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Morpho-Butterfly Inspired Lamella-based Optical Sensors for Measuring Percent Level Concentrations of H2 and CO with Au and CeO2

Published online by Cambridge University Press:  24 July 2020

Nora M. Houlihan  and
Michael A. Carpenter
Nora M. Houlihan
Affiliation:
SUNY Polytechnic Institute, 257 Fuller Road, AlbanyNY, 12203, U.S.A.
Michael A. Carpenter
Affiliation:
SUNY Polytechnic Institute, 257 Fuller Road, AlbanyNY, 12203, U.S.A.
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Abstract

Morpho-Butterfly inspired lamella structures were fabricated to make a multivariable optical sensor for measuring percent level concentrations of H2 and CO in a high temperature, zero-O2 environment. The SiO2 and Si3N4 3D structures were covered with gold nanoparticles (AuNPs) and cerium IV dioxide (CeO2) and exposed to varying concentrations of H2 and CO at 300°C. Experiments with AuNP sizes with an average diameter of 11 ± 3 nm and 3 ± 0.5 nm (larger and small AuNPs, respectively) showed that the larger AuNPs had a stronger response to the same concentrations of H2 and CO with less CO saturation and baseline drift. Further testing in the presence of 1% hydrocarbons (HCs) as an interfering gas showed excellent response to up to 17% H2 and CO in a zero-O2 environment with changes in reflected intensity of -13.1 ± 0.4% for H2 and -5.8 ± 0.3% for CO. The presence of HCs did not induce any baseline drift, with the total amount of drift being less than 0.5% over 13 hours of testing at 300°C.

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MRS Advances , Volume 5 , Issue 39: Electronics and Photonics , 2020 , pp. 2043 - 2053
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Copyright © Materials Research Society 2020

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