Hostname: page-component-586b7cd67f-dsjbd Total loading time: 0 Render date: 2024-11-24T07:24:55.820Z Has data issue: false hasContentIssue false

N-Vinylcaprolactam grafting onto cotton gauze by gamma radiation for loading and controlled release of antibacterial silver nanoparticles

Published online by Cambridge University Press:  09 October 2020

Daniel Espinosa-Olivares*
Affiliation:
Departamento de Química de Radiaciones y Radioquímica, Instituto de Ciencias Nucleares, Universidad Nacional Autónoma de México, Circuito Exterior, Ciudad Universitaria, CDMX04510, México.
Emilio Bucio
Affiliation:
Departamento de Química de Radiaciones y Radioquímica, Instituto de Ciencias Nucleares, Universidad Nacional Autónoma de México, Circuito Exterior, Ciudad Universitaria, CDMX04510, México.
Get access

Abstract

To contribute to the development of new alternatives in the area of polymers for biomedical applications, the surface modification of a cotton gauze grafted with a N-vinylcaprolactam (NVCL) by ionizing gamma radiation was developed, in to provide it with more physical and chemical properties. To verify that the grafting was successful, the samples were analyzed and characterized by attenuated total reflectance, by Fourier transform infrared spectroscopy, differential scanning calorimetry, and thermogravimetric analysis. The grafted samples showed greater hydrophilicity and affinity with drugs, as well as a critical solution temperature between 33 and 40 °C; therefore, this material was implemented as administrator of AgNPs in controlled doses, thus obtaining a material with greater absorption, anti-inflammatory and with antimicrobial characteristics.

Type
Articles
Copyright
Copyright © The Author(s), 2020, published on behalf of Materials Research Society by Cambridge University Press

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

Hruby, M., Kucka, J., Lebeda, O., Mackova, H., Babic, M., Konak, C., Studenovsky, M., Sikora, A., Kozempel, J., and Ulbrich, K., J. Controlled Release 119(1), 25 (2007).CrossRefGoogle Scholar
Rhine, W. S., Controlled Release of Bioactive Material. (Academic Press, New York 1980) p. 177.CrossRefGoogle Scholar
Cano Serrano, E. and Urbina Fraile, M., Polimeros inteligentes y aplicaciones. (Circuito de inovacion en materiales, Madrid 2009 p 5.Google Scholar
Basico, C.D., Aspectos generales de la interaccion de la radiacion con el medio biologico. (Cursode SUPERVISORES deinstalaciones radiactivas(IR) módulo básico, Madrid 2013) p 3Google Scholar
Nakamura, Y., Ogiwara, Y., and Philips, G. O., Polym. Photochem. 6(2), 135 (1985).10.1016/0144-2880(85)90020-XCrossRefGoogle Scholar
Luna-Straffon, M. A., Contreras-García, A., Brackman, G., Coenye, T., Concheiro, A., Alvarez-Lorenzo, C., and Bucio, E., Cellulose 21, 3767 (2014).CrossRefGoogle Scholar
Roy, D., Semsarilar, M., Guthrie, J.T., and Perrier, S., Chem. Soc. Rev. 38, 2046 (2009).CrossRefGoogle Scholar
Odian, G., Principles of Polymerization. (Wiley-Interscience New York 2004) p 745.CrossRefGoogle Scholar
Pino-Ramos, V.H., Ramos-Ballesteros, A., López-Saucedo, F., López-Barriguete, J.E., Varca, G.H.C., and Bucio, E., Top. Curr. Chem. 374, 63 (2016).CrossRefGoogle Scholar
Braun, D., Cherdron, H., Rehahn, M., Ritter, H, Voit, B., Polymer Synthesis; Theory and Practice. (Springer-Verlag Berlin Heidelberg, 2009). P. 323.Google Scholar
Chauhan, V., Howland, M., Kutzner, B., McNamee, J.P., Bellier, P.V., and Wilkins, R.C., Int. J. Hyg. Envir. Heal. 215, 339 (2012).CrossRefGoogle Scholar
Flores-Rojas, G.G., López-Saucedo, F., Vázquez, E., Hernández-Mecinas, E., Huerta, L., Cedillo, G., Concheiro, A., Alvarez-Lorenzo, C., and Bucio, E., Cellulose 27, 2785 (2020).CrossRefGoogle Scholar
Flores-Rojas, G.G., López-Saucedo, F., and Bucio, E., Radiat. Phys. Chem. 169, 107962 (2020).10.1016/j.radphyschem.2018.08.011CrossRefGoogle Scholar
Evanoff, D. D. Jr and Chumanov, G., Chem. Phys. Chem. 6, 1221 (2005).10.1002/cphc.200500113CrossRefGoogle Scholar
Martinez-Gutierrez, F., Thi, E.P., Silverman, J. M., de Oliveira, .C.C, Svensson, S.L-, Venden Hoek, A., Conway, E.M., Orrontia, E., Sanchez, E.M., Reinor, N.E., Gaynor, E.C., ryzdial, E.L.G. P, Ruiz, F., Av-Gay, Y. and Bach, H., Nanomed-Nanotechnol. 8, 328 (2012).10.1016/j.nano.2011.06.014CrossRefGoogle Scholar
Coutiño, E.M.R. and Ávila-Lagunes, L., and Arroyo-Helguera, O., Rev. Educ. Bioquimica 36(2), 39 (2017).Google Scholar
Honey, P.J., Rijo, J., and Anju, A., Acta Pharm Sin B.; 4(2): 120(2014).Google Scholar