Hostname: page-component-586b7cd67f-t7fkt Total loading time: 0 Render date: 2024-11-24T18:51:08.583Z Has data issue: false hasContentIssue false
  • English
  • Français

Phase Diagram of LiF-Li3PO4 System: A New Mechanism of Heterovalent Anionic Isomorphism

Published online by Cambridge University Press:  28 December 2017

G.V. Zimina ,
M. Tsygankova ,
M. Sadykova ,
F.M. Spiridonov ,
V.V. Fomichev  and
P.P. Fedorov
G.V. Zimina
Affiliation:
Moscow Technological University (Institute of Fine Chemical Technologies), Vernadskogo Avenue, 86, Moscow, 119571
M. Tsygankova
Affiliation:
Moscow Technological University (Institute of Fine Chemical Technologies), Vernadskogo Avenue, 86, Moscow, 119571
M. Sadykova*
Affiliation:
Moscow Technological University (Institute of Fine Chemical Technologies), Vernadskogo Avenue, 86, Moscow, 119571
F.M. Spiridonov
Affiliation:
Chemical Department, Lomonosov Moscow State University, Moscow119991, Russia
V.V. Fomichev
Affiliation:
Moscow Technological University (Institute of Fine Chemical Technologies), Vernadskogo Avenue, 86, Moscow, 119571
P.P. Fedorov
Affiliation:
Moscow Technological University (Institute of Fine Chemical Technologies), Vernadskogo Avenue, 86, Moscow, 119571 Prochorov General Physics Institute, Russian Academy of Sciences, Moscow, 119991, Russia
*
*(Email: [email protected])
Get access

Abstract

The phase diagram of LiF-Li3PO4 system is studied. The eutectic coordinates are 800±5°C, 8±1 mol% Li3PO4. A region of a solid solution based on lithium phosphate with a length of up to 11±2 mol% LiF was discovered. It is assumed that there is heterovalent isomorphism where anionic tetrahedron (PO4)3- is replaced by tetrahedron (LiF4)3-.

Keywords

Lielectronic materialx-ray diffraction (XRD)
Type
Articles
Information
MRS Advances , Volume 3 , Issue 23: Energy and Sustainability , 2018 , pp. 1309 - 1317
Check for updates
Copyright
Copyright © Materials Research Society 2017 

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

Palacin, M.R., Chem. Soc. Rev. 38 (2009) 2565–2575.Google Scholar
Dunn, B., Kamath, H., Tarascon, J.M., Science 1334 (2011) 928–935.Google Scholar
Wang, Y., Li, H., Chen, M., Yang, X., Jiang, D., Ionics 23 (2017) 377–384.Google Scholar
Karakulina, O.M., Khasanova, N.R., Drozhzhin, O.A., Tsirlin, A.A., Hadermann, J., Antipov, E.V., Abakumov, A.M., Chem. Mater. 28 (2016) 7578–7581.Google Scholar
Antipov, E.V., Khasanova, N.R., Fedotov, S.S., IUCrJ 2 (2015) 85–94.CrossRefGoogle Scholar
Bukhalova, G.A., Mardirosova, I.V., Zh. Neorg. Khim. 12 (1967) 2825–2828Google Scholar
Fedorov, P.P., Medvedeva, L.V., Zh. Neorg. Khim. 34 (1989) 2674–2677.Google Scholar
Wang, B., Chakoumakos, B.C., Kwak, B.S., Bates, J.B., J. Solid State Chem. 115 (1995) 313–319.Google Scholar
Jbara-Ramirez, C., Villapuerte-Castrejun, M.E., West, A.R., J. Mater. Sci. 20 (1985) 812–816Google Scholar
Rualean, E., Effukeir, A., Quarton, M., J. Solid State Chem. 79 (1989) 205–216Google Scholar
West, A.R.. Solid State Chemistry and its applications. Wiley, 2014. 584 p.Google Scholar
Fedorov, P.P., Crystallog. Rep. 42 (1997) 1064–1075.Google Scholar
Sani, E., Rabe, M., Reck, G., Becker, P., Roßberg, M., Bertram, R., Klimm, D., Cryst. Res. Techn. 40 (2005) 26–31.Google Scholar
Grzechnik, A., Krüger, H., Kahlenberg, V., Friese, K., J. Phys.: Condens Matter 18 (2006), 8925–8934.Google Scholar
Goryunov, A.V., Popov, A.I., Khajdukov, N.M., Fedorov, P.P., Mat. Res. Bull. 27 (1992) 213–220.Google Scholar
Burm, J.H., Busing, W.R., Inorganic Chemistry. 4 (1965) 1510–1512.Google Scholar
Bekker, T.B., Rashchenko, S.V., Solntsev, V.P., Yelisseyev, A.P., Kragzhda, A.A., Bakakin, V.V., Seryotkin, Y.V., Kokh, A.E., Kokh, K.A., Kuznetsov, A.B., Inorg. Chem. 56 (2017) 5411–5419.Google Scholar
Werner, F., Kubel, F., Chem, J.. Cryst. 35 (2005) 457–462.Google Scholar
Smirnov, P.S., Maak, H., Strukov, B.A.. Kristallografiya 30 (1985) 817–820.Google Scholar
Fedorov, P.P., Russ. J. Inorg. Chem. 45 (2000) 268–291.Google Scholar
Valley, J.W., Essene, E.J., Peacor, D.R., Am. Mineral. 68 (1983) 444–448.Google Scholar
Crepisson, C., Blanchard, M., Bureau, H., Sanloup, C., Withers, A.C., Khodja, H., Surble, S., Raepsaet, C., Beneut, K., Leroy, C., Giura, P., Balan, E., Earth Planet. Sci. Lett. 390 (2014) 287–295.Google Scholar
Ingrin, J., Kovacs, I., Deloule, E., Balan, E., Blanchard, M., Kohn, S.C., Hermann, J., Am. Mineral. 99 (2014) 2138–2141.Google Scholar
Rashchenko, S.V., Bekker, T.B., Bakakin, V.V., Seryotkin, Y.V., Kokh, A.E., Gille, P., Popov, A.I., Fedorov, P.P., J. Appl. Cryst. 46 (2013) 1081–1084.Google Scholar
Rashchenko, S.V., Bakakin, V.V., Kozlova, S.G., Bekker, T.B., Fedorov, P.P., J. Struct. Chem. 56 (2015) 85–91.CrossRefGoogle Scholar