 6514.CrossRefGoogle Scholar
18.Kim, Y.J., Busch, R., Johnson, W.L., Rulison, A.J., and Rhim, W.K., Appl. Phys. Lett. 65 (1994) p. 2136; Y.J. Kim, R. Busch, W.L. Johnson, A.J. Rulison, and W.K. Rhim, Appl. Phys. Lett. 68 (1996) p. 1057.CrossRefGoogle Scholar
19.Schwarz, R.B. and He, Y., Mater. Sci. Forum 235 (1997) p. 231.Google Scholar
20.Nishiyama, N. and Inoue, A., Mater. Trans. JIM 37 (1996) p. 1531.CrossRefGoogle Scholar
21.Egami, T. and Waseda, Y., J. Non-Cryst. Solids 64 (1984) p. 113.CrossRefGoogle Scholar
22.Egami, T., Mater. Sci. Eng. A 226 (1997) p. 261.CrossRefGoogle Scholar
23.Li, M. and Johnson, W.L., Phys. Rev. Lett. 70 (1993) p. 1120.CrossRefGoogle Scholar
24.Fecht, H.J., Desre, P., and Johnson, W.L., Philos. Mag. 59 (1989) p. 577.CrossRefGoogle Scholar
25.Hume-Rothery, W., The Structure of Metals and Alloys (The Institute of Metals, London, 1956) p. 101.Google Scholar
26.Tanner, L.E., Acta Metall. 27 (1979) p. 1727.CrossRefGoogle Scholar
27.Lin, X.H., PhD dissertation, California Institute of Technology, 1997.Google Scholar
28.Rhim, W.K., Rev. Sci. Instrum. 64 (1993) p. 2961.CrossRefGoogle Scholar
29.Busch, R., Kim, Y.J., Schneider, S., and Johnson, W.L., Mater. Sci. Forum 225 (1996) p. 77.CrossRefGoogle Scholar
30.Davies, H.A., in 3rd Int. Conf. Rapid Quenching, edited by Cantor, B. (The Metals Society, London, 1978) p. 1.Google Scholar
31.Davies, H.A., Phys. Chem. Glasses 17 (1976) p. 159.Google Scholar
32.Masuhr, A., PhD dissertation, California Institute of Technology, 1999.Google Scholar
33.Masuhr, A., Waniuk, T.A., Busch, R., and Johnson, W.L., Phys. Rev. Lett. 82 (1999) p. 2290.CrossRefGoogle Scholar
34.Busch, R., Schneider, S., Peker, A., and Johnson, W.L., Appl. Phys. Lett. 67 (1995) p. 1544.CrossRefGoogle Scholar
35.Miller, M.K., Russel, K.F., Martin, P.M., Busch, R., and Johnson, W.L., J. Phys. IV 6 (1996) p. 217.Google Scholar
36.Schneider, S., Geyer, U., Thiyagarajan, P., and Johnson, W.L., Mater. Sci. Forum 225 (1996) p. 59.CrossRefGoogle Scholar
37.Schneider, S., Geyer, U., Thiyagarajan, P., and Johnson, W.L., Mater. Sci. Forum 235 (1997) p. 337.Google Scholar
38.Busch, R. and Johnson, W.L., Appl. Phys. Lett. 72 (1998) p. 2695.CrossRefGoogle Scholar
39.Busch, R., Liu, W., and Johnson, W.L.,J. Appl. Phys. 83 (1998) p. 4134.CrossRefGoogle Scholar
40.Liu, W., Johnson, W.L., Schneider, S., Geyer, U., and Thiyagarajan, P., Phys. Rev. B 59 (1999) p. 11755.CrossRefGoogle Scholar
41.Liu, W., PhD dissertation, California Institute of Technology, 1998.Google Scholar
42.Desre, P.J., Mater. Trans. JIM 38 (1997) p. 583.Google Scholar
43.Desre, P.J., in Bulk Metallic Glasses (Mater. Res. Soc. Symp. Proc., 554, Warrendale, PA, 1999).Google Scholar
44.Lin, X.H., Johnson, W.L., and Rhim, W.K., Mater. Trans. JIM 38 (1997) p. 473.CrossRefGoogle Scholar
45.Lin, X.H., PhD dissertation, California Institute of Technology, 1997.Google Scholar
46.Bakke, E., Busch, R., and Johnson, W.L., Appl. Phys. Lett. 67 (1995) p. 3260.CrossRefGoogle Scholar
47.Bakke, E., Busch, R., and Johnson, W.L., Mater. Sci. Forum 225 (1996) p. 95.CrossRefGoogle Scholar
48.Busch, R. and Johnson, W.L., Mater. Sci. Forum 269 (1998) p. 577; R. Busch, A. Masuhr, E. Bakke, and W.L. Johnson, Mater. Sci. Forum 269 (1998) p. 547.CrossRefGoogle Scholar
49.Busch, R., Bakke, E., and Johnson, W.L., Acta Mater. 46 (1998) p. 4725.CrossRefGoogle Scholar
50.Waniuk, T.A., Busch, R., Masuhr, A., and Johnson, W.L., Acta Mater. 46 (1998) p. 5229.CrossRefGoogle Scholar
51.Chen, H.S. and Goldstein, M., J. Appl. Phys. 43 (1971) p. 1642.CrossRefGoogle Scholar
52.Taub, A.I. and Spaepen, F., Acta Metall. Mater. 28 (1980) p. 633.CrossRefGoogle Scholar
53.Volkert, C.A. and Spaepen, F., Acta Metall. Mater. 37 (1989) p. 1355.CrossRefGoogle Scholar
54.Angell, C.A., Science 267 (1995) p. 1924.CrossRefGoogle Scholar
55.Angell, C.A., Richards, B.E., and Velikov, V., J. Phys.: Condens. Matter. 11 (1999) p. A75.Google Scholar
56.Spaepen, F. and Turnbull, D., in Rapidly Quenched Metals II, edited by Grant, N.J. and Giessen, B.C. (MIT Press, Boston, 1976) p. 2057.Google Scholar
57.Davies, H.A., in Rapidly Quenched Metals III, edited by Cantor, B. (The Metals Society, London, 1978) p. 1.Google Scholar
58.Geyer, U., Schneider, S., Johnson, W.L., Qiu, Y., Tombrello, T.A., and Macht, M.P., Phys. Rev. Lett. 75 (1995) p. 2364.CrossRefGoogle Scholar
59.Geyer, U., Johnson, W.L., Schneider, S., Qiu, Y., Tombrello, T.A., and Macht, M.P., Appl. Phys. Lett. 69 (1996) p. 2492.CrossRefGoogle Scholar
60.Wenwer, F., Knorr, K., Macht, M.P., and Mehrer, H., Defect Diffusion Forum 143 (1997) p. 831.CrossRefGoogle Scholar
61.Dorner, W. and Mehrer, H., Phys. Rev. B 44 (1991) p. 101.CrossRefGoogle Scholar
62.Masuhr, A., Waniuk, T.A., Busch, R., and Johnson, W.L., Phys. Rev. Lett. 82 (1999) p. 2290; A. Masuhr, R. Busch, and W.L. Johnson, in Bulk Metallic Glasses (Mater. Res. Soc. Symp. Proc, 554, Warrendale, PA, 1999).CrossRefGoogle Scholar
63.Angell, C.A., Chem. Rev. 90 (1990) p. 523.CrossRefGoogle Scholar
64.Ediger, M.E., Angell, C.A., and Nagel, S.R., J. Phys. Chem. 100 (1996) p. 13200.CrossRefGoogle Scholar
65.Meyer, A., Wuttke, J., Petry, W., Randl, O.G., and Schober, H., Phys. Rev. Lett. 80 (1998) p. 4454.CrossRefGoogle Scholar
66.Bruck, H.A., Christman, T., Rosakis, A.J., and Johnson, W.L., Scripta Mater. 30 (1994) p. 429.CrossRefGoogle Scholar
67.Conner, R.D., Rosakis, A.J., Johnson, W.L., and Owen, D., Scripta Mater. 37 (1997) p. 1373.CrossRefGoogle Scholar
68.Gilbert, C.J., Ritchie, R.O., and Johnson, W.L., Appl. Phys. Lett. 71 (1997) p. 476.CrossRefGoogle Scholar
69.Lowhaphandu, P. and Lewandowski, J.J., Scripta Mater. 38 (1998) p. 1811.CrossRefGoogle Scholar
70.Leng, Y. and Courtney, T.H., J. Mater. Sci. 26 (1991) p. 588.CrossRefGoogle Scholar
71.Dandliker, R.B., Conner, R.D., and Johnson, W.L., J. Mater. Res. 13 (1998) p. 2896.CrossRefGoogle Scholar
72.Choi-Yim, H. and Johnson, W.L., Appl. Phys. Lett. 71 (1997) p. 3808.CrossRefGoogle Scholar
73.Conner, R.D., Dandliker, R.B., and Johnson, W.L., Acta Meter. 46 (1998) p. 6089.CrossRefGoogle Scholar
74.Choi-Yim, H., PhD dissertation, California Institute of Technology, 1999.Google Scholar
75.Choi-Yim, H., Busch, R., and Johnson, W.L., J. Appl. Phys. 83 (1998) p. 7993.CrossRefGoogle Scholar
76.Dandliker, R.B., PhD dissertation, California Institute of Technology, 1998.Google Scholar
77.Conner, R.D., PhD dissertation, California Institute of Technology, 1998.Google Scholar
78. For example, see Ashley, S., “Metallic Glasses Bulk Up,” Mech. Eng. (June 1998) p. 73.Google Scholar
79.Budke, E., Fielitz, P., Macht, M.P., Naundorf, V., and Frohberg, G., Defect Diffus. Forum 143–147 (1997) p. 825.CrossRefGoogle Scholar