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Synthesis of two cyanine dyes as potential artificial antennas for the bacterial photosynthetic Reaction Center

Published online by Cambridge University Press:  01 February 2019

R. Ragni ,
G. Leone ,
G. Rizzo ,
S. la Gatta ,
F. Milano ,
M. Trotta Open the ORCID record for M. Trotta [Opens in a new window]  and
G. M. Farinola
R. Ragni
Affiliation:
Dipartimento di Chimica, Università degli Studi di Bari “Aldo Moro”, via Orabona 4, I-70126Bari
G. Leone
Affiliation:
Dipartimento di Chimica, Università degli Studi di Bari “Aldo Moro”, via Orabona 4, I-70126Bari
G. Rizzo
Affiliation:
Dipartimento di Chimica, Università degli Studi di Bari “Aldo Moro”, via Orabona 4, I-70126Bari
S. la Gatta
Affiliation:
Dipartimento di Chimica, Università degli Studi di Bari “Aldo Moro”, via Orabona 4, I-70126Bari Istituto per i Processi Chimico-Fisici CNR-IPCF, Dipartimento di Chimica, via Orabona 4, I-70126Bari
F. Milano
Affiliation:
CNR-ISPA, Institute of Sciences of Food Production, Lecce Unit, Via Prov.le Monteroni, 73100Lecce, Italy.
M. Trotta
Affiliation:
Istituto per i Processi Chimico-Fisici CNR-IPCF, Dipartimento di Chimica, via Orabona 4, I-70126Bari
G. M. Farinola*
Affiliation:
Dipartimento di Chimica, Università degli Studi di Bari “Aldo Moro”, via Orabona 4, I-70126Bari
*
* Authors to whom correspondence should be addressed (Email: [email protected])
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Abstract:

Particular attention has been recently devoted to the development of biohybrid photoconverters based on the bacterial Reaction Center (RC) of Rhodobacter sphaeroides. This highly efficient photoenzyme has a conversion yield close to unit that makes it extremely appealing in the field of artificial photosynthesis. Isolated RCs suffer of a limited absorption cross-section in the visible spectral region that limits their applicative employment. Here we report the synthesis of two heptamethine cyanine molecules, whose photophysical properties make them potentially suitable as light harvesting antennas for the RC.

Keywords

biomimetic (assembly)biological synthesis (assembly)
Type
Articles
Information
MRS Advances , Volume 4 , Issue 22: Biomaterials and Soft Materials , 2019 , pp. 1293 - 1298
Copyright
Copyright © Materials Research Society 2019 

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Footnotes

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Permanent address: Istituto per i Processi Chimico-Fisici CNR-IPCF.

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